Characterization by Electron Diffraction of Two Thermodynamical Phases of Precipitation in Nb-Microalloyed Steels

Excellent mechanical properties (high strength and toughness) of microalloyed steels are mainly caused by induced precipitation during thermomechanical treatment (TMT) and grain refinement. It has been recently found that TMT of Nb-microalloyed steels can give rise to two different kinds of precipitates, manifested by the double plateau in the statically recrystallised fraction (Xa) against time curves. This work presents an electron diffraction study performed in a transmission electron microscope, equipped with an EDS analytical system. Lattice parameters of a great deal of particles, smaller than 200 nm and with face cubic centred structure, have been measured. Frequency distribution of the values of lattice parameters shows that these are grouped in two sets whose mean values are close. Comparison of these values with those found in the literature for carbides, nitrides and carbonitrides usually present in microalloyed steels demonstrates that they are Nb carbonitrides with slight stoichiometric differences (NbCxNy).Peer reviewe

MICROSTRUCTURAL STUDIES FOR OPTIMIZATION OF HEAT TREATMENT IN COMPONENTS OF STEEL X38CrMoV5-1 SUBJECTED TO HIGH STRESSES

This material X38CrMoV5-1 is an alloyed steel used for hot working, with good toughness and high resistance to thermal shock. The presence of Cr, Mo and V gives this steel a high resistance to wear, keeping its hardness properties at high temperature. Cr and Mo delay softening annealing and inhibit the grain growth. The great resistance to high temperatures of this type of steels is related with an easy martensitic transformation. This transformation happens even at low cooling speeds. The properties of these types of martensitic steels result as a consequence of their complex microstructure that is obtained by an extremely controlled thermal treatment. Dilatometric testing was performed on continuous cooling from austenization temperature (1050ºC). This testing shows the high hardenability of this type of steels. ATD studies have been done to complement the dilatometric testing. After the previous results, it has been considered that the optimal treatment to get tough and tenacious structure, consists in submitting material to an annealing processing at 780ºC/1hour, followed by a quenching treatment at 1020ºC/1hour and finally cooling in oil with a double tempering at 580ºC/2 hours. This treatment provides the best properties that guarantee service with safety parts.Peer Reviewe

Paper-based chromatic toxicity bioassay by analysis of bacterial ferricyanide reduction

Water quality assessment requires a continuous and strict analysis of samples to guarantee compliance with established standards. Nowadays, the increasing number of pollutants and their synergistic effects lead to the development general toxicity bioassays capable to analyse water pollution as a whole. Current general toxicity methods, e.g. Microtox®, rely on long operation protocols, the use of complex and expensive instrumentation and sample pre-treatment, which should be transported to the laboratory for analysis. These requirements delay sample analysis and hence, the response to avoid an environmental catastrophe. In an attempt to solve it, a fast (15 min) and low-cost toxicity bioassay based on the chromatic changes associated to bacterial ferricyanide reduction is here presented. E. coli cells (used as model bacteria) were stably trapped on low-cost paper matrices (cellulose-based paper discs, PDs) and remained viable for long times (1 month at -20 °C). Apart from bacterial carrier, paper matrices also acted as a fluidic element, allowing fluid management without the need of external pumps. Bioassay evaluation was performed using copper as model toxic agent. Chromatic changes associated to bacterial ferricyanide reduction were determined by three different transduction methods, i.e. (i) optical reflectometry (as reference method), (ii) image analysis and (iii) visual inspection. In all cases, bioassay results (in terms of half maximal effective concentrations, EC50) were in agreement with already reported data, confirming the good performance of the bioassay. The validation of the bioassay was performed by analysis of real samples from natural sources, which were analysed and compared with a reference method (i.e. Microtox). Obtained results showed agreement for about 70% of toxic samples and 80% of non-toxic samples, which may validate the use of this simple and quick protocol in the determination of general toxicity. The minimum instrumentation requirements and the simplicity of the bioassay open the possibility of in-situ water toxicity assessment with a fast and low-cost protocolPostprint (author's final draft

TPM Maintenance Management Model Focused on Reliability that Enables the Increase of the Availability of Heavy Equipment in the Construction Sector

