Sulphur Compounds: Comparison of Different Sorbent Tubes for their Detection

Different techniques have been developed for the analysis of gaseous sulphur pollutants, to maximize the analytical signals. In a complex matrix, such as odorous emissions, the detection of sulphur compounds can be critical in GC analysis, due to the lower concentration of these pollutants and the disturbing effect of co-eluting hydrocarbons. However, their detection is fundamental because they have a non-negligible odour impact. In the field of gaseous emissions analytics, it is common to use sorbent tubes for the sampling step. This technology uses different adsorbent materials, with different selectivity depending on the nature of the gas to be analysed. This work aims to evaluate the ability of three different sorbent tubes to collect different sulphur compounds, belonging to the classes of mercaptans, thioethers and aromatic heterocyclic compounds. A standard solution of 10 sulphur compounds was prepared by diluting in methanol 50 µL of each liquid standard into a 10 mL flask. Subsequently, this solution was diluted in methanol to obtain sulphur standards at five different concentrations (approximately 5-500 ng/µL). The tubes were loaded with the standard solutions with an aliquot of each solution, using a gas chromatograph packed column injector and subsequently analysed by TD-GC-MS. By the results obtained - average Response Factor (RF) and its Relative Standard Deviation (% RSD), it is possible to conduct a comparison among these tubes and evaluate their performance. From the comparison of the tubes, discussing % RSD, it is possible to highlight a slightly better performance, in terms of the number of compounds with % RSD ≤ 30%, for tubes specific for sulphur compounds. Focusing on RF values, multi-sorbent bed tubes show slightly higher RFs for very volatile sulphur compounds, but Sulphur tubes present higher RF values for 6 compounds out of 10 compounds considered. The performance of Tenax TA tubes, instead, appears strictly correlated with the compound’s volatility and therefore they don’t appear useful for sorption of very volatile compounds

Penning collisions of laser-cooled metastable helium atoms

We present experimental results on the two-body loss rates in a magneto-optical trap of metastable helium atoms. Absolute rates are measured in a systematic way for several laser detunings ranging from -5 to -30 MHz and at different intensities, by monitoring the decay of the trap fluorescence. The dependence of the two-body loss rate coefficient $\beta$ on the excited state ($2^3P_2$) and metastable state ($2^3S_1$) populations is also investigated. From these results we infer a rather uniform rate constant $K_{sp}=(1{\pm}0.4)\times10^{-7}$ cm$^3$/s.Comment: 8 pages, 9 figures, Revte

Stability of liquid bridges between twisted elliptical disks

The influence in the stability of long liquid bridges supported between two elliptical-shaped disks of their main axis relative orientation is investigated. A numerical continuation method capable of finding equilibrium shapes, both stable and unstable, is used to calculate a series of equilibrium shapes supported by disks of increasing eccentricity for different relative orientation of the disks axis. The stable or unstable character of each of the shapes is calculated to determine the position of the stability limit and its characte

Dorsal hippocampal damage disrupts the auditory context-dependent attenuation of taste neophobia in mice

Rodents exhibit neophobia for novel tastes, demonstrated by an initial reluctance to drink novel-tasting, potentially- aversive solutions. Taste neophobia attenuates across days if the solution is not aversive, demonstrated by increased consumption as the solution becomes familiar. This attenuation of taste neophobia is context dependent, which has been demonstrated by maintained reluctance to drink the novel tasting solution if the subject has to drink it after being brought to a novel environment. This spatial context-dependent attenuation of taste neophobia has been described and likely depends on the integrity of the dorsal hippocampus because this brain area is crucial for representing space and spatial context associations, but is unnecessary for processing taste memories per se. Whether changing the non-spatial auditory context causes a similar effect on attenuation of taste neophobia and the potential role of the dorsal hippocampus in processing this decidedly non-spatial information has not been determined. Here we demonstrate that changing the non-spatial auditory context affects the attenuation of taste neophobia in mice, and investigate the consequence of hippocampal lesion. The results demonstrate that the non-spatial auditory context-dependent attenuation of taste neophobia in mice is lost following NMDA excitotoxic lesions of the CA1 region of the dorsal hippocampus. These findings demonstrate that the dorsal hippocampus is crucial for the modulation non-associative taste learning by auditory context, neither of which provide information about space.This work was supported by the research projects PSI2014-57643-P and PSI2017-86381-P (MINECO, Spain)

