Synthesis and characterization of Sm2(MoO4)3, Sm2(MoO4)3/GO and Sm2(MoO4)3/C3N4 nanostructures for improved photocatalytic performance and their anti-cancer the MCF-7 cells

Samarium molybdate nanoparticles (Sm2(MoO4)3) were prepared through a hydrothermal procedure and were used to form various composites with graphene oxide (GO) and carbon nitride (C3N4). The changes in the dimensions and morphology of the products were prepared using template agents like cetyltrimethyl ammonium bromide (CTAB), Sodium dodecyl sulfate (SDS) (�90), Triton X-100 (90), Polyvinyl alcohol (95), Ethylene glycol (�99), and polyvinylpyrrolidone (PVP). DRS analysis indicated band gap for the Sm2(MoO4), Sm2(MoO4)3/GO, and Sm2(MoO4)3/C3N4 as 3.75, 3.15, and 3.4 respectively. The characteristics of the prepared nanostructures were studied through X-ray diffraction (XRD), energy dispersive X-ray (EDX), and scanning electron microscopy (SEM). Finally, the activity of the prepared Sm2(MoO4)3 as photo-catalysts for the degradation of different organic dyes such as methyl orange (MO), methylene blue (MB), and rhodamine B (Rh B) was evaluated. The photocatalytic property of Sm2(MoO4)3/C3N4 and Sm2(MoO4)3/GO for the degradation of MO, was obtained. Based on the empirical data Sm2(MoO4)3/C3N4 had the strongest photodegradation effect as compared to the other compounds tested after around 40 min. BET analysis revealed that the specific surface area of the Sm2(MoO4)3 nanocomposite prepared using C3N4 is 15 times that of in the absence of C3N4. Also, the cytotoxicity of synthesized samples was evaluated using MTT assay against human cell lines MCF-7 (cancer), and its IC50 was about 125 mg/L. © 202

Neural-based Compression Scheme for Solar Image Data

Studying the solar system and especially the Sun relies on the data gathered daily from space missions. These missions are data-intensive and compressing this data to make them efficiently transferable to the ground station is a twofold decision to make. Stronger compression methods, by distorting the data, can increase data throughput at the cost of accuracy which could affect scientific analysis of the data. On the other hand, preserving subtle details in the compressed data requires a high amount of data to be transferred, reducing the desired gains from compression. In this work, we propose a neural network-based lossy compression method to be used in NASA's data-intensive imagery missions. We chose NASA's SDO mission which transmits 1.4 terabytes of data each day as a proof of concept for the proposed algorithm. In this work, we propose an adversarially trained neural network, equipped with local and non-local attention modules to capture both the local and global structure of the image resulting in a better trade-off in rate-distortion (RD) compared to conventional hand-engineered codecs. The RD variational autoencoder used in this work is jointly trained with a channel-dependent entropy model as a shared prior between the analysis and synthesis transforms to make the entropy coding of the latent code more effective. Our neural image compression algorithm outperforms currently-in-use and state-of-the-art codecs such as JPEG and JPEG-2000 in terms of the RD performance when compressing extreme-ultraviolet (EUV) data. As a proof of concept for use of this algorithm in SDO data analysis, we have performed coronal hole (CH) detection using our compressed images, and generated consistent segmentations, even at a compression rate of $\sim0.1$ bits per pixel (compared to 8 bits per pixel on the original data) using EUV data from SDO.Comment: Accepted for publication in IEEE Transactions on Aerospace and Electronic Systems (TAES). arXiv admin note: text overlap with arXiv:2210.0647

Electrochemical Oxidation and Determination of Antiviral Drug Acyclovir by Modified Carbon Paste Electrode With Magnetic CdO Nanoparticles

With the development of nanomaterials in electrochemical sensors, the use of nanostructures to modify the electrode surface has been shown to improve the kinetics of the electron transfer process. In this study, a sensor was developed for the electrochemical determination of Acyclovir (ACV) based on the modified carbon paste electrode (CPE) by CdO/Fe3O4. The magnetic CdO nanoparticles characterization was studied by energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). To study of the modified CPE surface morphology, scanning electron microscopy (SEM) was used. At the optimal conditions, a noteworthy enhancement in the electrochemical behavior of ACV was observed at the surface of the modified CPE compared to the unmodified CPE. A detection limit of 300 nM and a linear range of 1�100 μM were obtained for the quantitative monitoring of ACV at the modified CPE surface using differential pulse voltammetry (DPV) in phosphate buffer. The RSD (relative standard deviation) of the electrode response was <4.3 indicating the development of a high precision method. Also, satisfactory results were obtained in the determination of ACV with the modified electrode in tablet, blood serum, and urine samples with a satisfactory relative recovery (RR) in the range of 94.0�104.4. © Copyright © 2020 Naghian, Marzi Khosrowshahi, Sohouli, Pazoki-Toroudi, Sobhani-Nasab, Rahimi-Nasrabadi and Ahmadi

