Paleogene initiation of the Western Branch of the East African Rift: The uplift history of the Rwenzori Mountains, Western Uganda

The two branches of the East African Rift System (EARS) are believed to have initiated diachronously. However, a growing body of work continues to suggest the onset of rifting in the Western Branch occurred in the Paleogene, coeval to the Eastern Branch. Due to a lack of pre-Miocene stratigraphy, attempts to resolve the geological history of the Western Branch must study the uplift and erosional histories of the modern rift topography. In this study, the rock uplift history of the Rwenzori Mountains, Western Uganda, is resolved to better our understanding of the tectonic history of the Western Branch of the EAR. Through the application of low-temperature thermochronology, χ-mapping and the modelling of river profiles, we show that rock uplift of the Rwenzori dates back to the Oligocene, with thermal history models suggesting uplift induced exhumation may date back as far as the Eocene. This provides tangible evidence that extension began in the region in the Paleogene, coeval with the Eastern Branch, and not the late Neogene. These results have broad implications for the tectonic evolution of the entire East African Rift System and suggest our current understanding of the region's rift history remains incomplete

Neogene and Quaternary tectonics of the Eastern Sierras Pampeanas, Argentina: Active intraplate deformation inboard of flat-slab subduction

The ranges of the Eastern Sierras Pampeanas are located >600 km east of the Andean Cordillera in central Argentina and have been interpreted to be a response to shortening related to flat-slab subduction of the Nazca plate. Uplift of the ranges has been broadly documented to occur during Neogene time, but many questions remain regarding the timing and style of deformation, and the subsurface structural configuration. In this study, we address these unknowns with observations at multiple scales, integrate our results into a tectonic model for the area, and discuss how our structural interpretation fits with more regional tectonic models. Our major findings are: (1) The range-bounding faults thrust late Proterozoic to Cambrian schist and gneiss over poorly dated Pliocene to Pleistocene alluvial strata. The timing of fault displacement and age of footwall strata suggest that deformation may have been active at least by Pliocene time. (2) Apatite and zircon (U-Th)/He thermochronometry exhibits cooling ages that range from Permian to Early Jurassic time and suggests that rock exhumation in the area is less than 2?3 km since that time. (3) Deploying a local seismic array allowed for locating seismicity and calculating receiver functions. These observations indicate that the Moho lies at a depth of 37 km and that a midcrustal discontinuity appears to correspond to a detachment zone between 15 and 20 km depth and aligns with a plane of seismicity. In our tectonic model, the craton appears to act as a rigid backstop to the eastward propagation of stresses from the shallowly subducting slab. Deformation then propagates back to the west via westward-verging faults along a midcrustal detachment.Fil: Richardson, T.. Purdue University. Department of Earth and Atmospheric Sciences; Estados UnidosFil: Ridgway, K.. Purdue University. Department of Earth and Atmospheric Sciences; Estados UnidosFil: Gilbert, H.. Purdue University. Department of Earth and Atmospheric Sciences; Estados UnidosFil: Martino, Roberto Donato. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales. Departamento de Geologia Básica y Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Enkelmann, E.. University of Cincinnati. Department of Geology; Estados UnidosFil: Anderson, M.. Colorado College. Department of Geology; Estados UnidosFil: Alvarado, Patricia Monica. Universidad Nacional de San Juan. Facultad de Ciencias Exactas, Físicas y Naturales. Departamento de Geofísica y Astronomía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin

Crustal flow around the Eastern Himalayan Syntaxis in western Yunnan, China

Abstract HKT-ISTP 2013 A

Polyamide capsules via soft templating with oil drops—1. Morphological studies of the capsule wall

Poly(terephthalamide) microcapsules can be reproducibly and easily prepared by interfacial polycondensation around emulsion droplets in water. Oil drops of cyclohexane/chloroform mixture stabilized with poly(vinyl alcohol) containing terephthaloylchloride serve as soft template. The interfacial polycondensation starts immediately after addition of an amine mixture (hexamethylenediamine/diethylenetriamine). Light and scanning electron microscopy prove the formation of capsules with size distribution in the range from a few up to 100 µm depending on particular composition of the reaction mixture. The morphology of the capsule wall is characterized by precipitated particles. If instead of pure organic solvents a reactive oil phase is used as template, the capsules can serve in subsequent reactions as templates for the synthesis of composite particles. In this way, styrene can be radically polymerized inside the capsule leading to composite capsules. The capsule morphology is determined by the partition of all components between all phases

