16 research outputs found
Pair distribution function and structure factor of spherical particles
The availability of neutron spallation-source instruments that provide total
scattering powder diffraction has led to an increased application of real-space
structure analysis using the pair distribution function. Currently, the
analytical treatment of finite size effects within pair distribution refinement
procedures is limited. To that end, an envelope function is derived which
transforms the pair distribution function of an infinite solid into that of a
spherical particle with the same crystal structure. Distributions of particle
sizes are then considered, and the associated envelope function is used to
predict the particle size distribution of an experimental sample of gold
nanoparticles from its pair distribution function alone. Finally, complementing
the wealth of existing diffraction analysis, the peak broadening for the
structure factor of spherical particles, expressed as a convolution derived
from the envelope functions, is calculated exactly for all particle size
distributions considered, and peak maxima, offsets, and asymmetries are
discussed.Comment: 7 pages, 6 figure
The Evolution of Compact Binary Star Systems
We review the formation and evolution of compact binary stars consisting of
white dwarfs (WDs), neutron stars (NSs), and black holes (BHs). Binary NSs and
BHs are thought to be the primary astrophysical sources of gravitational waves
(GWs) within the frequency band of ground-based detectors, while compact
binaries of WDs are important sources of GWs at lower frequencies to be covered
by space interferometers (LISA). Major uncertainties in the current
understanding of properties of NSs and BHs most relevant to the GW studies are
discussed, including the treatment of the natal kicks which compact stellar
remnants acquire during the core collapse of massive stars and the common
envelope phase of binary evolution. We discuss the coalescence rates of binary
NSs and BHs and prospects for their detections, the formation and evolution of
binary WDs and their observational manifestations. Special attention is given
to AM CVn-stars -- compact binaries in which the Roche lobe is filled by
another WD or a low-mass partially degenerate helium-star, as these stars are
thought to be the best LISA verification binary GW sources.Comment: 105 pages, 18 figure
QCD and strongly coupled gauge theories : challenges and perspectives
We highlight the progress, current status, and open challenges of QCD-driven physics, in theory and in experiment. We discuss how the strong interaction is intimately connected to a broad sweep of physical problems, in settings ranging from astrophysics and cosmology to strongly coupled, complex systems in particle and condensed-matter physics, as well as to searches for physics beyond the Standard Model. We also discuss how success in describing the strong interaction impacts other fields, and, in turn, how such subjects can impact studies of the strong interaction. In the course of the work we offer a perspective on the many research streams which flow into and out of QCD, as well as a vision for future developments.Peer reviewe
One-step, low temperature synthesis of reduced graphene oxide decorated with ZnO nanocrystals using galvanized iron steel scrap
Production of a ZnO-rGO composite, using a novel one-pot method consisting in continuously flowing argon into a GO aqueous suspension heated at 80 C, in the presence of galvanized iron steel scrap is presented. FTIR shows the complete disappearance of GO functional groups and only the C=C band remained, indicating extensive GO reduction. Raman spectra indicated sp2 character increase after reaction and the presence of the E2h mode of ZnO. SEM showed submicron crystals identified by XRD as ZnO in the hexagonal phase, while TEM images indicate ZnO nanoparticles decorate mainly the rGO borders. Optical band gap of 3.5 eV corresponding to ZnO, and optical transitions at 4.1 and 5.5 eV related with n → π and π → π∗ were observed. Electrochemical characterization by cyclic voltammetry shows an specific capacitance of 4.7 F g-1 at a scan rate of 5 mVs-1, which drops to ca. 0.8 F g-1 at 200 mVs-1. By electrochemical impedance spectroscopy, the relaxation time was ca. 5 ms. The proposed mechanism for the materials' synthesis includes Zn dissolution from scrap, galvanic displacement of oxygen moieties at the GO sheet, Zn deposition onto the carbon surface, and further oxidation and growth of ZnO nanocrystals.</p
One-step, low temperature synthesis of reduced graphene oxide decorated with ZnO nanocrystals using galvanized iron steel scrap
Production of a ZnO–rGO composite, using a novel one-pot method consisting in continuously flowing argon into a GO aqueous suspension heated at 80 °C, in the presence of galvanized iron steel scrap is presented. FTIR shows the complete disappearance of GO functional groups and only the C=C band remained, indicating extensive GO reduction. Raman spectra indicated sp ^2 character increase after reaction and the presence of the E _2h mode of ZnO. SEM showed submicron crystals identified by XRD as ZnO in the hexagonal phase, while TEM images indicate ZnO nanoparticles decorate mainly the rGO borders. Optical band gap of 3.5 eV corresponding to ZnO, and optical transitions at 4.1 and 5.5 eV related with n → π and π → π * were observed. Electrochemical characterization by cyclic voltammetry shows an specific capacitance of 4.7 F g ^−1 at a scan rate of 5 mVs ^−1 , which drops to ca. 0.8 F g ^−1 at 200 mVs ^−1 . By electrochemical impedance spectroscopy, the relaxation time was ca. 5 ms. The proposed mechanism for the materials‘ synthesis includes Zn dissolution from scrap, galvanic displacement of oxygen moieties at the GO sheet, Zn deposition onto the carbon surface, and further oxidation and growth of ZnO nanocrystals
International research in graphene-oxide based materials for net-zero energy, military and aeronautic applications catalysed by Tamaulipas, Mexico: A Mini Review
Graphene oxide, as a nanoscopic platform for functional materials, has been extensively studied for several applications. The present Mini Review stresses the collaborative research in graphene-oxide materials pivoted from the Group of Materials and Technologies for Energy, Health, and Environment at an Instituto Politecnico Nacional unit in Tamaulipas, in Northeastern Mexico, with Mexican, Turkish, and British collaborators. This review covers the recent works on photovoltaic and photocatalytic materials, coatings for thermonuclear reactors, and composites and metamaterials for military and aeronautic applications.</p
International research in graphene-oxide based materials for net-zero energy, military and aeronautic applications catalysed by Tamaulipas, Mexico: a Mini Review
Graphene oxide, as a nanoscopic platform for functional materials, has been extensively studied for several applications. The present Mini Review stresses the collaborative research in graphene-oxide materials pivoted from the Group of Materials and Technologies for Energy, Health, and Environment at an Instituto Politecnico Nacional unit in Tamaulipas, in Northeastern Mexico, with Mexican, Turkish, and British collaborators. This review covers the recent works on photovoltaic and photocatalytic materials, coatings for thermonuclear reactors, and composites and metamaterials for military and aeronautic applications.</p