Preparation of Fe3O4/SiO2/TiO2/CeVO4 Nanocomposites: Investigation of Photocatalytic Effects on Organic Pollutants, Bacterial Environments, and New Potential Therapeutic Candidate Against Cancer Cells

The new nanocomposite with various molar ratios along with magnetic properties was fabricated via precipitation (assisted by ultrasonic) procedure. The photocatalytic effects of methylene blue (�90 degradation for optimized sample in 100 min) for finding the optimized sample performed under visible light irradiation. Moreover, the photo-antibacterial impacts of bacteria culture environments were found with an optimized sample that had effective destruction of bacteria in comparison to control group. The cytotoxicity properties of panc1 cells and magnetic behaviors of the obtained nanomaterials were evaluated and its IC50 was about 500 mg/L. As an initial step, the structural, morphological and magnetic characteristics of the fabricated nanocomposites were evaluated by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX) and MAP, UV-visible diffuse reflectance spectroscopy (DRS), and vibrating sample magnetometry (VSM) approaches. Based on SEM results, the size of nanoparticles in fabricated nanocomposite was nearly 50�70 nm for Fe3O4/SiO2/TiO2 and 80�100 nm for Fe3O4/SiO2/TiO2/CeVO4. XRD results showed that desired nanocomposites were truly synthesized without any impurities. © Copyright © 2020 Marsooli, Rahimi-Nasrabadi, Fasihi-Ramandi, Adib, Eghbali-Arani, Ahmadi, Sohouli, Sobhani nasab, Mirhosseini, Gangali, Ehrlich and Joseph

Preparation of Fe3O4/SiO2/TiO2/CeVO4 Nanocomposites: Investigation of Photocatalytic Effects on Organic Pollutants, Bacterial Environments, and New Potential Therapeutic Candidate Against Cancer Cells

The new nanocomposite with various molar ratios along with magnetic properties was fabricated via precipitation (assisted by ultrasonic) procedure. The photocatalytic effects of methylene blue (�90 degradation for optimized sample in 100 min) for finding the optimized sample performed under visible light irradiation. Moreover, the photo-antibacterial impacts of bacteria culture environments were found with an optimized sample that had effective destruction of bacteria in comparison to control group. The cytotoxicity properties of panc1 cells and magnetic behaviors of the obtained nanomaterials were evaluated and its IC50 was about 500 mg/L. As an initial step, the structural, morphological and magnetic characteristics of the fabricated nanocomposites were evaluated by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX) and MAP, UV-visible diffuse reflectance spectroscopy (DRS), and vibrating sample magnetometry (VSM) approaches. Based on SEM results, the size of nanoparticles in fabricated nanocomposite was nearly 50�70 nm for Fe3O4/SiO2/TiO2 and 80�100 nm for Fe3O4/SiO2/TiO2/CeVO4. XRD results showed that desired nanocomposites were truly synthesized without any impurities. © Copyright © 2020 Marsooli, Rahimi-Nasrabadi, Fasihi-Ramandi, Adib, Eghbali-Arani, Ahmadi, Sohouli, Sobhani nasab, Mirhosseini, Gangali, Ehrlich and Joseph

Experiences of dementia in a foreign country: qualitative content analysis of interviews with people with dementia

Background: Dementia is a worldwide health concern of epidemic proportions. Research in the field of subjective experience of dementia suffers from a lack of diversity of their participants including immigrants. Different portraits of life with dementia could help us understand how people with dementia conceptualise their experiences of dementia and how they live. Our study aimed to explore the subjective experiences of living with dementia among Iranian immigrants in Sweden. Methods: Qualitative content analysis of interviews with fifteen people with dementia from Iranian immigrant backgrounds were conducted (8 females and 7 males). Results: Three themes and seven associated sub-themes were revealed. The themes included: Being a person with dementia means living with forgetfulness (personal sphere), living with forgetfulness in the private sphere means feeling incompetent but still loved, living with forgetfulness in the public sphere means feeling confident and secure but also isolated. Conclusions: Living with dementia for the participants meant living with forgetfulness. They experienced feeling incompetent but still loved within their families and feeling confident and secure but also isolated in the society. Educating people with dementia and their families about the course and process of dementia may help them understand the changes better and adjust their expectations. Our study can provide a basis for healthcare workers to understand the experiences of living with dementia from this specific perspective

