405 research outputs found
MANAGEMENTâS PERCEPTION OF STOCK DIVIDEND DISTRIBUTION IN AN EMERGING CAPITAL MARKET: THE CASE OF KUWAIT
The purpose of this study is to investigate perceptions of top managers of Kuwaiti companies regarding factors the affect their companiesâ decision to distribute stock dividend ( SD ). A questionnaire listing 32 reasons that could explain companiesâ decisions to declare SDs was distributed to a sample of 120 randomly selected top managers from 100 Kuwaiti companies and 73 responses were received (representing a 61% response rate ). Participants were classified according to: ( 1 )business sector ( investment, real estate, banking, service, and industrial ) and ( 2 ) size of SDs ( small ( less than 25% ) and large ( 25% or more )). Nonparametric statistical tests were employed to analyze the data.Stock Dividends, Importance Ratings, Trading Liquidity, Institutional Investors
Facile Synthesis Of Reduced Graphene Oxide-supported Pd/Cuo Nanoparticles As An Efficient Catalyst For Cross-coupling Reactions
The present communication reports a scientific investigation of a simple and versatile synthetic route for the synthesis of palladium nanoparticles decorated with copper oxide and supported on reduced graphene oxide (rGO). They are used as a highly active catalyst of Suzuki, Heck, and Sonogashira cross coupling reactions with a remarkable turnover number of 7000 and a turnover frequency of 85000 h-1. The Pd-CuO nanoparticles supported on reduced graphene oxide nanosheets (Pd-CuO/rGO) exhibit an outstanding performance through a high catalytic activity towards cross coupling reactions. A simple, reproducible, and reliable method is used to prepare this efficient catalyst using microwave irradiation synthetic conditions. The synthesis approach requires a simultaneous reduction of palladium and copper nitrates in presence of graphene oxide (GO) nanosheets using hydrazine hydrate as a strong reducing agent. The highly active and recyclable catalyst has many advantages including mild reaction conditions and short reaction durations in an environmentally benign solvent system. Moreover, the catalyst prepared can be recycled for up to five times with nearly identical high catalytic activity. Furthermore, the high catalytic activity and the recyclability of the catalyst prepared are due to the strong catalyst-support interaction. The defect sites of the reduced graphene oxide (rGO) act as nucleation centers that enable anchoring of both Pd and CuO nanoparticles and hence, minimize the possibility of agglomeration which leads to a severe decrease of the catalytic activity
Microwave-assisted Synthesis Of Palladium Nanoparticles Supported On Copper Oxide In Aqueous Medium As An Efficient Catalyst For Suzuki Cross-coupling Reaction
We report here a reliable green method for the synthesis of palladium nanoparticles supported on copper oxide as a highly active and efficient catalyst for Suzuki cross-coupling reaction. The experimental synthetic approach is based on microwave-assisted chemical reduction of an aqueous mixture of palladium and copper salt simultaneously using hydrazine hydrate as reducing agent. The catalyst was fully characterized using various techniques showing well-dispersed palladium nanoparticles. The catalytic activity and recyclability of the prepared catalyst were experimentally explored in the ligand-free Suzuki cross-coupling reaction with a diverse series of functionalized substrates. The synthesized Pd/CuO catalyst shows many advantages beside its high catalytic efficiency such as the recyclability of up to five times with negligible loss of catalytic activity, short reaction times, use of environmentally benign solvent systems, and mild reaction conditions
Mathematica as an Efficient Tool to Optimize the Kinetic Study of Ethyl Acetate Hydrolysis
Mathematica is a powerful program for computing both numeric and algebraic calculations as well as graphing two- and three-dimensional curves and surfaces. It is used increasingly in many fields of science now such as physics, engineering, chemistry and even biology because of the fast interaction of mathematics with almost the fields of science nowadays. We report here, optimizing the kinetic data for the hydrolysis of ethyl acetate through caustic soda via using Mathematica
The Kinetic Study of DPT Using Mathematica as an Efficient Optimization Tool
Mathematica is a powerful program for computing both numeric and algebraic calculations as well as graphing two- and three-dimensional curves and surfaces. It is used increasingly in many fields of science now such as physics, engineering, chemistry and even biology because of the fast interaction of mathematics with almost the fields of science nowadays. Synthesis of Cyclotetramethylene Tetramine through the action of nitrating mixture formed of ammonium nitrate and fuming nitric acid on hexamine in presence of acetic acid, acetic anhydride and p-formaldehyde has been proven. The pathway is relatively long and Hexamine Dinitrate and Dinitro Pentamethylene Tetramine (DPT) are two of the main intermediate compounds. The former was prepared, purified, and then characterized. Conversion of this compound into the latter has been followed up experimentally. Herein, we report the Preparation of Dinitro Pentamethylene Tetramine (DPT) from Hexamine Dinitrate - as an alternative synthetic route - which is an important intermediate appears through preparation of DPT from Hexamine directly. DPT was prepared at different temperatures. The variation of some factors like: temperature and time has been investigated. The obtained results were reliable and consistent with the literature. The conversion of Hexamine Dinitrate to HMX as another synthetic route was not fully studied from the point of view of kinetics. In this paper, it is intended to study the effect of time and temperature on the conversion rate of hexamine dinitrate to DPT. This scientific approach is considered as a bridge through which we aim to initiate a complete kinetic study of an important intermediate in the synthesis route of one of the most powerful energetic materials. We report here, optimizing the kinetic data for the synthesis of DPT via using Mathematica
