3,626 research outputs found
Flammability limits, ignition energy, and flame speeds in H₂–CH₄–NH₃–N₂O–O₂–N₂ mixtures
Experiments on flammability limits, ignition energies, and flame speeds were carried out in a 11.25- and a 400-liter combustion vessel at initial pressures and temperatures of 100 kPa and 295 K, respectively. Flammability maps of hydrogen–nitrous oxide–nitrogen, methane–nitrous oxide–nitrogen, ammonia–nitrous oxide–nitrogen, and ammonia–nitrous oxide–air, as well as lean flammability limits of various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures were determined. Ignition energy bounds of methane–nitrous oxide, ammonia–nitrous oxide, and ammonia–nitrous oxide–nitrogen mixtures have been determined and the influence of small amounts of oxygen on the flammability of methane–nitrous oxide–nitrogen mixtures has been investigated. Flame speeds have been measured and laminar burning velocities have been determined for ammonia–air–nitrous oxide and various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures. Lower and upper flammability limits (mixing fan on, turbulent conditions) for ignition energies of 8 J are: H₂–N₂O: 4.5 ∼ 5.0% H₂(LFL), 76 ∼ 80% H₂(UFL); CH₄–N₂O: 2.5 ∼ 3.0% CH₄(LFL), 43 ∼ 50% CH₄(UFL); NH₃–N₂O: 5.0 ∼ 5.2% NH₃(LFL), 67.5 ∼ 68% NH₃(UFL). Inerting concentrations are: H₂–N₂O–N₂: 76% N₂; CH₄–N₂O–N₂: 70.5% N₂; NH₃–N₂O–N₂: 61% N₂; NH₃–N₂O–air: 85% air. Flammability limits of methane–nitrous oxide–nitrogen mixtures show no pronounced dependence on small amounts of oxygen (<5%). Generally speaking, flammable gases with large initial amounts of nitrous oxide or ammonia show a strong dependence of flammability limits on ignition energy
Flammability limits, ignition energy, and flame speeds in H₂–CH₄–NH₃–N₂O–O₂–N₂ mixtures
Experiments on flammability limits, ignition energies, and flame speeds were carried out in a 11.25- and a 400-liter combustion vessel at initial pressures and temperatures of 100 kPa and 295 K, respectively. Flammability maps of hydrogen–nitrous oxide–nitrogen, methane–nitrous oxide–nitrogen, ammonia–nitrous oxide–nitrogen, and ammonia–nitrous oxide–air, as well as lean flammability limits of various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures were determined. Ignition energy bounds of methane–nitrous oxide, ammonia–nitrous oxide, and ammonia–nitrous oxide–nitrogen mixtures have been determined and the influence of small amounts of oxygen on the flammability of methane–nitrous oxide–nitrogen mixtures has been investigated. Flame speeds have been measured and laminar burning velocities have been determined for ammonia–air–nitrous oxide and various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures. Lower and upper flammability limits (mixing fan on, turbulent conditions) for ignition energies of 8 J are: H₂–N₂O: 4.5 ∼ 5.0% H₂(LFL), 76 ∼ 80% H₂(UFL); CH₄–N₂O: 2.5 ∼ 3.0% CH₄(LFL), 43 ∼ 50% CH₄(UFL); NH₃–N₂O: 5.0 ∼ 5.2% NH₃(LFL), 67.5 ∼ 68% NH₃(UFL). Inerting concentrations are: H₂–N₂O–N₂: 76% N₂; CH₄–N₂O–N₂: 70.5% N₂; NH₃–N₂O–N₂: 61% N₂; NH₃–N₂O–air: 85% air. Flammability limits of methane–nitrous oxide–nitrogen mixtures show no pronounced dependence on small amounts of oxygen (<5%). Generally speaking, flammable gases with large initial amounts of nitrous oxide or ammonia show a strong dependence of flammability limits on ignition energy
The impact of temperature changes on summer time ozone and its precursors in the Eastern Mediterranean
Changes in temperature due to variability in meteorology and climate change are expected to significantly impact atmospheric composition. The Mediterranean is a climate sensitive region and includes megacities like Istanbul and large urban agglomerations such as Athens. The effect of temperature changes on gaseous air pollutant levels and the atmospheric processes that are controlling them in the Eastern Mediterranean are here investigated. The WRF/CMAQ mesoscale modeling system is used, coupled with the MEGAN model for the processing of biogenic volatile organic compound emissions. A set of temperature perturbations (spanning from 1 to 5 K) is applied on a base case simulation corresponding to July 2004. The results indicate that the Eastern Mediterranean basin acts as a reservoir of pollutants and their precursor emissions from large urban agglomerations. During summer, chemistry is a major sink at these urban areas near the surface, and a minor contributor at downwind areas. On average, the atmospheric processes are more effective within the first 1000 m above ground. Temperature increases lead to increases in biogenic emissions by 9&plusmn;3% K<sup>−1</sup>. Ozone mixing ratios increase almost linearly with the increases in ambient temperatures by 1&plusmn;0.1 ppb O<sub>3</sub> K<sup>−1</sup> for all studied urban and receptor stations except for Istanbul, where a 0.4&plusmn;0.1 ppb O<sub>3</sub> K<sup>−1</sup> increase is calculated, which is about half of the domain-averaged increase of 0.9&plusmn;0.1 ppb O<sub>3</sub> K<sup>−1</sup>. The computed changes in atmospheric processes are also linearly related with temperature changes
