Combustion Behavior Of Sub-Millimeter Sized Oxygenated And N-Alkane Fuel Droplets

The primary scientific explorations of this thesis work are to better understand (a) microgravity fire-suppression of untested extinguisher, (b) combustion kinetic model refinement of renewable fuel butanol (C4H9OH) isomers, and (c) directly induced cool flame dynamics of higher n-alkane fuels from an isolated small droplet combustion perspective employing computational fluid dynamics with comprehensive chemical kinetics. The chronological development of the research direction shifts from a relatively small fuel like methanol (CH3OH) to heavier straight paraffinic fuel n-decane (n-C10H22). The first installment of the thesis is directed towards answering the feasibility of thennewly considered fire suppressant xenon (Xe) for microgravity space application by the National Aeronautics and Space Administration (NASA). Methanol was used as model fuel to assess the combustion behavior under xenon-rich environment. The comprehensive analysis revealed that xenon promotes longer burning time and higher flame temperature compared to existing other diluents/extinguishers and can support hot flame with much lesser oxygen content than its counterparts. The exceptionally low thermal diffusivity of xenon is identified to be responsible for the significantly higher peak gas temperature and prolonged burn time. This detailed analysis clearly debilitates the potential of xenon as a next-generation fire-suppressant for microgravity applications and helped NASA in safeguard financial investment for International Space Station (ISS) experiments using xenon. The second installment of the thesis outlines the efforts directed towards improving the gas phase kinetic model of butanol isomers based on droplet combustion experiments and computations. This is a unique contribution where the traditional gasphase experiment/theory-driven kinetic model is further refined in light of critical recommendations from the droplet combustion analysis. The comprehensive kinetic model of Sarathy et al. (Combust. Flame, 2012) is one of the two widely used model for butanol isomers which has been extensively validated against homogeneous gas phase experiments. The numerical simulation of the butanol droplet combustion experiments at atmospheric conditions predicted the faster burning rate and larger flame diameter using the above model. An exhaustive perturbation analysis is carried on chemical, thermodynamic and transport parameters influences (while simultaneously isolating their cross-influences) to pinpoint the root cause of faster burning tendency of the model. The synthesized results from this huge variable-matric perturbation revealed that the isomerspecific species transport parameters were culpable, and recommendations were made to update those Lennard-Jones potential parameters. Once updated, the computational predictions significantly improves for the Sarathy et al. model based on the feedback from droplet combustion. The final segment of the thesis discusses the direct initiation of cool flame combustion for submillimeter-sized higher n-alkane droplets (n-heptane and n-decane) for possible terrestrial experiments without the necessity of radiative extinction as frequently encountered onboard the ISS experiments. It has been found that the dimensionality of the droplet (Do = 0.5 mm) statistically reduces the possibility of achieving direct cool flame burn for the droplet by simply varying the ignition energy initiation. Therefore, it was conceptualized that a combination of a reduced ignition source and induction chemistry modulation may hold the possibility of direct initiation of cool flame for n-C7H16 and n-C10H22 even in ground-based drop tower experiments. To facilitate this idea, we numerically investigate the droplet combustion under selective ozone (O3) augmented ambient where O3 serves as an induction chemistry modulator through its liberation of atomic O via molecular decomposition. The available atomic O then reacts with the surrounding fuel producing OH radical, and eventually water and heat. This latter heat input acts as a secondary thermal feedback to the droplet surface maintaining steady surface burning rate which then stabilizes the cool flame very near the droplet surface. It was found that the fuel physical properties, especially flash point, play a decisive role in determining the nature of the initial cool flame dynamics and the ozone requirements. Higher flash point fuel (here, n-C10H22) is likely to undergo initial dumped cool flame oscillation than its lower value counterpart (n-C7H16) and will require higher O3 loading under identical ambient. In the near-limit condition, such directly introduced cool flame fails to attain a steady burn and enters into a continuously evolving oscillatory cool flame. Analyses further indicate that the dynamic interaction of degenerate chain branching and chain termination/propagation reaction classes of QOOH (Q=CnH2n) species associated with the low-temperature kinetic regimes, and continuous fuel leakage across the flame location contribute to the ever-increasing trends of the oscillation magnitude

Experimental study and empirical correlation development of fuel properties of waste cooking palm biodiesel and its diesel blends at elevated temperatures

10.1016/j.renene.2014.02.007Renewable Energy68282-28

An Experimental Study of Emission and Combustion Characteristics of Marine Diesel Engine in Case of Cylinder Valves Leakage

Presented paper shows the results of the laboratory tests on the relationship between throttling of both air intake duct and exhaust gas duct and a gaseous emission from the marine engine. The object of research is a laboratory, four-stroke, DI diesel engine, operated at loads from 50 kW to 250 kW at a constant speed equal to 750 rpm. During the laboratory tests over 50 parameters of the engine were measured with its technical condition recognized as a „working properly” and with simulated leakage of both air intake valve and exhaust gas valve on the second cylinder. The results of this laboratory research confirm that the leakage of cylinder valves causes no significant changes of the thermodynamic parameters of the engine. Simulated leakages through the inlet and exhaust valve caused a significant increase in fuel consumption of the engine. Valve leakages cause an increase of the exhaust gas temperature behind the cylinder with leakage and behind other cylinders. The exhaust gas temperature increase is relatively small and clearly visible only at low loads of the engine. The increase of the temperature and pressure of the charging air behind the intercooler were observed too. Charging air temperature is significantly higher during the engine operation with inlet valve leakage. The study results show significant increases of the CO, NOx and CO2 emission for all the mentioned malfunctions. The conclusion is that the results of measurements of the composition of the exhaust gas may contain valuable diagnostic information about the technical condition of the air intake duct and the exhaust gas duct of the marine engine