The role of contacts in molecular electronics

Molecular electronic devices are the upmost destiny of the miniaturization trend of electronic components. Although not yet reproducible on large scale, molecular devices are since recently subject of intense studies both experimentally and theoretically, which agree in pointing out the extreme sensitivity of such devices on the nature and quality of the contacts. This chapter intends to provide a general theoretical framework for modelling electronic transport at the molecular scale by describing the implementation of a hybrid method based on Green function theory and density functional algorithms. In order to show the presence of contact-dependent features in the molecular conductance, we discuss three archetypal molecular devices, which are intended to focus on the importance of the different sub-parts of a molecular two-terminal setup.Comment: 17 pages, 8 figure

Innermost Stable Circular Orbits and Epicyclic Frequencies Around a Magnetized Neutron Star

A full-relativistic approach is used to compute the radius of the innermost stable circular orbit (ISCO), the Keplerian, frame-dragging, precession and oscillation frequencies of the radial and vertical motions of neutral test particles orbiting the equatorial plane of a magnetized neutron star. The space-time around the star is modelled by the six parametric solution derived by Pachon et al. It is shown that the inclusion of an intense magnetic field, such as the one of a neutron star, have non-negligible effects on the above physical quantities, and therefore, its inclusion is necessary in order to obtain a more accurate and realistic description of the physical processes occurring in the neighbourhood of this kind of objects such as the dynamics of accretion disk. The results discussed here also suggest that the consideration of strong magnetic fields may introduce non-negligible corrections in, e.g., the relativistic precession model and therefore on the predictions made on the mass of neutron stars.Comment: LaTeX file, 13 pages, 4 figure

Ethics In Information Systems: Student Performance In Evaluating Ethical Dilemmas

The explosion in information technology in the last 20 years, and in particular, data communications networks, has had a major impact on ethical thinking and ethical issues. This has been manifested in the recent accounting and business scandals, as it is becoming apparent that the ethical dimensions of information systems-related business decisions cannot be safely ignored. It is important for business educators to introduce students to relevant ethical situations that they may face in the business world. This paper discusses the Information Systems ethical environment and students performance on business ethics cases in a telecommunications course. The results of this evaluation show that more exposure to ethical situations is needed, as students are not prepared to make sound ethical judgements

Fermion mass hierarchy and non-hierarchical mass ratios in SU(5) x U(1)_F

We consider a SU(5) x U(1)_F GUT-flavor model in which the number of effects that determine the charged fermions Yukawa matrices is much larger than the number of observables, resulting in a hierarchical fermion spectrum with no particular regularities. The GUT-flavor symmetry is broken by flavons in the adjoint of SU(5), realizing a variant of the Froggatt-Nielsen mechanism that gives rise to a large number of effective operators. By assuming a common mass for the heavy fields and universality of the fundamental Yukawa couplings, we reduce the number of free parameters to one. The observed fermion mass spectrum is reproduced thanks to selection rules that discriminate among various contributions. Bottom-tau Yukawa unification is preserved at leading order, but there is no unification for the first two families. Interestingly, U(1)_F charges alone do not determine the hierarchy, and can only give upper bounds on the parametric suppression of the Yukawa operators.Comment: 14 pages, one figure. Few typos correcte

Bias-dependent Contact Resistance in Rubrene Single-Crystal Field-Effect Transistors

We report a systematic study of the bias-dependent contact resistance in rubrene single-crystal field-effect transistors with Ni, Co, Cu, Au, and Pt electrodes. We show that the reproducibility in the values of contact resistance strongly depends on the metal, ranging from a factor of two for Ni to more than three orders of magnitude for Au. Surprisingly, FETs with Ni, Co, and Cu contacts exhibits an unexpected reproducibility of the bias-dependent differential conductance of the contacts, once this has been normalized to the value measured at zero bias. This reproducibility may enable the study of microscopic carrier injection processes into organic semiconductors.Comment: 4 pages, 4 figure