Electronic sculpting of ligand-GPCR subtype selectivity:the case of angiotensin II
GPCR subtypes possess distinct functional
and pharmacological profiles,
and thus development of subtype-selective ligands has immense therapeutic
potential. This is especially the case for the angiotensin receptor
subtypes AT1R and AT2R, where a functional negative control has been
described and AT2R activation highlighted as an important cancer drug
target. We describe a strategy to fine-tune ligand selectivity for
the AT2R/AT1R subtypes through electronic control of ligand aromatic-prolyl
interactions. Through this strategy an AT2R high affinity (<i>K</i><sub>i</sub> = 3 nM) agonist analogue that exerted 18,000-fold
higher selectivity for AT2R versus AT1R was obtained. We show that
this compound is a negative regulator of AT1R signaling since it is
able to inhibit MCF-7 breast carcinoma cellular proliferation in the
low nanomolar range
Observation of the rare decay K_S -> pi^0mu^+mu^-
A search for the decay K_S -> pi^0mu^+mu^- has been made by the NA48/1
Collaboration at the CERN SPS accelerator. The data were collected during 2002
with a high-intensity K_S beam. Six events were found with a background
expectation of 0.22^+0.18_-0.11 event. Using a vector matrix element and unit
form factor, the measured branching ratio is B(K_S ->
pi^0mu^+mu^-)=[2.9^+1.5_-1.2(stat)+/-0.2(syst)]x10^{-9}.Comment: 19 pages, 8 figures, 4 tables. To be published in Physics Letters
First observation and branching fraction and decay parameter measurements of the weak radiative decay Xi0 --> Lambda e+e-
The weak radiative decay Xi0 --> Lambda e+e- has been detected for the first
time. We find 412 candidates in the signal region, with an estimated background
of 15 +/- 5 events. We determine the branching fraction B(Xi0 --> Lambda e+e-)
= [7.6 +/- 0.4(stat) +/- 0.4(syst) +/- 0.2(norm)] x 10^{-6}, consistent with an
internal bremsstrahlung process, and the decay asymmetry parameter
alpha_{XiLambdaee} = -0.8 +/- 0.2, consistent with that of Xi0 --> Lambda
gamma. The charge conjugate reaction Xi0_bar --> Lambda_bar e+e- has also been
observed.Comment: 20 pages, 5 figures, 4 tables; revised: 19 pages, 4 figures, 4
tables, after reviewers' comments: 1 figure removed, 1 figure corrected,
minor editorial changes; to be published in Phys. Lett.
First observation of the KS->pi0 gamma gamma decay
Using the NA48 detector at the CERN SPS, 31 KS->pi0 gamma gamma candidates
with an estimated background of 13.7 +- 3.2 events have been observed. This
first observation leads to a branching ratio of BR(KS->pi0 gamma gamma) = (4.9
+- 1.6(stat) +- 0.9(syst)) x 10^-8 in agreement with Chiral Perturbation theory
predictions.Comment: 10 pages, 4 figures submitted to Phys. Lett.
A precision measurement of direct CP violation in the decay of neutral kaons into two pions
The direct CP violation parameter Re(epsilon'/epsilon) has been measured from
the decay rates of neutral kaons into two pions using the NA48 detector at the
CERN SPS. The 2001 running period was devoted to collecting additional data
under varied conditions compared to earlier years (1997-99). The new data yield
the result: Re(epsilon'/epsilon) = (13.7 +/- 3.1) times 10^{-4}. Combining this
result with that published from the 1997, 98 and 99 data, an overall value of
Re(epsilon'/epsilon) = (14.7 +/- 2.2) times 10^{-4} is obtained from the NA48
experiment.Comment: 19 pages, 5 figures, to be published in Physics Letters
Measurement of the branching ratios of the decays Xi0 --> Sigma+ e- nubar and anti-Xi0 --> anti-Sigma+ e+ nu
From 56 days of data taking in 2002, the NA48/1 experiment observed 6316 Xi0
--> Sigma+ e- nubar candidates (with the subsequent Sigma+ --> p pi0 decay) and
555 anti-Xi0 --> anti-Sigma+ e+ nu candidates with background contamination of
215+-44 and 136+-8 events, respectively. From these samples, the branching
ratios BR(Xi0 --> Sigma+ e- nubar)= (2.51+-0.03stat+-0.09syst)E(-4) and
BR(anti-Xi0 --> anti-Sigma+ e+ nu)= (2.55+-0.14stat+-0.10syst)E(-4) were
measured allowing the determination of the CKM matrix element |Vus| =
0.209+0.023-0.028. Using the Particle Data Group average for |Vus| obtained in
semileptonic kaon decays, we measured the ratio g1/f1 = 1.20+-0.05 of the
axial-vector to vector form factors.Comment: 16 pages, 11 figures Submitted to Phys.Lett.
Search for CP violation in K0 -> 3 pi0 decays
Using data taken during the year 2000 with the NA48 detector at the CERN SPS,
a search for the CP violating decay K_S -> 3 pi0 has been performed. From a fit
to the lifetime distribution of about 4.9 million reconstructed K0/K0bar -> 3
pi0 decays, the CP violating amplitude eta_000 = A(K_S -> 3 pi0)/A(K_L -> 3
pi0) has been found to be Re(eta_000) = -0.002 +- 0.011 +- 0.015 and
Im(eta_000) = -0.003 +- 0.013 +- 0.017. This corresponds to an upper limit on
the branching fraction of Br(K_S -> 3 pi0) < 7.4 x 10^-7 at 90% confidence
level. The result is used to improve knowledge of Re(epsilon) and the CPT
violating quantity Im(delta) via the Bell-Steinberger relation.Comment: 18 pages, 7 figures, submitted to Phys. Lett.
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