137 research outputs found
A Photoacoustic Spectrometer For Trace Gas Detection
A high-resolution external laser photoacoustic spectrometer has been developed for trace gas detection with absorption transitions in coincidence with CO 2 laser emission lines (9,2-10,9 ÎŒm: 920-1086 cm -1). The CO 2 laser operates in 90 CW lines with power of up to 15 W. A PC-controlled step motor can tune the laser lines. The resonance frequency of first longitudinal mode of the photoacoustic cell is at 1600 Hz. The cell Q-factor and cell constant are measured close to 50 and 28 mVcmW -1 respectively. The spectrometer has been tested in preliminary studies to analyze the absorption transitions of ozone (O 3). The ethylene (C 2H 4 from papaya fruit is also investigated using N 2 as carrier gas at a constant flow rate. © EDP Sciences.125885888Sigrist, M.W., (1994) Air Monitoring by Spectroscopic Techniques, pp. 163-238. , John Wiley & Sons, Inc, New YorkBijnen, F.G.C., Reuss, J., Harren, F.J.M., (1996) Rev. Sci. Instrum., 67, pp. 2914-2923NĂ€gele, M., Sigrist, M.W., (2000) Appl. Phys. B, 70, pp. 895-901Webber, M.E., Pushkarsky, M.B., Patel, C.K.N., Ultra-sensitive gas detection using diode laser and resonant photoacoustic spectroscopy (2002) SPIE's International Symposium on Optical Science and Technology, 4817, pp. 111-122. , Seattle, U.S.A., Alan Fried Editor Proceedings of SPIEThöny, A., Sigrist, M.W., (1995) Infrared Phys. Technol., 36, pp. 585-615Da Silva, M.G., Lima, J.A.P., Sthel, M.S., Marin, E., Gatts, C.E.N., Cardoso, S.L., Campostrini, E., Vargas, H., (2001) Analytical Sciences, 17, pp. s534-s53
Drude model and Lifshitz formula
Since nearly 10 years, it is known that inserting the permittivity of the
Drude model into the Lifshitz formula for free energy causes a violation of the
third law of thermodynamics. In this paper we show that the standard Matsubara
formulation for free energy contains a contribution that is non-perturbative in
the relaxation parameter. We argue that the correct formula must have a
perturbative expansion and conclude that the standard Matsubara formulation
with the permittivity of the Drude model inserted is not correct. We trace the
non-perturbative contribution in the complex frequency plane, where it shows up
as a self-intersection or a bifurcation of the integration path.Comment: accepted for publication in EPJ
Thermal correction to the Casimir force, radiative heat transfer, and an experiment
The low-temperature asymptotic expressions for the Casimir interaction
between two real metals described by Leontovich surface impedance are obtained
in the framework of thermal quantum field theory. It is shown that the Casimir
entropy computed using the impedance of infrared optics vanishes in the limit
of zero temperature. By contrast, the Casimir entropy computed using the
impedance of the Drude model attains at zero temperature a positive value which
depends on the parameters of a system, i.e., the Nernst heat theorem is
violated. Thus, the impedance of infrared optics withstands the thermodynamic
test, whereas the impedance of the Drude model does not. We also perform a
phenomenological analysis of the thermal Casimir force and of the radiative
heat transfer through a vacuum gap between real metal plates. The
characterization of a metal by means of the Leontovich impedance of the Drude
model is shown to be inconsistent with experiment at separations of a few
hundred nanometers. A modification of the impedance of infrared optics is
suggested taking into account relaxation processes. The power of radiative heat
transfer predicted from this impedance is several times less than previous
predictions due to different contributions from the transverse electric
evanescent waves. The physical meaning of low frequencies in the Lifshitz
formula is discussed. It is concluded that new measurements of radiative heat
transfer are required to find out the adequate description of a metal in the
theory of electromagnetic fluctuations.Comment: 19 pages, 4 figures. svjour.cls is used, to appear in Eur. Phys. J.
