Bohr-van Leeuwen theorem and the thermal Casimir effect for conductors

The problem of estimating the thermal corrections to Casimir and Casimir-Polder interactions in systems involving conducting plates has attracted considerable attention in the recent literature on dispersion forces. Alternative theoretical models, based on distinct low-frequency extrapolations of the plates reflection coefficient for transverse electric (TE) modes, provide widely different predictions for the magnitude of this correction. In this paper we examine the most widely used prescriptions for this reflection coefficient from the point of view of their consistency with the Bohr-van Leeuwen theorem of classical statistical physics, stating that at thermal equilibrium transverse electromagnetic fields decouple from matter in the classical limit. We find that the theorem is satisfied if and only if the TE reflection coefficient vanishes at zero frequency in the classical limit. This criterion appears to rule out some of the models that have been considered recently for describing the thermal correction to the Casimir pressure with non-magnetic metallic plates.Comment: 12 pages, no figures. Presentation has been significantly improved, more references included. The new version matches the one accepted for publication in Phys. Rev.

Magnetic Coupling Between Non-Magnetic Ions: Eu3+ in EuN and EuP

We consider the electronic structure of, and magnetic exchange (spin) interactions between, nominally nonmagnetic Eu^3+ ions (4f^6, S=3, L=3, J=0) within the context of the rocksalt structure compounds EuN and EuP. Both compounds are ionic [Eu^3+; N^3- and P^3-] semimetals similar to isovalent GdN. Treating the spin polarization within the 4f shell, and then averaging consistent with the J=0 configuration, we estimate semimetallic band overlaps (Eu 5d with pnictide 2p or 3p) of ~0.1 eV (EuN) and ~1.0 eV (EuP) that increase (become more metallic) with pressure. The calculated bulk modulus is 130 (86) GPa for EuN (EuP). Exchange (spin-spin) coupling calculated from correlated band theory is small and ferromagnetic in sign for EuN, increasing in magnitude with pressure. Conversely, the exchange coupling is antiferromagnetic in sign for EuP and is larger in magnitude, but decreases with compression. Study of a two-site model with S_1*S_2 coupling within the J=0,1 spaces of each ion illustrates the dependence of the magnetic correlation functions on the model parameters, and indicates that the spin coupling is sufficient to alter the Van Vleck susceptibility. We outline a scenario of a spin-correlation transition in a lattice of S=3, L=3, J=0 nonmagnetic ions

Heisenberg models and a particular isotropic model

The Heisenberg model, a quantum mechanical analogue of the Ising model, has a large ground state degeneracy, due to the symmetry generated by the total spin. This symmetry is also responsible for degeneracies in the rest of the spectrum. We discuss the global structure of the spectrum of Heisenberg models with arbitrary couplings, using group theoretical methods. The Hilbert space breaks up in blocks characterized by the quantum numbers of the total spin, $S$ and $M$, and each block is shown to constitute the representation space of an explicitly given irreducible representation of the symmetric group $S_N$, consisting of permutations of the $N$ spins in the system. In the second part of the paper we consider, as a concrete application, the model where each spin is coupled to all the other spins with equal strength. Its partition function is written as a single integral, elucidating its $N$-dependence. This provides a useful framework for studying finite size effects. We give explicit results for the heat capacity, revealing interesting behavior just around the phase transition.Comment: 16 pages LaTeX, one of the 2 figures included as a postscript file. Oxford preprint OUTP-93-18S, to be published in Phys. Rev.

Thermal Casimir Force between Magnetic Materials

We investigate the Casimir pressure between two parallel plates made of magnetic materials at nonzero temperature. It is shown that for real magnetodielectric materials only the magnetic properties of ferromagnets can influence the Casimir pressure. This influence is accomplished through the contribution of the zero-frequency term of the Lifshitz formula. The possibility of the Casimir repulsion through the vacuum gap is analyzed depending on the model used for the description of the dielectric properties of the metal plates.Comment: 9 pages, 3 figures. Contribution to the Proceedings of QFEXT09, Norman, OK, September 21-25, 200

A generalization of the Heine--Stieltjes theorem

We extend the Heine-Stieltjes Theorem to concern all (non-degenerate) differential operators preserving the property of having only real zeros. This solves a conjecture of B. Shapiro. The new methods developed are used to describe intricate interlacing relations between the zeros of different pairs of solutions. This extends recent results of Bourget, McMillen and Vargas for the Heun equation and answers their question on how to generalize their results to higher degrees. Many of the results are new even for the classical case.Comment: 12 pages, typos corrected and refined the interlacing theorem