Removal Of Methylene Blue By Adsorption Of Water Hyacinth Derived Active Carbon Embedded With Cobalt Nanoparticles
In this research, active carbon-based catalyst synthesis and characterization were tested for potential catalysts to be used in dye removal of methylene blue (MB). Water hyacinth is one of the major problems that is facing humankind and especially here in Egypt. One of the implications of industrial activities is environmental pollution. Dyes used in the production of textiles, paper, and clothes are one of the major pollutants. The waste of those dyes discharged into water supplies without treatment or with ineffective treatment harmfully impacts the environment. In this research, the treatment is implemented using active carbon-based catalysts using embedded nanoparticles. This leads to a huge increase in the adsorbent\u27s surface area, also increasing the adsorbent efficiency. The activated carbon was derived from water hyacinth that grows near the Nile River. Water hyacinth has many practical uses as it can absorb heavy metals like lead and dyes. Water hyacinth was converted into activated carbon through carbonization. Different dyes were used with different contact times in fixed conditions
Photometric study of three ultrashort-period contact binaries
We carried out high-precision photometric observations of three eclipsing ultrashort-period contact binaries (USPCBs). Theoretical models were fitted to the light curves by means of the Wilson-Devinney code. The solutions suggest that the three targets have evolved to a contact phase. The photometric results are as follows: (a) 1SWASP J030749.87â365201.7, q= 0.439 ± 0.003 , f= 0.0 ± 3.6 % ; (b) 1SWASP J213252.93â441822.6, q= 0.560 ± 0.003 , f= 14.2 ± 1.9 % ; (c) 1SWASP J200059.78+054408.9, q= 0.436 ± 0.008 , f= 58.4 ± 1.8 %. The light curves show OâConnell effects, which can be modeled by the assumed cool spots. The cool spots models are strongly supported by the night-to-night variations in the I-band light curves of 1SWASP J030749.87â365201.7. For a comparative study, we collected the whole set of 28 well-studied USPCBs with P 50 %). Generally, contact binaries with deep fill-out factors are going to merge, but it is believed that USPCBs have just evolved to a contact phase. Hence, the deep USPCB 1SWASP J200059.78+054408.9 seems to be a contradiction, making it very interesting. Particularly, 1SWASP J030749.87â365201.7 is a zero contact binary in thermal equilibrium, implying that it should be a turn-off sample as predicted by the thermal relaxation oscillation (TRO) theory.Fil: Liu, L.. Chinese Academy of Sciences; RepĂșblica de ChinaFil: Qian, S. B.. Chinese Academy of Sciences; RepĂșblica de ChinaFil: Fernandez Lajus, Eduardo Eusebio. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - La Plata. Instituto de AstrofĂsica La Plata. Universidad Nacional de La Plata. Facultad de Ciencias AstronĂłmicas y GeofĂsicas. Instituto de AstrofĂsica La Plata; ArgentinaFil: Essam, A.. National Research Institute of Astronomy and Geophysics; EgiptoFil: El Sadek, M. A.. National Research Institute of Astronomy and Geophysics; EgiptoFil: Xiong, X.. Chinese Academy of Sciences; RepĂșblica de Chin
Hydrogels and Dentin-Pulp Complex Regeneration: From the Benchtop to Clinical Translation
Dentin-pulp complex is a term which refers to the dental pulp (DP) surrounded by dentin along its peripheries. Dentin and dental pulp are highly specialized tissues, which can be affected by various insults, primarily by dental caries. Regeneration of the dentin-pulp complex is of paramount importance to regain tooth vitality. The regenerative endodontic procedure (REP) is a relatively current approach, which aims to regenerate the dentin-pulp complex through stimulating the differentiation of resident or transplanted stem/progenitor cells. Hydrogel-based scaffolds are a unique category of three dimensional polymeric networks with high water content. They are hydrophilic, biocompatible, with tunable degradation patterns and mechanical properties, in addition to the ability to be loaded with various bioactive molecules. Furthermore, hydrogels have a considerable degree of flexibility and elasticity, mimicking the cell extracellular matrix (ECM), particularly that of the DP. The current review presents how for dentin-pulp complex regeneration, the application of injectable hydrogels combined with stem/progenitor cells could represent a promising approach. According to the source of the polymeric chain forming the hydrogel, they can be classified into natural, synthetic or hybrid hydrogels, combining natural and synthetic ones. Natural polymers are bioactive, highly biocompatible, and biodegradable by naturally occurring enzymes or via hydrolysis. On the other hand, synthetic polymers offer tunable mechanical properties, thermostability and durability as compared to natural hydrogels. Hybrid hydrogels combine the benefits of synthetic and natural polymers. Hydrogels can be biofunctionalized with cell-binding sequences as arginine-glycine-aspartic acid (RGD), can be used for local delivery of bioactive molecules and cellularized with stem cells for dentin-pulp regeneration. Formulating a hydrogel scaffold material fulfilling the required criteria in regenerative endodontics is still an area of active research, which shows promising potential for replacing conventional endodontic treatments in the near future
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