The purpose of this paper is to present a maintenance study focused on total productive maintenance (TPM) and reliability-centered maintenance (RCM). Its approach is based on the first pillars of TPM, preventive and autonomous maintenance, as well as the FMEA analysis of RCM for maintenance analysis, which was conducted in this study. The implementation of TPM was successful in that various preventive maintenance (PM) policies assigned to the assets were implemented and it was demonstrated that TPM application in the construction industry could reduce the excessive accumulation of maintenance with the same effective optimization, and with support from RCM analysis and its heavy equipment systems analysis. Excessive corrective maintenance accounts for high investment and delay rates in work times of the assigned project. Traditional methods of availability guarantee, such as reactive or routine maintenance, are insufficient to satisfy a heavy equipment maintenance plan; therefore, what is called for is the systematic application of RCM and TMP because they allow the selection and application of effective PM tasks. An approach that develops and thoroughly analyzes the strategies of continuous corrective and PM is used with an atmosphere of uncertainty and with operational data limited by criticism. Results show a 90% improvement in availability.Revisión por pare

Evolution of the Density of States Gap in a Disordered Superconductor

It has only recently been possible to study the superconducting state in the attractive Hubbard Hamiltonian via a direct observation of the formation of a gap in the density of states N(w). Here we determine the effect of random chemical potentials on N(w) and show that at weak coupling, disorder closes the gap concurrently with the destruction of superconductivity. At larger, but still intermediate coupling, a pseudo-gap in N(w) remains even well beyond the point at which off-diagonal long range order vanishes. This change in the elementary excitations of the insulating phase corresponds to a crossover between Fermi- and Bose-Insulators. These calculations represent the first computation of the density of states in a finite dimensional disordered fermion model via the Quantum Monte Carlo and maximum entropy methods.Comment: 4 pages, 4 figure

Model for initiation of quality factor degradation at high accelerating fields in superconducting radio-frequency cavities

A model for the onset of the reduction in SRF cavity quality factor, the so-called Q-drop, at high accelerating electric fields is presented. Breakdown of the surface barrier against magnetic flux penetration at the cavity equator is considered to be the critical event that determines the onset of Q-drop. The worst case of triangular grooves with low field of first flux penetration Hp, as analyzed previously by Buzdin and Daumens, [1998 Physica C 294: 257], was adapted. This approach incorporates both the geometry of the groove and local contamination via the Ginzburg-Landau parameter kappa, so the proposed model allows new comparisons of one effect in relation to the other. The model predicts equivalent reduction of Hp when either roughness or contamination were varied alone, so smooth but dirty surfaces limit cavity performance about as much as rough but clean surfaces do. When in combination, contamination exacerbates the negative effects of roughness and vice-versa. To test the model with actual data, coupons were prepared by buffered chemical polishing and electropolishing, and stylus profilometry was used to obtain distributions of angles. From these data, curves for surface resistance generated by simple flux flow as a function of magnetic field were generated by integrating over the distribution of angles for reasonable values of kappa. This showed that combined effects of roughness and contamination indeed reduce the Q-drop onset field by ~30%, and that that contamination contributes to Q-drop as much as roughness. The latter point may be overlooked by SRF cavity research, since access to the cavity interior by spectroscopy tools is very difficult, whereas optical images have become commonplace. The model was extended to fit cavity test data, which indicated that reduction of the superconducting gap by contaminants may also play a role in Q-drop.Comment: 15 pages with 7 figure

Quantum superconductor-metal transition

We consider a system of superconducting grains embedded in a normal metal. At zero temperature this system exhibits a quantum superconductor-normal metal phase transition. This transition can take place at arbitrarily large conductance of the normal metal.Comment: 13 pages, 1 figure include

The Superconductor-Insulator Transition in a Tunable Dissipative Environment

We study the influence of a tunable dissipative environment on the dynamics of Josephson junction arrays near the superconductor-insulator transition. The experimental realization of the environment is a two dimensional electron gas coupled capacitively to the array. This setup allows for the well-controlled tuning of the dissipation by changing the resistance of the two dimensional electron gas. The capacitive coupling cuts off the dissipation at low frequencies. We determine the phase diagram and calculate the temperature and dissipation dependence of the array conductivity. We find good agreement with recent experimental results.Comment: 4 pages, 4 .eps figures, revte

Suppression of \bbox{T_c} in superconducting amorphous wires

The suppression of the mean field temperature of the superconducting transition, $T_c$, in homogeneous amorphous wires is studied. We develop a theory that gives $T_c$ in situations when the dynamically enhanced Coulomb repulsion competes with the contact attraction. The theory accurately describes recent experiments on $T_c$--suppression in superconducting wires, after a procedure that minimizes the role of nonuniversal mechanisms influencing $T_c$ is applied.Comment: RevTeX, 4 pages, 3 figure