Mid-Pleistocene climate transition drives net mass loss from rapidly uplifting St. Elias Mountains, Alaska

Erosion, sediment production and routing on a tectonically active continental margin reflect both tectonic and climatic processes; partitioning the relative importance of these processes remains controversial. Gulf of Alaska contains a preserved sedimentary record of Yakutat Terrane collision with North America. Because tectonic convergence in the coastal St. Elias orogen has been roughly constant for 6 Myr, variations in its eroded sediments preserved in the offshore Surveyor Fan constrain a budget of tectonic material influx, erosion, and sediment output. Seismically imaged sediment volumes calibrated with chronologies derived from Integrated Ocean Drilling Program boreholes shows that erosion accelerated in response to Northern Hemisphere glacial intensification (~2.7 Ma) and that the 900-km long Surveyor Channel inception appears to correlate with this event. However, tectonic influx exceeded integrated sediment efflux over the interval 2.8-1.2 Ma. Volumetric erosion accelerated following the onset of quasi-periodic (~100-kyr) glacial cycles in the mid-Pleistocene climate transition (1.2-0.7 Ma). Since then erosion and transport of material out of the orogen has outpaced tectonic influx by 50-80%. Such a rapid net mass loss explains apparent increases in exhumation rates inferred onshore from exposure dates and mapped out-of-sequence fault patterns. The 1.2 Myr mass budget imbalance must relax back toward equilibrium in balance with tectonic influx over the time scale of orogenic wedge response (Myrs). The St. Elias Range provides a key example of how active orogenic systems respond to transient mass fluxes, and the possible influence of climate driven erosive processes that diverge from equilibrium on the million-year scale

Statistics for Fission-Track Thermochronology

This chapter introduces statistical tools to extract geologically meaningful information from fission-track (FT) data using both the external detector and LA-ICP-MS methods. The spontaneous fission of 238U is a Poisson process resulting in large single-grain age uncertainties. To overcome this imprecision, it is nearly always necessary to analyse multiple grains per sample. The degree to which the analytical uncertainties can explain the observed scatter of the single-grain data can be visually assessed on a radial plot and objectively quantified by a chi-square test. For sufficiently low values of the chi-square statistic (or sufficiently high p values), the pooled age of all the grains gives a suitable description of the underlying ‘true’ age population. Samples may fail the chi-square test for several reasons. A first possibility is that the true age population does not consist of a single discrete age component, but is characterised by a continuous range of ages. In this case, a ‘random effects’ model can constrain the true age distribution using two parameters: the ‘central age’ and the ‘(over)dispersion’. A second reason why FT data sets might fail the chi-square test is if they are underlain by multimodal age distributions. Such distributions may consist of discrete age components, continuous age distributions, or a combination of the two. Formalised statistical tests such as chi-square can be useful in preventing overfitting of relatively small data sets. However, they should be used with caution when applied to large data sets (including length measurements) which generate sufficient statistical ‘power’ to reject any simple yet geologically plausible hypothesis

Guest-host systems of 1,3,5-tristyrylbenzenes

(E,E,E)-1,3,5-Tris(3,4,5-trimethoxystyryl)benzene (1a) forms monoclinic crystals of the space group P2(1)/c. Incorporation of three transoid diacetyl guest molecules between the three arms leads to triclinic crystals of the space group P1. The styryl groups, originally present in a nonsymmetrical conformation, are simultaneously transformed to a C-3 arrangement. (EEE)-1,3,5-Tris(3,4,5-tripropoxystyryl)benzene (1b) forms monoclinic crystals of the space group P2(1)/c. The C-3 arrangement of the styryl groups is present in the first, the unsymmetrical arrangement in the second modification. Incorporation of two acetone guests in the largest and the middle-sized angle space between the styryl arms in the unsymmetrical arrangement, leads to monoclinic crystals of the space group P2(1)/n. The third (smallest) angle space is filled with a propoxy chain of the neighboring molecule. The pure host crystals show significant deviations from planarity which are strongly reduced by the incorporation of the guest molecules