63 research outputs found

    Π‘Π’Π Π£ΠšΠ’Π£Π ΠΠ«Π• ΠžΠ‘ΠžΠ‘Π•ΠΠΠžΠ‘Π’Π˜ ΠŸΠ Π˜Π ΠžΠ”ΠΠ«Π₯ И ΠžΠ‘ΠžΠ“ΠΠ©Π•ΠΠΠ«Π₯ ΠšΠΠžΠ›Π˜ΠΠžΠ’ ΠœΠ•Π‘Π’ΠžΠ ΠžΠ–Π”Π•ΠΠ˜Π™ Π Π•Π‘ΠŸΠ£Π‘Π›Π˜ΠšΠ˜ БЕЛАРУБЬ

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    IR-spectroscopic results of study of primary kaolins of the Belarusian deposits Β«SitnicaΒ» and Β«DedovkaΒ» in a natural state and enriched by hydraulic sieve method are presented. The structural features of Belarusian kaolins as compared with known high-quality kaolin of Ukrainian deposits Β«ProsyanovskoeΒ» are revealed, the values of crystallinity index are determined. Analysis of IR-spectra in the high-frequency region allowed us to establish the water connection forms in natural and enriched kaolins, the presence of OH-groups in the interlayer space, inside and on the surface of the octahedral layer and adsorbed water molecules, which can affect the rheology of kaolin suspensions. Silicate absorption band of kaolin, as well as intense peaks of deformation vibrations of quartz, typical for unenriched natural kaolin of Belarusian deposits, are in the lowfrequency region. Investigation using IR-spectroscopy made it possible to establish the structural features of natural kaolins related to the presence in the primary kaolin of the Β«SitnitsaΒ» and Β«DedovkaΒ» deposits of the mineral of the kaolinite group of dikkite. The crystallinity index values (according to Hinckley) are established for natural and enriched kaolins Β«SitnicaΒ» (0.94 and 1.11) and Β«DedovkaΒ» (0.98 and 1.04) in comparison with kaolins of Prosyanovskoye deposit (1.31).Β ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½Ρ‹ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ ИК-спСктроскопичСского исслСдования ΠΏΠ΅Ρ€Π²ΠΈΡ‡Π½Ρ‹Ρ… ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ² бСлорусских мСстороТдСний Β«Π‘ΠΈΡ‚Π½ΠΈΡ†Π°Β» ΠΈ Β«Π”Π΅Π΄ΠΎΠ²ΠΊΠ°Β» Π² ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½ΠΎΠΌ состоянии ΠΈ ΠΎΠ±ΠΎΠ³Π°Ρ‰Π΅Π½Π½ΠΎΠΌ гидравличСским ситовым способом. ВыявлСны структурныС особСнности ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ² РСспублики Π‘Π΅Π»Π°Ρ€ΡƒΡΡŒ ΠΏΠΎ ΡΡ€Π°Π²Π½Π΅Π½ΠΈΡŽ с извСстным высококачСствСнным ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠΌ украинского мСстороТдСния Β«ΠŸΡ€ΠΎΡΡΠ½ΠΎΠ²ΡΠΊΠΎΠ΅Β», ΠΎΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½Ρ‹ значСния индСкса кристалличности. Анализ ИК-спСктров Π² высокочастотной области ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ» ΡƒΡΡ‚Π°Π½ΠΎΠ²ΠΈΡ‚ΡŒ Ρ„ΠΎΡ€ΠΌΡ‹ связи Π²ΠΎΠ΄Ρ‹ Π² ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½ΠΎΠΌ ΠΈ ΠΎΠ±ΠΎΠ³Π°Ρ‰Π΅Π½Π½ΠΎΠΌ ΠΊΠ°ΠΎΠ»ΠΈΠ½Π°Ρ…, Π½Π°Π»ΠΈΡ‡ΠΈΠ΅ ОН-Π³Ρ€ΡƒΠΏΠΏ Π² мСТслоСвом пространствС, Π²Π½ΡƒΡ‚Ρ€ΠΈ ΠΈ Π½Π° повСрхности октаэдричСского слоя, Π° Ρ‚Π°ΠΊΠΆΠ΅ адсорбированных ΠΌΠΎΠ»Π΅ΠΊΡƒΠ» Π²ΠΎΠ΄Ρ‹, Ρ‡Ρ‚ΠΎ ΠΌΠΎΠΆΠ΅Ρ‚ ΠΎΠΊΠ°Π·Π°Ρ‚ΡŒ влияниС Π½Π° рСологичСскиС свойства ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ²Ρ‹Ρ… суспСнзий. Π’ низкочастотной области сосрСдоточСны полосы поглощСния силикатных структур ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ², Π° Ρ‚Π°ΠΊΠΆΠ΅ интСнсивныС ΠΏΠΈΠΊΠΈ Π΄Π΅Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠ½Π½Ρ‹Ρ… ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ ΠΊΠ²Π°Ρ€Ρ†Π°, Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π½Ρ‹Π΅ для ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π΅ΠΎΠ±ΠΎΠ³Π°Ρ‰Π΅Π½Π½Ρ‹Ρ… ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ² бСлорусских мСстороТдСний. ИсслСдованиС с ΠΏΠΎΠΌΠΎΡ‰ΡŒΡŽ ИК-спСктроскопии ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ»ΠΎ ΡƒΡΡ‚Π°Π½ΠΎΠ²ΠΈΡ‚ΡŒ структурныС особСнности ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½Ρ‹Ρ… ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ², связанныС с присутствиСм Π² ΠΏΠ΅Ρ€Π²ΠΈΡ‡Π½Ρ‹Ρ… ΠΊΠ°ΠΎΠ»ΠΈΠ½Π°Ρ… мСстороТдСний Β«Π‘ΠΈΡ‚Π½ΠΈΡ†Π°Β» ΠΈ Β«Π”Π΅Π΄ΠΎΠ²ΠΊΠ°Β» ΠΌΠΈΠ½Π΅Ρ€Π°Π»Π° ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΈΡ‚ΠΎΠ²ΠΎΠΉ Π³Ρ€ΡƒΠΏΠΏΡ‹ Π΄ΠΈΠΊΠΊΠΈΡ‚Π°. ΠžΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½Ρ‹ значСния показатСля индСкса кристалличности (ΠΏΠΎ Π₯ΠΈΠ½ΠΊΠ»ΠΈ) для ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½Ρ‹Ρ… ΠΈ ΠΎΠ±ΠΎΠ³Π°Ρ‰Π΅Π½Π½Ρ‹Ρ… ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠ² Β«Π‘ΠΈΡ‚Π½ΠΈΡ†Π°Β» (0,94 ΠΈ 1,11) ΠΈ Β«Π”Π΅Π΄ΠΎΠ²ΠΊΠ°Β» (0,98 ΠΈ 1,04) Π² сравнСнии с извСстным просяновским ΠΊΠ°ΠΎΠ»ΠΈΠ½ΠΎΠΌ (1,31).

