321 research outputs found
The molecular size continuum of soil organic phosphorus and its chemical associations
The chemical nature of most organic P (Porg) in soil remains âunresolvedâ but is accounted for by a broad signal in the phosphomonoester region of solution 31P nuclear magnetic resonance (NMR) spectra. The molecular size range of this broad NMR signal and its molecular structure remain unclear. The aim of this study was to elucidate the chemical nature of Porg with increasing molecular size in soil extracts combining size exclusion chromatography (SEC) with solution 31P NMR spectroscopy. Gel-filtration SEC was carried out on NaOH-EDTA extracts of four soils (range 238-1135 mg Porg/kgsoil) to collect fractions with molecular sizes of 70 kDa. These were then analysed by NMR spectroscopy.
Organic P was detected across the entire molecular size continuum from 70 kDa. Concentrations of Porg in the >10kDa fraction ranged from 107 to 427 mg P/kgsoil and exhibited on average three to four broad signals in the phosphomonoester region of NMR spectra. These broad signals were most prominent in the 10-20 and 20-50 kDa fractions, accounting for on average 77 % and 74 % of total phosphomonoesters, respectively. Our study demonstrates that the broad signal is present in all investigated molecular size fractions and comprises on average three to four components of varying NMR peak line width (20 to 250 Hz).
The stereoisomers myo- and scyllo-inositol hexakisphosphates (IP6) were also present across multiple molecular size ranges but were predominant in the 5-10 kDa fraction. The proportion of IP associated with large molecular size fractions >10 kDa was on average 23 % (SD=39 %) of total IP across all soils. These findings suggest that stabilisation of IP in soil includes processes associated with the organic phase
WIMPs search by scintillators: possible strategy for annual modulation search with large-mass highly-radiopure NaI(Tl)
The DAMA experiments are running deep underground in the Gran Sasso National
Laboratory. Several interesting results have been achieved so far. Here a
maximum likelihood method to search for the WIMP annual modulation signature is
discussed and applied to a set of preliminary test data collected with large
mass highly radiopure NaI(Tl) detectors. Various related technical arguments
are briefly addressed.Comment: 6 pages, 4 figures, LaTex. Contributed paper to TAUP97; to appear in
the Proceeding
The effect of culture preservation techniques on patulin and citrinin production by Penicillium expansum Link
Aims: To study the influence of culture preservation methods and culture conditions on the
production of the mycotoxins patulin and citrinin by Penicillium expansum.
Methods and results: Ten strains of Penicillium expansum were preserved using subculture
and maintenance at 4 ÂșC, mineral oil, drying on silica gel and freeze-drying. Patulin and
citrinin production was assessed on yeast extract sucrose agar (YES) and grape juice agar (GJ),
using TLC before and after 0.5, 2â3, 6 and 12 months preservation. Citrinin was detected in all
cultures for all preservation techniques on YES. The patulin profiles obtained differed with
strain and culture media used.
Conclusions: Citrinin production seems to be a stable character for the tested strains. There is
a tendency for patulin detection with time apparently more consistent for silica gel storage and
freeze-drying, especially when the strains are grown on GJ.
Significance and Impact of the Study: Variability in the profiles of the mycotoxins tested
seems to be more strain-specific than dependent on the preservation technique used
New limits on dark--matter WIMPs from the Heidelberg--Moscow experiment
New results after 0.69 kg yr of measurement with an enriched 76Ge detector of
the Heidelberg--Moscow experiment with an active mass of 2.758 kg are
presented. An energy threshold of 9 keV and a background level of 0.042
counts/(kg d keV) in the energy region between 15 keV and 40 keV was
reached.The derived limits on the WIMP--nucleon cross section are the most
stringent limits on spin--independent interactions obtained to date by using
essentially raw data without background subtraction.Comment: 8 pages (latex) including 5 postscript figures and 2 tables. To
appear in Phys. Rev. D, 15. December 199
Search for an annual modulation of dark-matter signals with a germanium spectrometer at the Sierra Grande Laboratory
Data collected during three years with a germanium spectrometer at the Sierra
Grande underground laboratory have been analyzed for distinctive features of
annual modulation of the signal induced by WIMP dark matter candidates. The
main motivation for this analysis was the recent suggestion by the DAMA/NaI
Collaboration that a yearly modulation signal could not be rejected at the 90%
confidence level when analyzing data obtained with a high-mass low-background
scintillator detector. We performed two different analyses of the data: First,
the statistical distribution of modulation-significance variables (expected
from an experiment running under the conditions of Sierra Grande) was compared
with the same variables obtained from the data. Second, the data were analyzed
in energy bins as an independent check of the first result and to allow for the
possibility of a crossover in the expected signal. In both cases no
statistically significant deviation from the null result was found, which could
support the hypothesis that the data contain a modulated component. A plot is
also presented to enable the comparison of these results to those of the DAMA
collaboration.Comment: New version accepted by Astroparticle Physics. Changes suggested by
the referee about the theoretical prediction of rates are included.
Conclusions remain unaffected. 14 pages, LaTeX, 7 figures. Uses epsfig macr
First Results of the EDELWEISS WIMP Search using a 320 g Heat-and-Ionization Ge Detector
The EDELWEISS collaboration has performed a direct search for WIMP dark
matter using a 320 g heat-and-ionization cryogenic Ge detector operated in a
low-background environment in the Laboratoire Souterrain de Modane. No nuclear
recoils are observed in the fiducial volume in the 30-200 keV energy range
during an effective exposure of 4.53 kg.days. Limits for the cross-section for
the spin-independent interaction of WIMPs and nucleons are set in the framework
of the Minimal Supersymmetric Standard Model (MSSM). The central value of the
signal reported by the experiment DAMA is excluded at 90% CL.Comment: 14 pages, Latex, 4 figures. Submitted to Phys. Lett.
Particle Dark Matter Physics: An Update
This write--up gives a rather elementary introduction into particle physics
aspects of the cosmological Dark Matter puzzle. A fairly comprehensive list of
possible candidates is given; in each case the production mechanism and
possible ways to detect them (if any) are described. I then describe detection
of the in my view most promising candidates, weakly interacting massive
particles or WIMPs, in slightly more detail. The main emphasis will be on
recent developments.Comment: Invited talk at the 5th Workshop on Particle Physics Phenomenology,
Pune, India, January 1998; 21 pages, LaTeX with equation.st
Identification of Purported Agaricus campestris Strains (NRRL 2334, 2335, 2336) as Beauveria tenella (Delacroix Siem.)
Comparison of two methods used for monitoring low-copy cytomegalovirus infection in a patient with chronic myeloid leukemia after unrelated umbilical cord blood transplantation
Effects of galactic dark halo rotation on WIMP direct detection
The effects of a possible rotation of the galactic dark halo on the
calculation of the direct detection rates for particle dark matter are
analyzed, with special attention to the extraction of the upper limits on the
WIMP--nucleon scalar cross section from the experimental data. We employ a
model of dark halo rotation which describes the maximal possible effects. For
WIMP masses above 50 GeV, the upper limit exclusion plot is modified by less
than a factor of two when rotation is included. For lighter masses the effect
can be stronger, suggesting the necessity to develop specific models of halo
rotation in order to provide more accurate conclusions.Comment: 14 pages, 7 figures included as PS file
- âŠ