Integrating process and factor understanding of environmental innovation by water utilities

Innovations in technology and organisations are central to enabling the water sector to adapt to major environmental changes such as climate change, land degradation or drinking water pollution. While there are literatures on innovation as a process and on the factors that influence it, there is little research that integrates these. Development of such an integrated understanding of innovation is central to understanding how policy makers and organisations can stimulate and direct environmental innovation. In the research reported here a framework is developed that enables such an integrated analysis of innovation process and factors. From research interviews and the literature twenty factors were identified that affect the five stages of the environmental innovation process in English and Welsh water utilities. The environmental innovations investigated are measures taken by water utilities to reduce or prevent pollution in drinking water catchments rather than technical measures to treat water. These Source Control Interventions are similar to other environmental innovations, such as ecosystem and species conservation, in that they emphasise the mix of technology, management and engagement with multiple actors. Results show that in water utilities direct performance regulation and regulation that raises awareness of a ‘performance’ gap as a ‘problem’ can stimulate innovation, but only under particular organisational, natural physical and regulatory conditions. The integrated framework also suggests that while flexible or framework legislation (e.g. Water Framework Directive) does not stimulate innovation in itself, it has shaped the option spaces and characteristics of innovations selected towards source control instead of technical end-of-pipe solutions

Improved magnetic charged system search optimization algorithm with application to satellite formation flying

This paper is devoted to the implementation and application of an improved version of the metaheuristic algorithm called magnetic charged system search. Some modifications and novelties are introduced and tested. Firstly, the authors’ attempt is to develop a self-adaptive and user-friendly algorithm which can automatically set all the preliminary parameters (such as the numbers of particles, the maximum iterations number) and the internal coefficients. Indeed, some mathematical laws are proposed to set the parameters and many coefficients can dynamically change during the optimization process based on the verification of internal conditions. Secondly, some strategies are suggested to enhance the performances of the proposed algorithm. A chaotic local search is introduced to improve the global best particle of each iteration by exploiting the features of ergodicity and randomness. Moreover, a novel technique is proposed to handle bad-defined boundaries; in fact, the possibility to self-enlarge the boundaries of the optimization variables is considered, allowing to achieve the global optimum even if it is located on the boundaries or outside. The algorithm is tested through some benchmark functions and engineering design problems, showing good results, followed by an application regarding the problem of time-suboptimal manoeuvres for satellite formation flying, where the inverse dynamics technique, together with the B-splines, is employed. This analysis proves the ability of the proposed algorithm to optimize control problems related to space engineering, obtaining better results with respect to more common and used algorithms in literature

Carbon Monoxide Binding to the Iron–Molybdenum Cofactor of Nitrogenase: a Detailed Quantum Mechanics/Molecular Mechanics Investigation

Carbon monoxide (CO) is a well-known inhibitor of nitrogenase activity. Under turnover conditions, CO binds to FeMoco, the active site of Mo nitrogenase. Time-resolved IR measurements suggest an initial terminal CO at 1904 cm–1 that converts to a bridging CO at 1715 cm–1, and an X-ray structure shows that CO can displace one of the bridging belt sulfides of FeMoco. However, the CO-binding redox state(s) of FeMoco (En) and the role of the protein environment in stabilizing specific CO-bound intermediates remain elusive. In this work, we carry out an in-depth analysis of the CO–FeMoco interaction based on quantum chemical calculations addressing different aspects of the electronic structure. (1) The local electronic structure of the Fe–CO bond is studied through diamagnetically substituted FeMoco. (2) A cluster model of FeMoco within a polarizable continuum illustrates how CO binding may affect the spin-coupling between the metal centers. (3) A QM/MM model incorporates the explicit influence of the amino acid residues surrounding FeMoco in the MoFe protein. The QM/MM model predicts both a terminal and a bridging CO in the E1 redox state. The scaled calculated CO frequencies (1922 and 1716 cm–1, respectively) are in good agreement with the experimentally observed IR bands supporting CO binding to the E1 state. Alternatively, an E2 state QM/MM model, which has the same atomic structure as the CO-bound X-ray structure, features a semi-bridging CO with a scaled calculated frequency (1718 cm–1) similar to the bridging CO in the E1 model

The possibilities for mobile and fixed services up to the 20/30 GHz frequency bands

Satellite Communications and broadcasting is presently in a period of considerable change. In the fixed service there is strong competition from terrestrial fiber optic systems which have virtually arrested the growth of the traditional satellite market for long distance high capacity communications. The satellite has however made considerable progress in areas where it has unique advantages; for example, in point to multipoint (broadcasting), multipoint to point (data collection) and generally in small terminal system applications where flexibility of deployment coupled with ease of installation are of importance. In the mobile service, in addition to the already established geostationary systems, there are numerous proposals for HEO, MEO and LEO systems. There are also several new frequency allocations as a result of the WARC 92 to be taken into account. At one extreme there are researchers working on Ka band 20/30 GHz mobile systems and there are other groups who foresee no future above the L-band frequency allocations. Amongst all these inputs it is difficult to see the direction in which development activities both for satellites and for earth segment should be focused. However, as an aid to understanding, this paper seeks to find some underlying relationships and to clarify some of the variables

Entanglement of superconducting charge qubits by homodyne measurement

We present a scheme by which projective homodyne measurement of a microwave resonator can be used to generate entanglement between two superconducting charge qubits coupled to this resonator. The non-interacting qubits are initialised in a product of their ground states, the resonator is initialised in a coherent field state, and the state of the system is allowed to evolve under a rotating wave Hamiltonian. Making a homodyne measurement on the resonator at a given time projects the qubits into an state of the form (|gg> + exp(-i phi)|ee>)/sqrt(2). This protocol can produce states with a fidelity as high as required, with a probability approaching 0.5. Although the system described is one that can be used to display revival in the qubit oscillations, we show that the entanglement procedure works at much shorter timescales.Comment: 17 pages, 7 figure

Entanglement generation in persistent current qubits

In this paper we investigate the generation of entanglement between two persistent current qubits. The qubits are coupled inductively to each other and to a common bias field, which is used to control the qubit behaviour and is represented schematically by a linear oscillator mode. We consider the use of classical and quantum representations for the qubit control fields and how fluctuations in the control fields tend to suppress entanglement. In particular, we demonstrate how fluctuations in the bias fields affect the entanglement generated between persistent current qubits and may limit the ability to design practical systems.Comment: 7 pages, 4 figures, minor changes in reply to referees comment