    The efficiency of using case-method for training staff of the higher qualification

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    Π’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ ΠΎΡ‚ΠΌΠ΅Ρ‡Π΅Π½ΠΎ Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ примСнСния кСйс-Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ для ΠΏΠΎΠ΄Π³ΠΎΡ‚ΠΎΠ²ΠΊΠΈ ΠΈΠ½ΠΆΠ΅Π½Π΅Ρ€Π½Ρ‹Ρ… ΠΊΠ°Π΄Ρ€ΠΎΠ² Π²Ρ‹ΡΡˆΠ΅ΠΉ ΠΊΠ²Π°Π»ΠΈΡ„ΠΈΠΊΠ°Ρ†ΠΈΠΈ. ΠžΠ±ΠΎΠ·Π½Π°Ρ‡Π΅Π½ΠΎ, Ρ‡Ρ‚ΠΎ кСйсовыС Ρ‡Π΅ΠΌΠΏΠΈΠΎΠ½Π°Ρ‚Ρ‹ ΡΠ²Π»ΡΡŽΡ‚ΡΡ эффСктивным инструмСнтом для ΠΏΠ΅Ρ€Π΅Π΄Π°Ρ‡ΠΈ Π±ΡƒΠ΄ΡƒΡ‰ΠΈΠΌ спСциалистам-ΠΈΠ½ΠΆΠ΅Π½Π΅Ρ€Π°ΠΌ практичСских Π·Π½Π°Π½ΠΈΠΉ, ΠΎΠΏΡ‹Ρ‚Π° ΠΈ Π½ΠΎΠ²Ρ‹Ρ… ΠΊΠΎΠΌΠΏΠ΅Ρ‚Π΅Π½Ρ†ΠΈΠΉ. ΠŸΡ€ΠΈΠ²Π΅Π΄Π΅Π½Ρ‹ Π΄ΠΎΠΊΠ°Π·Π°Ρ‚Π΅Π»ΡŒΡΡ‚Π²Π°, Ρ‡Ρ‚ΠΎ ΠΌΠ΅Ρ‚ΠΎΠ΄ с использованиСм кСйсов, ΠΈΠΌΠ΅Π΅Ρ‚ Π°ΠΊΡ‚ΡƒΠ°Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ, ΡΡ„Ρ„Π΅ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ ΠΈ Π²ΠΎΡΡ‚Ρ€Π΅Π±ΠΎΠ²Π°Π½Π½ΠΎΡΡ‚ΡŒ ΠΏΠΎ ΡΡ€Π°Π²Π½Π΅Π½ΠΈΡŽ с Ρ‚Ρ€Π°Π΄ΠΈΡ†ΠΈΠΎΠ½Π½Ρ‹ΠΌΠΈ ΠΌΠ΅Ρ‚ΠΎΠ΄Π°ΠΌΠΈ обучСния, Ρ‚Π°ΠΊ ΠΊΠ°ΠΊ Ρ€Π΅Π°Π»ΠΈΠ·ΡƒΠ΅Ρ‚ Π³Π»Π°Π²Π½Ρ‹Π΅ ΠΎΠ±Ρ€Π°Π·ΠΎΠ²Π°Ρ‚Π΅Π»ΡŒΠ½Ρ‹Π΅ аспСкты: ΠΏΡ€Π°ΠΊΡ‚ΠΈΡ‡Π΅ΡΠΊΡƒΡŽ Π½Π°ΠΏΡ€Π°Π²Π»Π΅Π½Π½ΠΎΡΡ‚ΡŒ, ΠΈΠ½Ρ‚Π΅Ρ€Π°ΠΊΡ‚ΠΈΠ²Π½Ρ‹ΠΉ Ρ„ΠΎΡ€ΠΌΠ°Ρ‚ ΠΈ ΠΊΠΎΠ½ΠΊΡ€Π΅Ρ‚Π½Ρ‹Π΅ Π½Π°Π²Ρ‹ΠΊΠΈ.The article notes the importance of using case technologies for the training of highly qualified engineering personnel. It is indicated that case championships are an effective tool for transferring practical knowledge, experience and new competencies to future engineers. Evidence is given that the method using cases is relevant, effective and in demand in comparison with traditional teaching methods, as it implements the main educational aspects: practical orientation, interactive format and Soft skills

