Hydrological change: reaping prosperity and pain in Australia

International audienceThe adage: "There is no such thing as a free lunch?, is relevant to land-use hydrology in Australia. Changes in land use to achieve greater productivity of food and fibre may have an adverse effect on the water balance and hence on the natural resource capital of a catchment. An altered regime of catchment outflow accompanies those land-use changes which, together with land degradation, impairs available water resources in quantity and quality and threatens enterprise sustainability, notwithstanding the initial improvement in productivity. Central to any hydrological change is an altered pattern of seasonal and annual water use by vegetation that has become modified in function with an amended transpiration fraction of daily evapotranspiration. In Australia, since measurement of evapotranspiration became feasible, the hydrological consequences of changes in land use have been determined, allowing the benefits in terms of plant productivity achieved through enhanced water use efficiency to be weighed against changed catchment outflows, diminished in either quantity or quality. Four case studies are presented as examples of ecological and hydrological changes: two deal with the upland forest environment and two with arable lowlands. In an upland eucalypt forest, following wildfire with subsequent regeneration from natural seedling establishment, substantial reduction in water yield occurred throughout a 50-year period of succession in the even-aged stand. In comparison, the effect of converting eucalypt forest to pine plantations was less detrimental to the yield of water from the catchments, with substantial growth increases over 30 years. In the lowlands, agricultural productivity, both as annual pasture and as crop, far exceeds that of natural perennial grassland and woodland. This increase in productivity comes not so much from any change to the yield of total water outflow but at the expense of water quality, compromised with increased material transport in suspension and solution resulting from accelerated erosion in association with outbreaks of soil salinity and acidity. The present study is aimed at optimising management to give plant production outcomes that ensure environmental protection through resource conservation. In the uplands, harvesting of water is the dominant consideration so that conservative management with limited plant productivity is sought. In the lowlands, the objective is to devise novel ecosystems with profitable plant production that exercises due control on outflow in maintaining the chemical and physical integrity of the edaphic environment

Wigner Distribution Deconvolution Adaptation for Live Ptychography Reconstruction

We propose a modification of Wigner Distribution Deconvolution (WDD) to support live processing ptychography. Live processing allows to reconstruct and display the specimen transfer function gradually while diffraction patterns are acquired. For this purpose we reformulate WDD and apply a dimensionality reduction technique that reduces memory consumption and increases processing speed. We show numerically that this approach maintains the reconstruction quality of specimen transfer functions as well as reduces computational complexity during acquisition processes. Although we only present the reconstruction for Scanning Transmission Electron Microscopy (STEM) datasets, in general, the live processing algorithm we present in this paper can be applied to real-time ptychographic reconstruction for different fields of application

Structural, chemical and magnetic properties of secondary phases in Co-doped ZnO

We have utilized a comprehensive set of experimental techniques such as transmission electron microscopy (TEM) and synchrotron-based x-ray absorption spectroscopy (XAS) and the respective x-ray linear dichroism and x-ray magnetic circular dichroism to characterize the correlation of structural, chemical and magnetic properties of Co-doped ZnO samples. It can be established on a quantitative basis that the superparamagnetic (SPM) behavior observed by integral superconducting quantum interference device magnetometry is not an intrinsic property of the material but stems from precipitations of metallic Co. Their presence is revealed by TEM as well as XAS. Annealing procedures for these SPM samples were also studied, and the observed changes in the magnetic properties found to be due to a chemical reduction or oxidation of the metallic Co species

Dynamic study of carbon nanotube growth and catalyst morphology evolution during acetylene decomposition on Co/SBA-15 in an environmental TEM

International @ SURFACES+FCA:MAO:ATUInternational audienceNon

A composite double-/single-stranded RNA-binding region in protein Prp3 supports tri-snRNP stability and splicing