Survey of diversity, distribution, abundance and biomass of macrobenthic fauna in the southern Caspian Sea

Sediments samples were collected using Veen Grab Sampler (0.1 square meter) at 8 transects namely Astara, Anzali, Sefidroud, Tonekabon, Noshahr, Babolsar, Amirabad, Torkman in the southern of Caspian Sea. Five stations were selected at 5, 10, 20, 50 and 100 meter depths in each transect. Sediments were sampled triplicate at each station. Samples also were collected during four seasons (spring (May), summer (July), fall (November) and winter (January)) in 2009. Results of this study showed that species composition of Macrobenthos consisted of 32 species which belonged to 7 families of Polychaeta, Crustacea and Bivalvia at studied area. In addition, Oligochaeta identified in “Class”, Chironomidae considered in Insecta categories “Family” and Streblospio spp. (Polychaeta) was recognized in “Genus”. Gammaridae and Pseudocumidae of Crustacea with 12 and 10 species had the highest species diversity compared to other groups, respectively. Polychaeta was consisted 75.5 percent of total abundance of macrobenthos which the major abundance (equal 62.4% of total abundance) were belong to Streblospio spp. from Spionidae family, while its biomass was equals 5.11% of total macrobenthos. In contrast, Cerastoderma lamarcki species from Bivalvia Class with only 1.7% of total abundance of macrobenthos allocated 69 percent of total biomass. In the southern of Caspian Sea, average total abundance was significantly less at 4 western transects (Astara, Anzali, Sefidroud, Tonekabon) compared to 4 eastern transects (Noshahr, Babolsar, Amirabad, Torkman) (p<0.05). The highest average abundance of macrobenthos (10655±1246SE ind/m^2) was observed at transect of Torkman, and lowest value (4032 ± 686SE ind/m^2) was recorded at transect of Sefidroud (p< 0.05). Generally, minimum species diversity were obtained at 20 m depth in all transects and the maximum value was observed at 5 m depth in most of transects (p<0.05). In contrary, maximum average abundance of Macrobenthoses was at 20 m depth in transects of Anzali, Sefidroud, Tonekabon, Nowshahr and Amirabad compared to other depths. Macrobenthoses abundance average in 5 m depth (except Astara and Torkman) was less than other depths in 6 transect (p < 0.05). Total average abundance and biomass of macrobenthos was 5976±583SE ind/m^2 and 43.675 ± 11.402SE gr/ m^2, respectively. Maximum and minimum of abundance of macrobenthos were observed in summer (7714±778 ind/m^2) and winter (4071 ± 340 ind/m^2), respectively. Maximum and minimum of biomass of macrobenthos were obtained in fall (50.271±13.258SE gr/ m^2) and in summer (35.123 ± 8.903SE gr/ m^2), respectively (p< 0.05). Percent of total organic matter (TOM) were low in 5 and 10 m depths and increased toward offshore depths. TOM percent was 2.06±0.11SE at 10 m depth and increased to 4.62 ±0.17SE in 100 m depth. Percent of silt and clay (grains size less than 63 micron) had positive significantly correlation with percent of TOM (p<0.01).While they had negative significantly correlation with percent of sand (grains size between 63 and 1000 micron) (p<0.01). Percent of silt and clay like organic matter, had ascending trend toward to depth increased and varied from 44.4 ± 4.06SE percent in 5 m depth to 96.5 ± 0.59SE percent in 100 m depth. In contrast, percent of sand decreased toward depth and varied from 54.5 ± 4.13SE percent in 5 m depth to 2.8 ± 0.53SE percent in 100 m depth. Result of current study showed that total abundance of macrobenthoses had positive significantly correlation with TOM percent (p<0.01) and silt/clay percent (p<0.05). Abundance of Oligochaeta had positive significantly correlation (p< 0.01) with TOM and silt/clay percent. Two groups of Polychaeta, Gammaridae and Cerastoderma lamarcki had negative significantly correlation with TOM and silt/clay percent (p< 0.01), and every four aforementioned groups had positive significantly correlation with sand percent (p< 0.01). Overall, different correlation between abundance of various macrobenthos groups and TOM percent and type of grain size of sediment could be related to fluctuation of abundance of various macrobenthos groups at difference transects and depths. On the other hand, in study area were occurred simultaneously some phenomena such as increased abundance of Oligochaeta and Polychaeta, dominance of Streblospio Genuse (Polychaeta group), and decreases abundance of Bivalvia and appearance of Menemiopsis leidyi which need to study more and monitoring of this area