Optimizing Phase Settings of High-Frequency Voltage Regulators for Power Delivery Applications

Every new computer server introduced to the market aims at delivering the best tradeoff between performance and power consumption. This goal is crucial in the case of servers for cloud computing hardware infrastructure. In this context, power delivery (PD) experts are adopting higher frequency switching voltage regulators (VR) to reduce platform’s cost as well as total cost of ownership (TCO). Because of this fact, the real estate of components, such as voltage regulators and output inductors, is shrinking as VR frequency increases. As a consequence, achieving the best performance of the VR implies looking into phase shedding schemes, as well as EM coupled inductor design, among other techniques, to mitigate power losses. This paper focuses on the study of the best angle arrangement possible for high frequency VR applications, by exploring angle settings under light load scenarios, aiming to minimize VR’s power loss and output’s voltage ripple

Influence of the effect pigment size on the sparkle detection distance

5 págs.; 5 figs.In an effort to create more dynamic looking automobiles, there is an ever increasing trend among automobile manufacturers towards the use of gonio-apparent coatings in car bodies. These coatings consist of transparent pigments mixed with metallic or interference flakes. The flakes in the coating cause a change in color and brightness of the finish with viewing and illumination direction. This change in appearance accentuates the 3D shading of a car body, making it visually more attractive. Besides this angular dependence on viewing/illumination direction, the metallic finishes also exhibit a visually complex texture. Depending on the properties of the finish and the viewing and illumination conditions, the flakes exhibit a sparkle like texture, while the glossy clear coat may show a rough or smooth surface. As a result of these complex visual attributes, capturing the appearance and finding a perfect color match for an automotive coating is a non trivial task. The main objective of this work is to evaluate the relationship between the special-effect pigments size, and the maximum distance which is detectable the sparkle texture effect. For this, two different sets of samples with different structural features were evaluated in a lighting booth specifically designed for the visual experiment. The booth allows to vary the lighting conditions, the viewing geometry and the distance at which the sample is perceived. The visual experiment was applied to evaluate the high correlation between a structural parameter (i.e. pigment size) and the visual appearance attribute related with texture (sparkle detection distance). Under some fixed environmental conditions, as light intensity, color temperature and geometry of the light source, the sparkle detection distance was evaluated by applying the adjustment psychophysical method for two panel sets (metallic grays and blues), with known pigment sizes and colorimetry, with a small set of observers. The visual results show that a greater the pigment size, a greater the sparkle detection, but with some considerations. In future, we will extend this method, even reinforced applying the statistical design of experiments (DOE), for understanding the relevance and interplay of structural (size, shape, concentration, orientation, etc.), environmental (illuminance level, color rendering, geometry, etc.) and colorimetric (dark vs. light background, chroma, etc.) factors on the sparkle detection distance. © 2015 Society for Imaging Science and Technology.Authors are grateful to EMRP for funding the project “Multidimensional reflectometry for industry”. The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union. We would like to thank the Ministry of Economy and Competitiveness for the coordinated project “New developments in visual optics, vision and color technology” (DPI2011-30090-C02). Omar Gómez would also like to thank the Ministry of Economy and Competitiveness for his pre- doctoral fellowship grant (FPI BES-2012-053080).Peer Reviewe

Pulpos: Una reproducción que les cuesta la vida

Postprin

Fixation of bioactive compounds to the cuticle of Artemia

Artemia is extensively used in aquaculture to feed early stages of cultured marine species. A problem associated with this practice is that Artemia fails to supply some essential nutrients. As a possible solution, we have devised a procedure to make Artemia a vehicle for exogenous nutrients and other bioactive compounds. It consists of the construction of chimeric proteins composed of a chitin-binding domain, which binds to the cuticle of Artemia, and a carrier domain that conveys a functional property. As confirmatory examples, we describe the successful fixation to Artemia's metanauplii of two hybrid proteins: a β-galactosidase from the thermophilic bacterium Thermotoga maritima and the jellyfish green fluorescent protein (GFP), both linked to the CBM2 chitin-binding domain from the hyperthermophilic archaeon Pyrococcus furiosus. Positive results of experiments carried out ex vivo and in vivo show the validity of this approach. The methodology used could become a general procedure for the attachment of different kinds of bioactive compounds, such as enzymes, hormones, antibiotics, etc., to the cuticle of Artemia as well as other arthropods. Statement of relevance: Our results overcome shortcomings of Artemia as a feedstock.En prensa2,04