648 research outputs found
Correlation length of hydrophobic polyelectrolyte solutions
The combination of two techniques (Small Angle X-ray Scattering and Atomic
Force Microscopy) has allowed us to measure in reciprocal and real space the
correlation length of salt-free aqueous solutions of highly charged
hydrophobic polyelectrolyte as a function of the polymer concentration ,
charge fraction and chain length . Contrary to the classical behaviour
of hydrophilic polyelectrolytes in the strong coupling limit, is strongly
dependent on . In particular a continuous transition has been observed from
to when decreased from 100% to
35%. We interpret this unusual behaviour as the consequence of the two features
characterising the hydrophobic polyelectrolytes: the pearl necklace
conformation of the chains and the anomalously strong reduction of the
effective charge fraction.Comment: 7 pages, 5 figures, submitted to Europhysics Letter
Nonperturbative renormalization group approach to Lifshitz critical behaviour
The behaviour of a d-dimensional vectorial N=3 model at a m-axial Lifshitz
critical point is investigated by means of a nonperturbative renormalization
group approach that is free of the huge technical difficulties that plague the
perturbative approaches and limit their computations to the lowest orders. In
particular being systematically improvable, our approach allows us to control
the convergence of successive approximations and thus to get reliable physical
quantities in d=3.Comment: 6 pages, 3 figure
Joint Learning of Pre-Trained and Random Units for Domain Adaptation in Part-of-Speech Tagging
Fine-tuning neural networks is widely used to transfer valuable knowledge
from high-resource to low-resource domains. In a standard fine-tuning scheme,
source and target problems are trained using the same architecture. Although
capable of adapting to new domains, pre-trained units struggle with learning
uncommon target-specific patterns. In this paper, we propose to augment the
target-network with normalised, weighted and randomly initialised units that
beget a better adaptation while maintaining the valuable source knowledge. Our
experiments on POS tagging of social media texts (Tweets domain) demonstrate
that our method achieves state-of-the-art performances on 3 commonly used
datasets
A glassy phase in quenched disordered graphene and crystalline membranes
We investigate the flat phase of -dimensional crystalline membranes
embedded in a -dimensional space and submitted to both metric and curvature
quenched disorders using a nonperturbative renormalization group approach. We
identify a second order phase transition controlled by a finite-temperature,
finite-disorder fixed point unreachable within the leading order of
and expansions. This critical point divides the flow
diagram into two basins of attraction: that associated to the
finite-temperature fixed point controlling the long distance behaviour of
disorder-free membranes and that associated to the zero-temperature,
finite-disorder fixed point. Our work thus strongly suggests the existence of a
whole low-temperature glassy phase for quenched disordered graphene,
graphene-like compounds and, more generally, crystalline membranes.Comment: 6 pages, 1 figur
Hydrophobic Polyelectrolytes in Better Polar Solvent. Structure and Chain Conformation as seen by Saxs and Sans
We demonstrate in this paper the influence of solvent quality on the
structure of the semi-dilute solution of a hydrophobic polyelectrolyte,
partially sulfonated Poly-Styrene Sulfonate. Two solvents are used: (i) one
mixture of water and an organic solvent: THF, which is also slightly polar;
(ii) DMSO, a polar organic solvent. In case (i), it is shown by SAXS study that
the structure - namely the scattering from all chains, characterised by a
maximum ("polyelectrolyte peak"), of the aqueous hydrophobic polyelectrolyte
solutions (PSS) depends on the solvent quality through the added amount of
organic solvent THF. This dependence is more pronounced when the sulfonation
rate is low (more hydrophobic polyelectrolyte). It is proposed that when THF is
added, the chain conformation evolves from the pearl necklace shape already
reported in pure water, towards the conformation in pure water for fully
sulfonated PSS, which is string-like as also reported previously. On the
contrary, for a hydrophilic polyelectrolyte, AMAMPS, no evolution occurs with
added THF in the aqueous solution. In case (ii), it is shown directly by SANS
study that PSS can behave as a classical solvophilic polyelectrolyte when
dissolved in an organic polar solvent such as DMSO: the structure (total
scattering) as well as the form factor (single chain scattering measured by
SANS using the Zero Average Contrast method) of the PSS chains is independent
of the charge content in agreement with Manning condensation, and identical to
the one of a fully charged PSS chain in pure water, which has a classical
polyelectrolyte behaviour in the semi-dilute regime
Adaptive parameters adjustment in WBAN to mitigate Wi-Fi interferences