Design Specifications for an Auxiliary Incision Retractor in Dacryocystorhinostomy Surgeries
It is presented the design specifications for a Retractor Robotic System (RRS) based on the surgical necessities in the incisions procedure for a dacryocystorhinostomy. The specifications are conformed by a mathematical model, the experimental data measured, a modular flexible architecture, energy supplier system, the mechanical group, and the safety system. The specifications suggest that the use of flexible polymeric materials for the RRS provide a mayor adaptability of the system with the biological tissue; so a pneumatic actuator could be a suitable option.This research was funded by CONACYT (Consejo Nacional de Ciencia y TecnologĂa) Grant No. 86356
Fermentation characteristics and chemical composition of elephant grass silage with ground maize and fermented juice of epiphytic lactic acid bacteria
This study aimed to evaluate the microbial populations, fermentation profile, dry matter recovery and chemical composition of elephant grass silage with ground maize (GM) and the fermented juice of epiphytic lactic acid bacteria (FJLB). A factorial design was used with four levels of GM (0 g/kg, 50 g/kg, 100 g/kg and 200 g/kg), untreated or treated with FJLB, in a completely randomized design with five replicates. A pre-experiment was undertaken to determine the optimum level of sucrose to be added to fermented juice for the development of epiphytic microflora. In this pre-experiment, a completely randomized design with three replications was used. The treatments were represented by the levels of sucrose (0 g/kg, 5 g/kg, 10 g/kg, 20 g/kg, 40 g/kg, 60 g/kg and 80 g/kg, fresh matter basis). The microbial populations, dry matter recovery, and effluent losses were affected by the interaction between GM and FJLB. Dry matter (DM) and crude protein (CP) contents increased linearly with the inclusion of GM. The addition of GM enhanced the fermentation process via a reduction in losses, and improvements were identified in the nutritional value of elephant grass silages. The use of fermented juice increased dry matter recovery, and its effect was more pronounced when ground maize was added.Keywords: dry matter recovery, lactic acid, microbiology, Pennisetum purpureu
Temperature dependence of the Casimir effect between metallic mirrors
We calculate the Casimir force and free energy for plane metallic mirrors at
non-zero temperature. Numerical evaluations are given with temperature and
conductivity effects treated simultaneously. The results are compared with the
approximation where both effects are treated independently and the corrections
simply multiplied. The deviation between the exact and approximated results
takes the form of a temperature dependent function for which an analytical
expression is given. The knowledge of this function allows simple and accurate
estimations at the % level.Comment: 8 pages, 4 figures, uses RevTe
Violation of the Nernst heat theorem in the theory of thermal Casimir force between Drude metals
We give a rigorous analytical derivation of low-temperature behavior of the
Casimir entropy in the framework of the Lifshitz formula combined with the
Drude dielectric function. An earlier result that the Casimir entropy at zero
temperature is not equal to zero and depends on the parameters of the system is
confirmed, i.e. the third law of thermodynamics (the Nernst heat theorem) is
violated. We illustrate the resolution of this thermodynamical puzzle in the
context of the surface impedance approach by several calculations of the
thermal Casimir force and entropy for both real metals and dielectrics.
Different representations for the impedances, which are equivalent for real
photons, are discussed. Finally, we argue in favor of the Leontovich boundary
condition which leads to results for the thermal Casimir force that are
consistent with thermodynamics.Comment: 24 pages, 3 figures, accepted for publication in Phys. Rev.
Temperature correction to the Casimir force in cryogenic range and anomalous skin effect
Temperature correction to the Casimir force is considered for real metals at
low temperatures. With the temperature decrease the mean free path for
electrons becomes larger than the field penetration depth. In this condition
description of metals with the impedance of anomalous skin effect is shown to
be more appropriate than with the permittivity. The effect is crucial for the
temperature correction. It is demonstrated that in the zero frequency limit the
reflection coefficients should coincide with those of ideal metal if we demand
the entropy to be zero at T=0. All the other prescriptions discussed in the
literature for the term in the Lifshitz formula give negative entropy. It
is shown that the temperature correction in the region of anomalous skin effect
is not suppressed as it happens in the plasma model. This correction will be
important in the future cryogenic measurements of the Casimir force.Comment: 12 pages, 2 figures, to be published in Phys. Rev.
Characterization of alpha thalassemic genotypes by multiplex ligation-dependent probe amplification in the Brazilian population
Alpha-thalassemia is the most common inherited disorder of hemoglobin synthesis. Genomic deletions involving the alpha-globin gene cluster on chromosome 16p13.3 are the most frequent molecular causes of the disease. Although common deletions can be detected by a single multiplex gap-PCR, the rare and novel deletions depend on more laborious techniques for their identification. The multiplex ligation-dependent probe amplification (MLPA) technique has recently been used for this purpose and was successfully used in the present study to detect the molecular alterations responsible for the alpha-thalassemic phenotypes in 8 unrelated individuals (3 males and 5 females; age, 4 months to 30 years) in whom the molecular basis of the disease could not be determined by conventional methods. A total of 44 probe pairs were used for MLPA, covering approximately 800 kb from the telomere to the MSLN gene in the 16p13.3 region. Eight deletions were detected. Four of these varied in size from 240 to 720 kb and affected a large region including the entire alpha-globin gene cluster and its upstream regulatory element (alpha-MRE), while the other four varied in size from 0.4 to 100 kb and were limited to a region containing this element. This study is the first in Brazil to use the MLPA method to determine the molecular basis of alpha-thalassemia. The variety of rearrangements identified highlights the need to investigate all cases presenting microcytosis and hypochromia, but without iron deficiency or elevated hemoglobin A2 levels and suggests that these rearrangements may be more frequent in our population than previously estimated.162
Improved tests of extra-dimensional physics and thermal quantum field theory from new Casimir force measurements
We report new constraints on extra-dimensional models and other physics
beyond the Standard Model based on measurements of the Casimir force between
two dissimilar metals for separations in the range 0.2--1.2 m. The Casimir
force between an Au-coated sphere and a Cu-coated plate of a
microelectromechanical torsional oscillator was measured statically with an
absolute error of 0.3 pN. In addition, the Casimir pressure between two
parallel plates was determined dynamically with an absolute error of mPa. Within the limits of experimental and theoretical errors, the results
are in agreement with a theory that takes into account the finite conductivity
and roughness of the two metals. The level of agreement between experiment and
theory was then used to set limits on the predictions of extra-dimensional
physics and thermal quantum field theory. It is shown that two theoretical
approaches to the thermal Casimir force which predict effects linear in
temperture are ruled out by these experiments. Finally, constraints on Yukawa
corrections to Newton's law of gravity are strengthened by more than an order
of magnitude in the range 56 nm to 330 nm.Comment: Revtex 4, 35 pages, 14 figures in .gif format, accepted for
publication in Phys. Rev.
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