11,350 research outputs found
Electron-hole pairs during the adsorption dynamics of O2 on Pd(100) - Exciting or not?
During the exothermic adsorption of molecules at solid surfaces dissipation
of the released energy occurs via the excitation of electronic and phononic
degrees of freedom. For metallic substrates the role of the nonadiabatic
electronic excitation channel has been controversially discussed, as the
absence of a band gap could favour an easy coupling to a manifold of
electronhole pairs of arbitrarily low energies. We analyse this situation for
the highly exothermic showcase system of molecular oxygen dissociating at
Pd(100), using time-dependent perturbation theory applied to first-principles
electronic-structure calculations. For a range of different trajectories of
impinging O2 molecules we compute largely varying electron-hole pair spectra,
which underlines the necessity to consider the high-dimensionality of the
surface dynamical process when assessing the total energy loss into this
dissipation channel. Despite the high Pd density of states at the Fermi level,
the concomitant non-adiabatic energy losses nevertheless never exceed about 5%
of the available chemisorption energy. While this supports an electronically
adiabatic description of the predominant heat dissipation into the phononic
system, we critically discuss the non-adiabatic excitations in the context of
the O2 spin transition during the dissociation process.Comment: 20 pages including 7 figures; related publications can be found at
http://www.fhi-berlin.mpg.de/th/th.html [added two references, changed
V_{fsa} to V_{6D}, modified a few formulations in interpretation of spin
asymmetry of eh-spectra, added missing equals sign in Eg.(2.10)
Heavy Meson Production in NN Collisions with Polarized Beam and Target -- A new facility for COSY
The study of near--threshold meson production in pp and pd collisions
involving polarized beams and polarized targets offers the rare opportunity to
gain insight into short--range features of the nucleon--nucleon interaction.
The Cooler Synchrotron COSY at FZ--J\"ulich is a unique environment to perform
such studies. Measurements of polarization observables require a cylindrically
symmetrical detector, capable to measure the momenta and the directions of
outgoing charged hadrons. The wide energy range of COSY leads to momenta of
outgoing protons to be detected in a single meson production reaction between
300 and 2500 MeV/c. Scattering angles of protons to be covered extend to about
in the laboratory system. An azimuthal angular coverage of the
device around 98% seems technically achievable. The required magnetic
spectrometer could consist of a superconducting toroid, providing fields around
3 T.Comment: 6 pages, 1 figure, submitted to Czechoslovak Journal of Physic
Toy Model for Pion Production II: The role of three-particle singularities
The influence of three-particle breakup singularities on s-wave meson
production in nucleon-nucleon collisions is studied within the distorted wave
Born approximation. This study is based on a simple scalar model for the
two-nucleon interaction and the production mechanism. An algorithm for the
exact numerical treatment of the inherent three-body cuts, together with its
straightforward implementation is presented. It is also shown that two
often-used approximations to avoid the calculation of the three-body breakup
are not justified. The possible impact on pion production observables is
discussed.Comment: 14 pages, 6 figure
Imaging glutathione depletion in the rat brain using ascorbate-derived hyperpolarized MR and PET probes.
Oxidative stress is a critical feature of several common neurologic disorders. The brain is well adapted to neutralize oxidative injury by maintaining a high steady-state concentration of small-molecule intracellular antioxidants including glutathione in astrocytes and ascorbic acid in neurons. Ascorbate-derived imaging probes for hyperpolarized 13C magnetic resonance spectroscopy and positron emission tomography have been used to study redox changes (antioxidant depletion and reactive oxygen species accumulation) in vivo. In this study, we applied these imaging probes to the normal rat brain and a rat model of glutathione depletion. We first studied hyperpolarized [1-13C]dehydroascorbate in the normal rat brain, demonstrating its robust conversion to [1-13C]vitamin C, consistent with rapid transport of the oxidized form across the blood-brain barrier. We next showed that the kinetic rate of this conversion decreased by nearly 50% after glutathione depletion by diethyl maleate treatment. Finally, we showed that dehydroascorbate labeled for positron emission tomography, namely [1-11C]dehydroascorbate, showed no change in brain signal accumulation after diethyl maleate treatment. These results suggest that hyperpolarized [1-13C]dehydroascorbate may be used to non-invasively detect oxidative stress in common disorders of the brain
Dependence of pp->pp pi0 near Threshold on the Spin of the Colliding Nucleons
A polarized internal atomic hydrogen target and a stored, polarized beam are
used to measure the spin-dependent total cross section Delta_sigma_T/sigma_tot,
as well as the polar integrals of the spin correlation coefficient combination
A_xx-A_yy, and the analyzing power A_y for pp-> pp pi0 at four bombarding
energies between 325 and 400 MeV. This experiment is made possible by the use
of a cooled beam in a storage ring. The polarization observables are used to
study the contribution from individual partial waves.Comment: 6 pages, 1 table, 4 figures, corrected equations 2 and
Quantum strategies
We consider game theory from the perspective of quantum algorithms.
Strategies in classical game theory are either pure (deterministic) or mixed
(probabilistic). We introduce these basic ideas in the context of a simple
example, closely related to the traditional Matching Pennies game. While not
every two-person zero-sum finite game has an equilibrium in the set of pure
strategies, von Neumann showed that there is always an equilibrium at which
each player follows a mixed strategy. A mixed strategy deviating from the
equilibrium strategy cannot increase a player's expected payoff. We show,
however, that in our example a player who implements a quantum strategy can
increase his expected payoff, and explain the relation to efficient quantum
algorithms. We prove that in general a quantum strategy is always at least as
good as a classical one, and furthermore that when both players use quantum
strategies there need not be any equilibrium, but if both are allowed mixed
quantum strategies there must be.Comment: 8 pages, plain TeX, 1 figur
Experimental search for evidence of the three-nucleon force and a new analysis method
A research program with the aim of investigating the spin dependence of the
three-nucleon continuum in pd collisions at intermediate energies was carried
out at IUCF using the Polarized INternal Target EXperiments (PINTEX) facility.
In the elastic scattering experiment at 135 and 200 MeV proton beam energies a
total of 15 independent spin observables were obtained. The breakup experiment
was done with a vector and tensor polarized deuteron beam of 270 MeV and an
internal polarized hydrogen gas target. We developed a novel technique for the
analysis of the breakup observables, the sampling method. The new approach
takes into account acceptance and non-uniformities of detection efficiencies
and is suitable for any kinematically complete experiment with three particles
in the final state.Comment: Contribution to the 19th European Few-Body Conference, Groningen Aug.
23-27, 200
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