Wireless Body Area Network (WBAN), called also Wireless Body Sensor Network (WBSN), is composed of a set of tiny wireless devices (sensors) attached, implanted or ingested into the body. It offers real time and ubiquitous applications thanks to the small form, the lightness, and the wireless interface of sensors. WBAN performance is expected to be considerably degraded in the presence of Wi-Fi networks. Their operating channels overlap in the 2.4 GHz Industrial Scientific and Medical (ISM) band which produces interference when they transmit data, accompanied by data losses and quick battery exhaustion. Therefore, it is crucial to mitigate the interference between WBAN and Wi-Fi networks in order to maintain the efficiency and the reliability of the WBAN system. Proposals in the literature use an added complex hardware in WBAN system, or perform the exchange of additional information, or establish expensive communications, or affect the quality of service of the WBAN. Unlike previous researches, we proposed simple, low cost and dynamic method that adaptively adjusts specific parameters in the Medium Access Control (MAC) layer. We have proved the effectiveness of our approach based on theoretical analysis and simulation using MiXiM framework of OMNet++ simulato
Biotic and abiotic interactions between the superficial and interstitial water of a river to the Middle Atlas (Oued Tizguit)
Biotic and abiotic interactions between the superficial and interstitial waters have been analysed on the level of the interfacing zone between a river (Tizguit oued) and its underflow. The interactions were the results of water, mineral nutrients, organic matter and live beings transfers. Biotic interactions estimated by the taxonomic richness of invertebrate interstitial and superficial communities permitted to describe a zone of interfacing characterized by a dominance of epigean taxa and the scarcity of hypogean individus, represented here by the only stygobionte species Pseudoniphargus sp. The physico-chemistry of water permits to determines its quality and detect a certain natural or artificial pollution. It allows to determine its origin and explain the variations of the biological function. The interstitial waters of the Oued are relatively cold, slightly alkalised, mineralised, and relatively similar to the superficial waters from which they originate. The dynamic of exchanges at the level of interfacing zone between the river and its underflow is a direct vertical type. Exchanges take place from the surface to interstitial middle. They drag in depth epigean fauna, washed P.O.M (Particulate organic matter) and the physico-chemical features of the superficial water.Biotic and abiotic interactions between the superficial and interstitial waters have been analysed on the level of the interfacing zone between a river (Tizguit oued) and its underflow. The interactions were the results of water, mineral nutrients, organic matter and live beings transfers. Biotic interactions estimated by the taxonomic richness of invertebrate interstitial and superficial communities permitted to describe a zone of interfacing characterized by a dominance of epigean taxa and the scarcity of hypogean individus, represented here by the only stygobionte species Pseudoniphargus sp. The physico-chemistry of water permits to determines its quality and detect a certain natural or artificial pollution. It allows to determine its origin and explain the variations of the biological function. The interstitial waters of the Oued are relatively cold, slightly alkalised, mineralised, and relatively similar to the superficial waters from which they originate. The dynamic of exchanges at the level of interfacing zone between the river and its underflow is a direct vertical type. Exchanges take place from the surface to interstitial middle. They drag in depth epigean fauna, washed P.O.M (Particulate organic matter) and the physico-chemical features of the superficial water
A Proactive Approach for Coping with Uncertain Resource Availabilities on Desktop Grids
International audienceUncertainties stemming from multiple sources affect distributed systems and jeopardize their efficient utilization. Desktop grids are especially concerned by this issue as volunteers lending their resources may have irregular and unpredictable behaviors. Efficiently exploiting the power of such systems raises theoretical issues that received little attention in the literature. In this paper, we assume that there exist predictions on the intervals during which machines are available. When these predictions have a limited error, it is possible to schedule a set of jobs such that the effective total execution time will not be higher than the predicted one. We formally prove it is the case when scheduling jobs only in large intervals and when provisioning sufficient slacks to absorb uncertainties. We present multiple heuristics with various efficiencies and costs that are empirically assessed through simulations
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