The Inhibition of Mixing in Chaotic Quantum Dynamics

We study the quantum chaotic dynamics of an initially well-localized wave packet in a cosine potential perturbed by an external time-dependent force. For our choice of initial condition and with $\hbar$ small but finite, we find that the wave packet behaves classically (meaning that the quantum behavior is indistinguishable from that of the analogous classical system) as long as the motion is confined to the interior of the remnant separatrix of the cosine potential. Once the classical motion becomes unbounded, however, we find that quantum interference effects dominate. This interference leads to a long-lived accumulation of quantum amplitude on top of the cosine barrier. This pinning of the amplitude on the barrier is a dynamic mechanism for the quantum inhibition of classical mixing.Comment: 20 pages, RevTeX format with 6 Postscript figures appended in uuencoded tar.Z forma

Quantum Dot Version of Berry's Phase: Half-Integer Orbital Angular Momenta

We show that Berry's geometrical (topological) phase for circular quantum dots with an odd number of electrons is equal to \pi and that eigenvalues of the orbital angular momentum run over half-integer values. The non-zero value of the Berry's phase is provided by axial symmetry and two-dimensionality of the system. Its particular value (\pi) is fixed by the Pauli exclusion principle. Our conclusions agree with the experimental results of T. Schmidt {\it at el}, \PR B {\bf 51}, 5570 (1995), which can be considered as the first experimental evidence for the existence of a new realization of Berry's phase and half-integer values of the orbital angular momentum in a system of an odd number of electrons in circular quantum dots.Comment: 4 pages, 2 figure

On the verge of Umdeutung in Minnesota: Van Vleck and the correspondence principle (Part One)

In October 1924, the Physical Review, a relatively minor journal at the time, published a remarkable two-part paper by John H. Van Vleck, working in virtual isolation at the University of Minnesota. Van Vleck combined advanced techniques of classical mechanics with Bohr's correspondence principle and Einstein's quantum theory of radiation to find quantum analogues of classical expressions for the emission, absorption, and dispersion of radiation. For modern readers Van Vleck's paper is much easier to follow than the famous paper by Kramers and Heisenberg on dispersion theory, which covers similar terrain and is widely credited to have led directly to Heisenberg's "Umdeutung" paper. This makes Van Vleck's paper extremely valuable for the reconstruction of the genesis of matrix mechanics. It also makes it tempting to ask why Van Vleck did not take the next step and develop matrix mechanics himself.Comment: 82 page

Thermodynamic perturbation theory for dipolar superparamagnets

Thermodynamic perturbation theory is employed to derive analytical expressions for the equilibrium linear susceptibility and specific heat of lattices of anisotropic classical spins weakly coupled by the dipole-dipole interaction. The calculation is carried out to the second order in the coupling constant over the temperature, while the single-spin anisotropy is treated exactly. The temperature range of applicability of the results is, for weak anisotropy (A/kT << 1), similar to that of ordinary high-temperature expansions, but for moderately and strongly anisotropic spins (A/kT > 1) it can extend down to the temperatures where the superparamagnetic blocking takes place (A/kT \sim 25), provided only the interaction strength is weak enough. Besides, taking exactly the anisotropy into account, the results describe as particular cases the effects of the interactions on isotropic (A = 0) as well as strongly anisotropic (A \to \infty) systems (discrete orientation model and plane rotators).Comment: 15 pages, 3 figure

Spin versus Lattice Polaron: Prediction for Electron-Doped CaMnO3

CaMnO3 is a simple bi-partite antiferromagnet(AF) which can be continuously electron-doped up to LaMnO3. Electrons enter the doubly degenerate E_g subshell with spins aligned to the S=3/2 core of Mn^4+ (T_2g^3)$. We take the Hubbard and Hund energies to be effectively infinite. Our model Hamiltonian has two E_g orbitals per Mn atom, nearest neighbor hopping, nearest neighbor exchange coupling of the S=3/2 cores, and electron-phonon coupling of Mn orbitals to adjacent oxygen atoms. We solve this model for light doping. Electrons are confined in local ferromagnetic (FM) regions (spin polarons) where there proceeds an interesting competition between spin polarization (spin polarons) which enlarges the polaron, and lattice polarization (Jahn-Teller polarons) which makes it smaller. A symmetric 7-atom ferromagnetic cluster (Mn_7^27+) is the stable result, with net spin S=2 relative to the undoped AF. The distorted oxygen positions around the electron are predicted. The model also predicts a critical doping x_c=0.045 where the polaronic insulator becomes unstable relative to a FM metal.Comment: 9 pages with 7 embedded postscript figures and 2 table