Perfluoroalkylated amphiphiles with a morpholinophosphate or a dimorpholinophosphate polar head group

Some previously synthesized (perfluoroalkyl)alkyldimorpholinophosphates, CnF2n+1CmH2mOP(O)-[N(CH2CH2)(2)O](2), were found remarkably to stabilize heat sterilizable water-in-fluorocarbon reverse emulsions and to have a strong proclivity to self-aggregate into microtubular assemblies when dispersed in water. This series has now been extended in order to allow structure-property relationships to be established and product optimization to be achieved. A new series of even more fluorophilic compounds consisting in bis[(perfluoroalkyl)alkyl]monomorpholinophosphates, (CnF2n+1CmH2mO)(2)P(O)N(CH2CH2)(2)O, was also synthesized. Preliminary surfactant activity and biocompatibility data are presented and compared to data obtained with non-fluorinated analogues

SYMPA, a dedicated instrument for Jovian Seismology. II. Real performance and first results

Context. Due to its great mass and its rapid formation, Jupiter has played a crucial role in shaping the Solar System. The knowledge of its internal structure would strongly constrain the solar system formation mechanism. Seismology is the most efficient way to probe directly the internal structure of giant planets. Aims. SYMPA is the first instrument dedicated to the observations of free oscillations of Jupiter. Principles and theoretical performance have been presented in paper I. This second paper describes the data processing method, the real instrumental performance and presents the first results of a Jovian observation run, lead in 2005 at Teide Observatory. Methods. SYMPA is a Fourier transform spectrometer which works at fixed optical path difference. It produces Doppler shift maps of the observed object. Velocity amplitude of Jupiter's oscillations is expected below 60 cm/s. Results Despite light technical defects, the instrument demonstrated to work correctly, being limited only by photon noise, after a careful analysis. A noise level of about 12 cm/s has been reached on a 10-night observation run, with 21 % duty cycle, which is 5 time better than previous similar observations. However, no signal from Jupiter is clearly highlighted.Comment: 13 pages, 26 figure

Dome C site testing: surface layer, free atmosphere seeing and isoplanatic angle statistics

This paper analyses 3.5 years of site testing data obtained at Dome C, Antarctica, based on measurements obtained with three DIMMs located at three different elevations. Basic statistics of the seeing and the isoplanatic angle are given, as well as the characteristic time of temporal fluctuations of these two parameters, which we found to around 30 minutes at 8 m. The 3 DIMMs are exploited as a profiler of the surface layer, and provide a robust estimation of its statistical properties. It appears to have a very sharp upper limit (less than 1 m). The fraction of time spent by each telescope above the top of the surface layer permits us to deduce a median height of between 23 m and 27 m. The comparison of the different data sets led us to infer the statistical properties of the free atmosphere seeing, with a median value of 0.36 arcsec. The C_n^2 profile inside the surface layer is also deduced from the seeing data obtained during the fraction of time spent by the 3 telescopes inside this turbulence. Statistically, the surface layer, except during the 3-month summer season, contributes to 95 percent of the total turbulence from the surface level, thus confirming the exceptional quality of the site above it

Studying the vertical extent of the ground layer turbulence using sonic-anemometers

The optical turbulence above Dome C in winter is mainly concentrated in the first tens of meters above the ground. The properties of this so-called surface layer were investigated during the last two winterover by a set of sonics anemometers placed on a 45 m high tower. These anemometers provide measurements of the temperature and the wind speed vector. The sampling rate of 10 Hz allows to derivate the refractive index structure constant C_n^2. We report here the first analysis of these data

Typical duration of good seeing sequences at Concordia

Context. The winter seeing at Concordia is bimodal, i.e. either excellent or quite poor, depending on the altitude above the snow surface. We study the temporal behavior of the good seeing sequences. Efficient exploitation of extremely good seeing conditions with an adaptive optics system requires long integrations. Aims. We examine the temporal distribution of time intervals providing excellent seeing at Concordia. Methods. We create temporal windows of good seeing by applying a simple binary process: good or bad. We correct the autocorrelations of these windows for those of the existing data sets, since these are not continuous, often being interrupted by technical problems in addition to the adverse weather gaps. We infer the typical duration of good seeing sequences from these corrected autocorrelations. This study has to be a little detailed as its results depend on the season, summer or winter. Results. When we adopt a threshold of 0.5 arcsec to define “good seeing”, we find that three characteristic numbers describe the temporal evolution of the good seeing windows. The first number is the mean duration of an uninterrupted good seeing sequence, which is τ0 = 7.5 h at 8 m above the ground and 15 h at 20 m. These sequences are randomly distributed in time, following a negative exponential law of damping time τ1 = 29 h (at elevation 8 m and 20 m), which represents our second number. The third number is the mean time between two 29 h episodes, which is T = 10 days at 8 m high (5 days at 20 m). Conclusions. There is certainly no other site on Earth, except for the few other high altitude Domes on the Antarctic plateau, at which we can achieve these exceptionally high quality seeing conditions

GIVRE: A Protection Against Frost Deposit on Polar Instruments

The CEA, in coordination with IPEV and LUAN, will prepare an experiment to study frost formation on surfaces in radiative cooling in the winter. This experiment has been shipped to be installed at Concordia before the 2007 winter period. It will be controlled from Concordia winterover personal, through PC server that will locally archive data from WEBcams and several local heat regulators. This experiment will be used to give recipes on the way to compensate with heaters the radiative cooling from the sky and maintain instrument surfaces at temperature just above icing conditions. The individual regulators proposed in this experiment will be usable as standalone ice protection systems for existing and future telescopes