Survey of diversity, distribution, abundance and biomass of macrobenthic fauna in the southern Caspian Sea

The Sampling of macrobenthic communities in southeastern Caspian Sea, Iranian coast, were investigated seasonally from April to March 2012. Sampling was carried out at 8 transect as named Astara, Badar Anzali, Sefied rood, Tonekaboon, Nooshahr, Babolsar, Amirabad, Gomishan.In each transect were choice 8 stations at 5m, 10m, 20m, 50m, 100m depths respectively. Samples were taken in triplet with a 0.1m^² van Veen grab.Totally 28 macrofaunal species belonging to 10 families were identified as gamaridae (9species), corophidae (3species),psudocumidae(8 species), amphartidae (2species), balanidae, chironomidae, cardidae scorbicolaridae, nereidae, sponoidae, each one species. Polychaetes were dominated, representing 72.5% of the whole fauna while while (equal 62.4% of total abundance and 5/1%biomass) were belong to Streblospio spp. from Spionidae family. Cerastoderma lamarcki belong to bivavia consist of 2/3% total macobethos abundance and 73% biomass. Total abundance of macrobenthos of middle area were higher than east and west area in southern Caspian Sea. Average benthic population density (no/m^2) with (SE) was 4581(444 ). The benthic biomass (mg/m^2) with an overall mean of 12. 125(02). Spatial and temporal variations of benthos. In the present study showed, maximum abundance Macrobenthos 17855(5543) no/m^2) were recorded in 20 meter depths at Nooshahr trancect , while minimum 841(109 )in 10 meter depths at Amirabad trancect p<0.05. Maximum biomass 135.10(126) g/m^2 were obtained at 10m depths in Astara minimum 0.51(0.4) ) g/m^2 at 5m depths in Nooshahr transect . maximum were obtained in winter and minimum in summer Number of species varied 3 to 18 , Generally, minimum species diversity were obtained at 20 m depth in Tonekabon transects and the maximum value was observed at 100 m depth of sefeidrood variations physicochemical factors were between salinity 12.5to12.9ppt ,temperature 8-19˚c and PH 8.1 dissolve oxygen 69-101mg/li. Total secondary production calculated, according ,104/996g AFDW/m^2/yr.Maximum were recorded in 10meter depth (30/381AFDW/m^2/yr) and minimum at 50 meter depth(11/007g AFDW/m^2/yr) respectively. Average total organic matter were 3/18 percent in sample periods. Percent of total organic matter (TOM) were low in 5 and 10 m depths and increased toward offshore depths. TOM percent was 1/67(0.11 ) at 5 m depth and increased to 4/38(0.13 )in 100 m depth. Average total silt &clay were 68/63(2.97) percent in sample periods. Positive significant relation was between silt &clay and total organic matter. Macrobenthos community reduce in high silt clay and high sandy contents. Due to increase of streptolosbio.spp, monitoring program for understanding effect of this organism on ecosystem and on fish feeding is necessary

Incident type 2 diabetes attributable to suboptimal diet in 184 countries

The global burden of diet-attributable type 2 diabetes (T2D) is not well established. This risk assessment model estimated T2D incidence among adults attributable to direct and body weight-mediated effects of 11 dietary factors in 184 countries in 1990 and 2018. In 2018, suboptimal intake of these dietary factors was estimated to be attributable to 14.1 million (95% uncertainty interval (UI), 13.814.4 million) incident T2D cases, representing 70.3% (68.871.8%) of new cases globally. Largest T2D burdens were attributable to insufficient whole-grain intake (26.1% (25.027.1%)), excess refined rice and wheat intake (24.6% (22.327.2%)) and excess processed meat intake (20.3% (18.323.5%)). Across regions, highest proportional burdens were in central and eastern Europe and central Asia (85.6% (83.487.7%)) and Latin America and the Caribbean (81.8% (80.183.4%)); and lowest proportional burdens were in South Asia (55.4% (52.160.7%)). Proportions of diet-attributable T2D were generally larger in men than in women and were inversely correlated with age. Diet-attributable T2D was generally larger among urban versus rural residents and higher versus lower educated individuals, except in high-income countries, central and eastern Europe and central Asia, where burdens were larger in rural residents and in lower educated individuals. Compared with 1990, global diet-attributable T2D increased by 2.6 absolute percentage points (8.6 million more cases) in 2018, with variation in these trends by world region and dietary factor. These findings inform nutritional priorities and clinical and public health planning to improve dietary quality and reduce T2D globally. (c) 2023, The Author(s)