Energy distribution function based universal adsorption isotherm model for all types of isotherm

Based upon the adsorbate-adsorbent interactions due to pore size distribution and surface heterogeneity, as characterized by the adsorption isotherms, the adsorption phenomenon has many industrial and environmental applications. These adsorption isotherms are very important to define the information related to the equilibrium uptake of adsorbate-adsorbent pair. Due to the presence of different energy distribution of adsorption sites, pore size distribution, surface area availability and surface heterogeneity, of each of the adsorbent-adsorbate pair, these isotherms are categorized into six types by the International Union of Pure and Applied Chemistry and so far, in the literature, there is no generalized adsorption isotherm model available that can define and predict the behavior of all adsorption isotherm types. In this study, a universal adsorption isotherm model is developed based upon the energy distribution function of the available adsorption sites and the pore size. The proposed model is able to define all adsorption isotherm characteristics, irrespective of their multi- or monolayer formations and micro- or meso-pore distribution

Hydrogen at the rooftop: Compact CPV-hydrogen system to convert sunlight to hydrogen

Despite being highest potential energy source, solar intermittency and low power density make it difficult for solar energy to compete with the conventional power plants. Highly efficient concentrated photovoltaic (CPV) system provides best technology to be paired with the electrolytic hydrogen production, as a sustainable energy source with long term energy storage. However, the conventional gigantic design of CPV system limits its market and application to the open desert fields without any rooftop installation scope, unlike conventional PV. This makes CPV less popular among solar energy customers. This paper discusses the development of compact CPV-Hydrogen system for the rooftop application in the urban region. The in-house built compact CPV system works with hybrid solar tracking of 0.1° accuracy, ensured through proposed double lens collimator based solar tracking sensor. With PEM based electrolyser, the compact CPV-hydrogen system showed 28% CPV efficiency and 18% sunlight to hydrogen (STH) efficiency, for rooftop operation in tropical region of Singapore. For plant designers, the solar to hydrogen production rating of 217 kWhe/kgH2 has been presented with 15% STH daily average efficiency, recorded from the long term field operation of the syste

Desalination Processes’ Efficiency and Future Roadmap

For future sustainable seawater desalination, the importance of achieving better energy efficiency of the existing 19,500 commercial-scale desalination plants cannot be over emphasized. The major concern of the desalination industry is the inadequate approach to energy efficiency evaluation of diverse seawater desalination processes by omitting the grade of energy supplied. These conventional approaches would suffice if the efficacy comparison were to be conducted for the same energy input processes. The misconception of considering all derived energies as equivalent in the desalination industry has severe economic and environmental consequences. In the realms of the energy and desalination system planners, serious judgmental errors in the process selection of green installations are made unconsciously as the efficacy data are either flawed or inaccurate. Inferior efficacy technologies' implementation decisions were observed in many water-stressed countries that can burden a country's economy immediately with higher unit energy cost as well as cause more undesirable environmental effects on the surroundings. In this article, a standard primary energy-based thermodynamic framework is presented that addresses energy efficacy fairly and accurately. It shows clearly that a thermally driven process consumes 2.5-3% of standard primary energy (SPE) when combined with power plants. A standard universal performance ratio-based evaluation method has been proposed that showed all desalination processes performance varies from 10-14% of the thermodynamic limit. To achieve 2030 sustainability goals, innovative processes are required to meet 25-30% of the thermodynamic limit

Desalination Processes’ Efficiency and Future Roadmap

For future sustainable seawater desalination, the importance of achieving better energy efficiency of the existing 19,500 commercial-scale desalination plants cannot be over emphasized. The major concern of the desalination industry is the inadequate approach to energy efficiency evaluation of diverse seawater desalination processes by omitting the grade of energy supplied. These conventional approaches would suffice if the efficacy comparison were to be conducted for the same energy input processes. The misconception of considering all derived energies as equivalent in the desalination industry has severe economic and environmental consequences. In the realms of the energy and desalination system planners, serious judgmental errors in the process selection of green installations are made unconsciously as the efficacy data are either flawed or inaccurate. Inferior efficacy technologies' implementation decisions were observed in many water-stressed countries that can burden a country's economy immediately with higher unit energy cost as well as cause more undesirable environmental effects on the surroundings. In this article, a standard primary energy-based thermodynamic framework is presented that addresses energy efficacy fairly and accurately. It shows clearly that a thermally driven process consumes 2.5-3% of standard primary energy (SPE) when combined with power plants. A standard universal performance ratio-based evaluation method has been proposed that showed all desalination processes performance varies from 10-14% of the thermodynamic limit. To achieve 2030 sustainability goals, innovative processes are required to meet 25-30% of the thermodynamic limit

ADMINISTRATIVE LAW INITIATIVES AND REFORMS

Administrative law is one of the key components of the rule of law in a country. The functionality of public administration mostly depends on good administrative laws and procedures. The ambitious phenomenon of transparency and accountability in public administration can only be achieved through good public administrative social contracting laws. As every component of the rule of law needs reform, administrative laws also need initiatives for reform. The administrative laws need to be amended and updated based on the time requirements and circumstances to make sure they function well. Thereby, this paper comparatively studies and analyzes the administrative law initiatives and reforms in three countries: Afghanistan, The Republic of Georgia, and Pakistan. The paper reflects on the historical view of administrative laws and policies in Afghanistan and discusses the related legislation passed for this purpose. Furthermore, it discusses the strengths and weaknesses of public administrative reform initiatives and their framework. At the end, the paper will provide recommendations for the government of Afghanistan in compliance with the lessons learned from the innovative approaches taken in Georgia and Pakistan. The study finds that the Public Administration Reform (PAR) process in Georgia has been smoother than the PAR in Pakistan and Afghanistan because Georgia has had a political will on PAR from the top to the bottom. Pakistan, due to the several regime changes, has struggled to survive but has implemented PAR initiatives that developed to the level of administrative law reforms. In Afghanistan, the PAR after the Bonn Conference Agreement has led to failure due to the pervasive administrative corruption and lack of political will and has not been able to justify the international funds raised for it. However, the Independent Administrative Reform and Civil Service Commission (IARCSC) has brought about structural reforms including the new administrative law and procedure, and the establishment of an electronic recruitment system within IARCSC

Bibliography for Open Access Week 2019

A bibliography created to accompany the Open Access Week 2019 display at the Leatherby Libraries at Chapman University

A novel intermittent fault detection algorithm and health monitoring for electronic interconnections

There are various occurrences and root causes that result in no-fault-found (NFF) events but an intermittent fault (IF) is the most frustrating. This paper describes the challenging and most important area of an IF detection and health monitoring that focuses toward NFF situation in electronics interconnections. The experimental work focuses on mechanically-induced intermittent conditions in connectors. This paper illustrates a test regime, which can be used to repeatedly reproduce intermittence in electronic connectors, while subjected to vibration. A novel algorithm is used to detect an IF in interconnection. It sends a sine wave and decodes the received signal for intermittent information from the channel. This algorithm has been simulated to capture an IF signature using PSpice (electronic circuit simulation software). A simulated circuit is implemented for practical verification. However, measurements are presented using an oscilloscope. The results of this experiment provide an insight into the limitations of existing test equipment and requirements for future IF detection techniques. Aside from scheduled maintenance, this paper considers the possibility for in-service intermittent detection to be built into future systems, i.e., can IFs be captured without external test gear