Prp3 is an essential U4/U6 di-snRNP-associated protein whose functions and molecular mechanisms in pre-mRNA splicing are presently poorly understood. We show by structural and biochemical analyses that Prp3 contains a bipartite U4/U6 di-snRNA-binding region comprising an expanded ferredoxin-like fold, which recognizes a 3′-overhang of U6 snRNA, and a preceding peptide, which binds U4/U6 stem II. Phylogenetic analyses revealed that the single-stranded RNA-binding domain is exclusively found in Prp3 orthologs, thus qualifying as a spliceosome-specific RNA interaction module. The composite double-stranded /single-stranded RNA-binding region assembles cooperatively with Snu13 and Prp31 on U4/U6 di-snRNAs and inhibits Brr2-mediated U4/U6 di-snRNA unwinding in vitro. RNP-disrupting mutations in Prp3 lead to U4/U6•U5 tri-snRNP assembly and splicing defects in vivo. Our results reveal how Prp3 acts as an important bridge between U4/U6 and U5 in the tri-snRNP and comparison with a Prp24-U6 snRNA recycling complex suggests how Prp3 may be involved in U4/U6 reassembly after splicing

A realisation of Lorentz algebra in Lorentz violating theory

A Lorentz non-invariant higher derivative effective action in flat spacetime, characterised by a constant vector, can be made invariant under infinitesimal Lorentz transformations by restricting the allowed field configurations. These restricted fields are defined as functions of the background vector in such a way that background dependance of the dynamics of the physical system is no longer manifest. We show here that they also provide a field basis for the realisation of Lorentz algebra and allow the construction of a Poincar\'e invariant symplectic two form on the covariant phase space of the theory.Comment: text body edited, reference adde

The impact of trench defects in InGaN/GaN light emitting diodes and implications for the "green gap" problem

The impact of trench defects in blue InGaN/GaN light emitting diodes (LEDs) has been investigated. Two mechanisms responsible for the structural degradation of the multiple quantum well (MQW) active region were identified. It was found that during the growth of the p-type GaN capping layer, loss of part of the active region enclosed within a trench defect occurred, affecting the top-most QWs in the MQW stack. Indium platelets and voids were also found to form preferentially at the bottom of the MQW stack. The presence of high densities of trench defects in the LEDs was found to relate to a significant reduction in photoluminescence and electroluminescence emission efficiency, for a range of excitation power densities and drive currents. This reduction in emission efficiency was attributed to an increase in the density of non-radiative recombination centres within the MQW stack, believed to be associated with the stacking mismatch boundaries which form part of the sub-surface structure of the trench defects. Investigation of the surface of green-emitting QW structures found a two decade increase in the density of trench defects, compared to its blue-emitting counterpart, suggesting that the efficiency of green-emitting LEDs may be strongly affected by the presence of these defects. Our results are therefore consistent with a model that the “green gap” problem might relate to localized strain relaxation occurring through defects.This is the accepted manuscript version. The final version is available from AIP at http://scitation.aip.org/content/aip/journal/apl/105/11/10.1063/1.4896279?showFTTab=true&containerItemId=content/aip/journal/apl

Efficient large field of view electron phase imaging using near-field electron ptychography with a diffuser

Most implementations of ptychography on the electron microscope operate in scanning transmission (STEM) mode, where a small focussed probe beam is rapidly scanned across the sample. In this paper we introduce a different approach based on near-field ptychography, where the focussed beam is replaced by a wide-field, structured illumination, realised through a purpose-designed etched Silicon Nitride window. We show that fields of view as large as 100 μm2 can be imaged using the new approach, and that quantitative electron phase images can be reconstructed from as few as nine near-field diffraction pattern measurements

Correlation between magnetic spin structure and the three-dimensional geometry in chemically synthesized nanoscale magnetite rings

The correlation between magnetic spin structure and geometry in nanoscale chemically synthesized Fe(3)O(4) rings has been investigated by transmission electron microscopy. We find primarily the flux closure vortex states but in rings with thickness variations, an effective stray field occurs. Using tomography, we determine the complete three-dimensional geometries of thicker rings. A direct correlation between the geometry and the magnetization which points out of plane in the thickest parts of the ring yielding an intermediate magnetic state between the vortex state and the tube state is found. The interaction between exchange coupled rings leads to antiparallel vortex states and extended onion states. (c) 2008 American Institute of Physics.Physics, AppliedSCI(E)EI2ARTICLE22null9