Euler buckling instability and enhanced current blockade in suspended single-electron transistors

Single-electron transistors embedded in a suspended nanobeam or carbon nanotube may exhibit effects originating from the coupling of the electronic degrees of freedom to the mechanical oscillations of the suspended structure. Here, we investigate theoretically the consequences of a capacitive electromechanical interaction when the supporting beam is brought close to the Euler buckling instability by a lateral compressive strain. Our central result is that the low-bias current blockade, originating from the electromechanical coupling for the classical resonator, is strongly enhanced near the Euler instability. We predict that the bias voltage below which transport is blocked increases by orders of magnitude for typical parameters. This mechanism may make the otherwise elusive classical current blockade experimentally observable.Comment: 15 pages, 10 figures, 1 table; published versio

A Self-Organized-Criticality model consistent with statistical properties of edge turbulence in a fusion plasma

The statistical properties of the intermittent signal generated by a recent model for self-organized-criticality (SOC) are examined. A successful comparison is made with previously published results of the equivalent quantities measured in the electrostatic turbulence at the edge of a fusion plasma. This result re-establishes SOC as a potential paradigm for transport in magnetic fusion devices, overriding shortcomings pointed out in earlier works [E. Spada, et al, Phys. Rev. Lett. 86, 3032 (2001); V. Antoni, et al, Phys. Rev. Lett. 87, 045001 (2001)].Comment: 4 pages, 4 figure

Entanglement of identical particles and reference phase uncertainty

We have recently introduced a measure of the bipartite entanglement of identical particles, E_P, based on the principle that entanglement should be accessible for use as a resource in quantum information processing. We show here that particle entanglement is limited by the lack of a reference phase shared by the two parties, and that the entanglement is constrained to reference-phase invariant subspaces. The super-additivity of E_P results from the fact that this constraint is weaker for combined systems. A shared reference phase can only be established by transferring particles between the parties, that is, with additional nonlocal resources. We show how this nonlocal operation can increase the particle entanglement.Comment: 8 pages, no figures. Invited talk given at EQIS'03, Kyoto, September, 2003. Minor typos corrected, 1 reference adde

Dynamics of light propagation in spatiotemporal dielectric structures

Propagation, transmission and reflection properties of linearly polarized plane waves and arbitrarily short electromagnetic pulses in one-dimensional dispersionless dielectric media possessing an arbitrary space-time dependence of the refractive index are studied by using a two-component, highly symmetric version of Maxwell's equations. The use of any slow varying amplitude approximation is avoided. Transfer matrices of sharp nonstationary interfaces are calculated explicitly, together with the amplitudes of all secondary waves produced in the scattering. Time-varying multilayer structures and spatiotemporal lenses in various configurations are investigated analytically and numerically in a unified approach. Several new effects are reported, such as pulse compression, broadening and spectral manipulation of pulses by a spatiotemporal lens, and the closure of the forbidden frequency gaps with the subsequent opening of wavenumber bandgaps in a generalized Bragg reflector

A photochemical dehydrogenative strategy for aniline synthesis

Chemical reactions that reliably join two molecular fragments together (cross-couplings) are essential to the discovery and manufacture of pharmaceuticals and agrochemicals1,2. The introduction of amines onto functionalized aromatics at specific and pre-determined positions (ortho versus meta versus para) is currently achievable only in transition-metal-catalysed processes and requires halogen- or boron-containing substrates3-6. The introduction of these groups around the aromatic unit is dictated by the intrinsic reactivity profile of the method (electrophilic halogenation or C-H borylation) so selective targeting of all positions is often not possible. Here we report a non-canonical cross-coupling approach for the construction of anilines, exploiting saturated cyclohexanones as aryl electrophile surrogates. Condensation between amines and carbonyls, a process that frequently occurs in nature and is often used by (bio-)organic chemists7, enables a predetermined and site-selective carbon-nitrogen (C-N) bond formation, while a photoredox- and cobalt-based catalytic system progressively desaturates the cyclohexene ring en route to the aniline. Given that functionalized cyclohexanones are readily accessible with complete regiocontrol using the well established carbonyl reactivity, this approach bypasses some of the frequent selectivity issues of aromatic chemistry. We demonstrate the utility of this C-N coupling protocol by preparing commercial medicines and by the late-stage amination-aromatization of natural products, steroids and terpene feedstocks

Model for the spatio-temporal intermittency of the energy dissipation in turbulent flows

