Waste Wood Fly Ash Treatment in Switzerland: Effects of Co-Processing with Fly Ash from Municipal Solid Waste on Cr(VI) Reduction and Heavy Metal Recovery

In Switzerland, waste wood fly ash (WWFA) must be treated before deposition on landfills due to its high pollutant load (Cr(VI) and heavy metals). Acid fly ash leaching, the process used for heavy metal recovery from municipal solid waste incineration fly ash (MSWIFA), represents a possible treatment for heavy metal depletion and Cr(VI) reduction in WWFA. The co-processing of WWFA with MSWIFA during acid fly ash leaching was investigated in laboratory- and industrial- scale experiments with different setups. Of interest were the effects on heavy metal recovery efficiency, the successful outcome of Cr(VI) reduction and consumption of neutralizing chemicals (HCl, H2O2). Detailed chemical and mineralogical characterization of two WWFA types and MSWIFA showed that MSWIFA has higher concentrations in potentially harmful elements than WWFA. However, both WWFA types showed high concentrations in Pb and Cr(VI), and therefore need treatment prior to deposition. Depending on the waste wood proportion and quality, WWFA showed chemical and mineralogical differences that affect leaching behavior. In all experimental setups, successful Cr(VI) reduction was achieved. However, WWFA showed higher consumption of HCl and H2O2, the latter resulting in a particularly negative effect on the recovery of Pb and Cu. Thus, co-processing of smaller WWFA portions could be expedient in order to diminish the negative effects of Pb and Cu recovery

Inventory of MSWI Fly Ash in Switzerland: Heavy Metal Recovery Potential and Their Properties for Acid Leaching

From the year 2021 on, heavy metals from Swiss municipal solid waste incineration (MSWI) fly ash (FA) must be recovered before landfilling. This is predominantly performed by acid leaching. As a basis for the development of defined recovery rates and for the implementation of the recovery process, the authorities and plant operators need information on the geochemical properties of FA. This study provides extended chemical and mineralogical characterization of all FA produced in 29 MSWI plants in Switzerland. Acid neutralizing capacity (ANC) and metallic aluminum (Al0) were additionally analyzed to estimate the effort for acid leaching. Results show that all FA samples are composed of similar constituents, but their content varies due to differences in waste input and incineration conditions. Based on their geochemical properties, the ashes could be divided into four types describing the leachability: very good (6 FA), good (10 FA), moderate (5 FA), and poor leaching potential (8 FA). Due to the large differences it is suggested that the required recovery rates are adjusted to the leaching potential. The quantity of heavy metals recoverable by acid leaching was estimated to be 2420 t/y Zn, 530 t/y Pb, 66 t/y Cu and 22 t/y Cd

Partikelcharakterisierung in Verbrennungsabgasen

Based on our current knowledge, particulate matter in Diesel-engine exhaust gases should be classified as toxic. The current regulations define limits only for the total mass emission of particulate matter given in g/km or per energy unit. Other properties such as particle size or chemical composition are not yet considered.The EMPA has been concerned with the detailed analysis of particulate emission since 1992. For this investigation, samples of Diesel exhaust gases and heating-system flue gases are being used. The Diesel engine is operating under various conditions whereas two different oil-burner types are being used in the heating system. The burners are designated 'yellow-flame' and 'blue-flame'.The size distribution of the particles, their morphology, and chemical composition are determined. The initial results show that the particle properties depend on the combustion processes and operating conditions. This investigation is being continued

S-process production in rotating massive stars at solar and low metallicities

This article has been accepted for publication by Monthly Notices of the Royal Astronomical Society. © The Authors. Published by the Oxford University Press on behalf of the Royal Astronomical Society.Rotation was shown to have a strong impact on the structure and light element nucleosynthesis in massive stars. In particular, models including rotation can reproduce the primary nitrogen observed in halo extremely metal poor (EMP) stars. Additional exploratory models showed that rotation may enhance s-process production at low metallicity. Here we present a large grid of massive star models including rotation and a full s-process network to study the impact of rotation on the weak s-process.We explore the possibility of producing significant amounts of elements beyond the strontium peak, which is where the weak s-process usually stops.We used the Geneva stellar evolution code coupled to an enlarged reaction network with 737 nuclear species up to bismuth to calculate 15-40M⊙ models at four metallicities (Z = 0.014, 10-3, 10-5 and 10-7) from the main sequence up to the end of oxygen burning. We confirm that rotation-induced mixing between the convective H-shell and He-core enables an important production of primary 14N and 22Ne and s-process at low metallicity. At low metallicity, even though the production is still limited by the initial number of iron seeds, rotation enhances the s-process production, even for isotopes heavier than strontium, by increasing the neutronto- seed ratio. The increase in this ratio is a direct consequence of the primary production of 22Ne. Despite nuclear uncertainties affecting the s-process production and stellar uncertainties affecting the rotation-induced mixing, our results show a robust production of s-process at low metallicity when rotation is taken into account. Considering models with a distribution of initial rotation rates enables us to reproduce the observed large range of the [Sr/Ba] ratios in (carbon-enhanced and normal) EMP stars.Peer reviewe

Moderne NMR‐Pulsexperimente: eine graphische Beschreibung der Entwicklung von Spinsystemen

A review with 25 refs. [on SciFinder (R)

Dataset on ten-years monitoring of MSWI bottom ashes in six MSWI plants in the Canton of Zürich, Switzerland

The dataset presented in this article is the supplementary data for the research article “Ten-years monitoring of MSWI bottom ashes with focus on TOC development and leaching behaviour” by Glauser et al. (2020) [1]. From 2008 – 2018 bottom ashes have been monitored in six MSWI plants in the Canton of Zürich with regular sampling campaigns and analysis of important species defined in the Swiss Waste Legislation [2]. Both the size of the dataset and the long period of consistent and representative monitoring are unique for Switzerland. Relevant aspects of the monitoring data are discussed and interpreted in the above mentioned research article and complemented by simple emission forecast modelling. While only selected species were discussed in the research article, this data article covers all the monitoring data. The focus of the monitoring was laid on carbon-species with the analysis of total carbon (TC), total organic carbon (TOC), total inorganic carbon (TIC), degradable organic carbon (OC) and elemental carbon (EC). Total contents of nitrogen (N), sulphur (S), phosphorus (P), selected heavy metals (As, Cd, Cr, Cu, Ni, Pb, Sb and Zn) and loss on ignition (LOI) complete the solid chemical analysis. In addition, particulate ferrous (Fe) and non-ferrous (NF) metals and unburnt material were determined manually. Batch eluate tests according to Swiss Waste Legislation [3] were performed and analysed for dissolved organic carbon (DOC), ammonium (NH4+), nitrite (NO2-), fluoride (F-), sulphite (SO32-), sulphide (S2-), chromate Cr(IV) and the heavy metals Cu (aq) and Zn (aq) and Cr(IV). In addition, data on the biochemical oxygen demand (BOD) and the physical parameters pH and electrical conductivity complete the eluate analysis