    nnovative Seasonal Migrations and Subsistence System of the Mobile Pastoralists of the Desert-Steppe Zone of Eurasia:role of social groups

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    The study of the economic system of the earliest nomads which inhabited the Eurasian desert-steppe belt in 5000-2000 is a relevant task of contemporary studies. The data on the organization of living space and the role of social groups of early prehistoric pastoralists in the exploitation of open steppe resources are scarce. The paper presents a new methodological approach to searching camps of the earliest pastoralists. The application of this approach enabled the archaeologists to discover numerous seasonal camps in the Sal-Manych Ridge located in the western part of the Eurasian steppes, including Eneolithic camps dated to 4200-3600 BC. The study of the occupation layers at the sites, evaluation of the productivity of pasture systems made it possible to categorize such sites as short-term seasonal camps occupied by pastoralists, evaluate the role of social groups in the organization of innovative seasonal migrations and reconstruct their subsistence system. The camps emerged as a result of developing pastoral economic strategy in the Lower Don region and the abutting areas reflecting the role of special social groups of pastoralists who managed to organize seasonal moves and address the issue of exploiting pastures located beyond the permanently occupied area

    Hybrid nanoparticles based on sulfides, oxides, and carbides

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    The methods for synthesis of hybrid nanoparticles based on sulfides, oxides, and carbides of heavy and transition metals were considered. The problem of the influence of the method of synthesis of the hybrid nanoparticles on their atomic structure, morphology of the nanomaterials, and functional properties was analyzed. The areas of practical use of the hybrid nanoparticles were proposed. Β© 2013 Springer Science+Business Media New York

    Origin of Axial and Radial Expansions in Carbon Nanotubes Revealed by Ultrafast Diffraction and Spectroscopy

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    The coupling between electronic and nuclear degrees of freedom in low-dimensional, nanoscale systems plays a fundamental role in shaping many of their properties. Here, we report the disentanglement of axial and radial expansions of carbon nanotubes, and the direct role of electronic and vibrational excitations in determining such expansions. With subpicosecond and subpicometer resolutions, structural dynamics were explored by monitoring changes of the electron diffraction following an ultrafast optical excitation, whereas the transient behavior of the charge distribution was probed by time-resolved, electron-energy-loss spectroscopy. Our experimental results, and supporting density functional theory calculations, indicate that a population of the excited carriers in the antibonding orbitals of the nanotube walls drives a transient axial deformation in ∼1 ps; this deformation relaxes on a much longer time scale, 17 ps, by nonradiative decay. The electron-driven expansion is distinct from the phonon-driven dynamics observed along the radial direction, using the characteristic Bragg reflections; it occurs in 5 ps. These findings reveal the nonequilibrium distortion of the unit cell at early times and the role of the electron(phonon)-induced stress in the lattice dynamics of one-dimensional nanostructures

    Low-expanding ceramics based on ferrous cordierite

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    ЦСлью Π΄Π°Π½Π½ΠΎΠΉ Ρ€Π°Π±ΠΎΡ‚Ρ‹ являСтся ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΈΠ΅ исслСдований Π² области синтСза кСрамичСских ΠΌΠ°Ρ‚Π΅Ρ€ΠΈΠ°Π»ΠΎΠ² тСхничСского назначСния Π½Π° основС систСмы FeO-Al[2]O[3]-SiO[2], которая ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΡ‚ Π²Ρ‹Ρ€ΠΎΠ²Π½ΡΡ‚ΡŒ нСдостатки Ρ‚Ρ€Π°Π΄ΠΈΡ†ΠΈΠΎΠ½Π½ΠΎΠΉ ΠΊΠΎΡ€Π΄ΠΈΠ΅Ρ€ΠΈΡ‚ΠΎΠ²ΠΎΠΉ ΠΊΠ΅Ρ€Π°ΠΌΠΈΠΊΠΈ
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