Modeling the intermittent behavior of turbulent energy dissipation processes both in space and time is often a relevant problem when dealing with phenomena occurring in high Reynolds number flows, especially in astrophysical and space fluids. In this paper, a dynamical model is proposed to describe the spatio-temporal intermittency of energy dissipation rate in a turbulent system. This is done by using a shell model to simulate the turbulent cascade and introducing some heuristic rules, partly inspired by the well known $p$-model, to construct a spatial structure of the energy dissipation rate. In order to validate the model and to study its spatially intermittency properties, a series of numerical simulations have been performed. These show that the level of spatial intermittency of the system can be simply tuned by varying a single parameter of the model and that scaling laws in agreement with those obtained from experiments on fully turbulent hydrodynamic flows can be recovered. It is finally suggested that the model could represent a useful tool to simulate the spatio-temporal intermittency of turbulent energy dissipation in those high Reynolds number astrophysical fluids where impulsive energy release processes can be associated to the dynamics of the turbulent cascade.Comment: 22 pages, 9 figure

Turbulence in the First Stars

We present preliminary results of 2-D simulations of the effects of turbulence in the mixing of Pair Instability Supenovae. We make use of the FLASH code to evolve initial 1-D models of post-bounce PISNe and seed turbulence in form of velocity perturbations. We identify the energetic and spatial scale for the turbulence to have mixing effects on the metal shells inside the star. Under the conditions we examine, we observe some mixing but the onion structure of the metal distribution is not disrupted

Environmental Impact of Dietary Choices: Role of the Mediterranean and Other Dietary Patterns in an Italian Cohort

Background: Current scientific literature suggests healthy dietary patterns may have less environmental impact than current consumption patterns, but most of the studies rely on theoretical modeling. The aim of this study was to assess the impact on resources (land, water, and energy) use and greenhouse gas (GHG) emissions of healthy dietary patterns in a sample of Italian adults. Methods: Participants (n = 1806) were recruited through random sampling in the city of Catania, southern Italy. Dietary consumption was assessed through a validated food frequency questionnaire (FFQ); dietary patterns were calculated through dietary scores. The specific environmental footprints of food item production/processing were obtained from various available life-cycle assessments; a sustainability score was created based on the impact of the four environmental components calculated. Results: The contribution of major food groups to the environmental footprint showed that animal products (dairy, egg, meat, and fish) represented more than half of the impact on GHG emissions and energy requirements; meat products were the stronger contributors to GHG emissions and water use, while dairy products to energy use, and cereals to land use. All patterns investigated, with the exception of the Dietary Approach to Stop Hypertension (DASH), were linearly associated with the sustainability score. Among the components, higher adherence to the Mediterranean diet and Alternate Diet Quality Index (AHEI) was associated with lower GHG emissions, dietary quality index-international (DQI-I) with land use, while Nordic diet with land and water use. Conclusions: In conclusion, the adoption of healthy dietary patterns involves less use of natural resources and GHG emissions, representing eco-friendlier options in Italian adults

Comparative Study on Anterior Cruciate Ligament Reconstruction: Determination of Isometric Points with and Without Navigation

OBJECTIVES: To compare the accuracy of tunnel placement and graft isometry for anterior cruciate ligament reconstruction performed using a computer-assisted navigation system (Orthopilot) and using traditional instruments. METHODS: The anterior cruciate ligament was removed intact from 36 pairs of human cadaver knees. From each pair, one knee was randomized to Group 1 (conventional) and the other to Group 2 (Orthopilot). An inelastic suture was then passed through the central points of the tibial and femoral tunnels. Neither of the tunnels was drilled. All knees were then dissected, and six parameters were obtained: distances from the tibial tunnel center to the 1) posterior cruciate ligament, 2) anterior horn of the lateral meniscus and 3) medial tibial spine; 4) distance from the femoral tunnel center to the posterior femoral cortex; 5) femoral tunnel coronal angle; and 6) variation of the distance from the femoral to the tibial tunnel with the knee extended and at 90 degrees of flexion. RESULTS: The variation of the distance from the femoral to the tibial tunnel during flexion and extension was smaller in the Orthopilot group (better isometry) compared to the conventional group. There were no statistical differences in any other parameters between the groups, and all tunnels were considered to be in satisfactory positions. DISCUSSION: The results obtained for anterior cruciate ligament reconstruction depend on precise isometric point positioning, and a navigation system is a precision tool that can assist surgeons in tunnel positioning. CONCLUSION: No differences in tunnel position were observed between the groups. Nonetheless, better isometry was achieved in the Orthopilot group than with conventional instruments

GRBs from the First Stars

We present an estimate of the Gamma Ray Bursts which should be expected from metal-free, elusive first generation of stars known as PopulationIII (PopIII). We derive the GRB rate from these stars from the Stellar Formation Rate obtained in several Reionization scenarios available in the literature. In all of the analyzed models we find that GRBs from PopIII are subdominant with respect to the ''standard'' (PopII) ones up to z {approx} 10