278 research outputs found
A Kinetic Contribution to the Knowledge of Carbon-rings
A mechanism involving a cyclic intermediate has been suggested by Welsh and Fodor independently. To obtain a deeper insight acyl shifts with (1) 2-acylamidocyclopentanol-cis (2) 2-benzamidocyclohexanol-cis
and (3) trans have been -investigated kinetically with hydrochloric acid in dry dioxan
Estimating the Rotation Rate in the Vacuolar Proton-ATPase in Native Yeast Vacuolar Membranes
The rate of rotation of the rotor of the yeast vacuolar proton-ATPase (V-ATPase), relative to the stator or the steady parts of enzyme, is estimated in native vacuolar membrane vesicles of Saccharomyces cerevisiae under standardised conditions. Membrane vesicles are spontaneously formed after exposing purified yeast vacuoles to osmotic shock. The fraction of the total ATPase activity originating from V-ATPase is determined using the potent and specific inhibi-tor of the enzyme, concanamycin A. Inorganic phosphate liberated from ATP in the vacuolar membrane vesicle system, during 10 min of ATPase activity at 20 °C, is assayed spectrophotometrically for different concanamycin A concentrations. A fit to the quadratic binding equation, assuming a single concanamycin A binding site on a monomeric V-ATPase (our data is incompatible with models assuming more binding sites) to the inhibitor titration curve determines the concentration of the enzyme. Combining it with the known rotation:ATP stoichiometry of V-ATPase and the assayed concentration of inorganic phosphate liberated by V-ATPase leads to an average rate of ~9.53 Hz of the 360 degrees rotation, which, according to the time-dependence of the activity, extrapolates to ~14.14 Hz for the beginning of the reaction. These are low limit estimates. To our knowledge this is the first report of the rotation rate in a V-ATPase that is not subjected to genetic or chemical modification and it is not fixed on a solid support, instead it is functioning in its native membrane environment
Phase-space dependence of particle-ratio fluctuations in Pb+Pb collisions from 20A to 158A GeV beam energy
A novel approach, the identity method, was used for particle identification
and the study of fluctuations of particle yield ratios in Pb+Pb collisions at
the CERN Super Proton Synchrotron (SPS). This procedure allows to unfold the
moments of the unknown multiplicity distributions of protons (p), kaons (K),
pions () and electrons (e). Using these moments the excitation function of
the fluctuation measure [A,B] was measured, with A and
B denoting different particle types. The obtained energy dependence of
agrees with previously published NA49 results on the related
measure . Moreover, was found to depend
on the phase space coverage for [K,p] and [K,] pairs. This feature most
likely explains the reported differences between measurements of NA49 and those
of STAR in central Au+Au collisions
Production of deuterium, tritium, and He in central Pb+Pb collisions at 20A, 30A, 40A, 80A, and 158A GeV at the CERN SPS
Production of , , and He nuclei in central Pb+Pb interactions was
studied at five collision energies ( 6.3, 7.6, 8.8, 12.3, and
17.3 GeV) with the NA49 detector at the CERN SPS. Transverse momentum spectra,
rapidity distributions, and particle ratios were measured. Yields are compared
to predictions of statistical models. Phase-space distributions of light nuclei
are discussed and compared to those of protons in the context of a coalescence
approach. The coalescence parameters and , as well as coalescence
radii for and He were determined as a function of transverse mass at
all energies.Comment: 22 pages, 29 figures, 8 tables, for submission to Phys. Rev.
Bose-Einstein Correlations of Charged Kaons in Central Pb+Pb Collisions at
Bose-Einstein correlations of charged kaons were measured near mid-rapidity
in central Pb+Pb collisions at 158 AGeV by the NA49 experiment at the
CERN SPS. Source radii were extracted using the Yano-Koonin-Podgoretsky and
Bertsch-Pratt parameterizations. The results are compared to published pion
data. The measured dependence for kaons and pions is consistent with
collective transverse expansion of the source and a freeze-out time of about
9.5 .Comment: 14 pages with 7 figures, submitted to Phys. Lett.
Transverse Momentum Fluctuations in Nuclear Collisions at 158 AGeV
Results are presented on event-by-event fluctuations in transverse momentum
of charged particles, produced at forward rapidities in p+p, C+C, Si+Si and
Pb+Pb collisions at 158 AGeV. Three different characteristics are discussed:
the average transverse momentum of the event, the Phi_pT fluctuation measure
and two-particle transverse momentum correlations. In the kinematic region
explored, the dynamical fluctuations are found to be small. However, a
significant system size dependence of Phi_pT is observed, with the largest
value measured in peripheral Pb+Pb interactions. The data are compared with
predictions of several models.Comment: will be submitted to Phys. Rev.
Measurement of event-by-event transverse momentum and multiplicity fluctuations using strongly intensive measures and in nucleus-nucleus collisions at the CERN Super Proton Synchrotron
Results from the NA49 experiment at the CERN SPS are presented on
event-by-event transverse momentum and multiplicity fluctuations of charged
particles, produced at forward rapidities in central Pb+Pb interactions at beam
momenta 20, 30, 40, 80, and 158 GeV/c, as well as in systems of
different size (, C+C, Si+Si, and Pb+Pb) at 158 GeV/c. This publication
extends the previous NA49 measurements of the strongly intensive measure
by a study of the recently proposed strongly intensive measures of
fluctuations and . In the explored kinematic
region transverse momentum and multiplicity fluctuations show no significant
energy dependence in the SPS energy range. However, a remarkable system size
dependence is observed for both and , with the
largest values measured in peripheral Pb+Pb interactions. The results are
compared with NA61/SHINE measurements in collisions, as well as with
predictions of the UrQMD and EPOS models.Comment: 12 pages, 14 figures, to be submitted to PR
High p_T Spectra of Identified Particles Produced in Pb+Pb Collisions at 158GeV/nucleon Beam Energy
Transverse momentum spectra of pi^{+/-}, p, pbar, K^{+/-}, K^0_s and Lambda
at midrapidity were measured at high p_T in Pb+Pb collisions at 158GeV/nucleon
beam energy by the NA49 experiment. Particle yield ratios (p/pi, K/pi and
Lambda/K^0_s) show an enhancement of the baryon/meson ratio for p_T>2GeV/c. The
nuclear modification factor R_{CP} is extracted and compared to RHIC
measurements and pQCD calculations.Comment: Quark Matter 2005 parallel section proceeding
Antideuteron and deuteron production in mid-central Pb+Pb collisions at 158 GeV
Production of deuterons and antideuterons was studied by the NA49 experiment
in the 23.5% most central Pb+Pb collisions at the top SPS energy of
=17.3 GeV. Invariant yields for and were measured
as a function of centrality in the center-of-mass rapidity range .
Results for together with previously published
measurements are discussed in the context of the coalescence model. The
coalescence parameters were deduced as a function of transverse momentum
and collision centrality.Comment: 9 figure
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