Synthesis of strontium ferrite/iron oxide exchange coupled nano-powders with improved energy product for rare earth free permanent magnet applications

We present a simple, scalable synthesis route for producing exchange coupled soft/hard magnetic composite powder that outperforms pure soft and hard phase constituents. Importantly, the composites is iron oxide based (SrFe12O19 and Fe3O4) and contain no rare earth or precious metal. The two step synthesis process consists of first precipitating, an Iron oxide/hydroxide precursor directly on top of SrFe12O19 nano-flakes, ensuring a very fine degree of mixing between the hard and the soft magnetic phases. We then use a second step that serves to reduce the precursor to create the proper soft magnetic phase and create the intimate interface necessary for exchange coupling. We establish a clear processing window; at temperatures below this window the desired soft phase is not produced, while higher temperatures result in deleterious reaction at the soft/hard phase interfaces, causing an improper ratio of soft to hard phases. Improvements of Mr, Ms, and (BH)max are 42%, 29% and 37% respectively in the SrFe12O19/Fe3O4 composite compared to pure hard phase (SrFe12O19). We provide evidence of coupling (exchange spring behavior) with hysteresis curves, first order reversal curve (FORC) analysis and recoil measurements.Comment: in J. Mater. Chem. C, 201

Maximum likelihood estimation of cloud height from multi-angle satellite imagery

We develop a new estimation technique for recovering depth-of-field from multiple stereo images. Depth-of-field is estimated by determining the shift in image location resulting from different camera viewpoints. When this shift is not divisible by pixel width, the multiple stereo images can be combined to form a super-resolution image. By modeling this super-resolution image as a realization of a random field, one can view the recovery of depth as a likelihood estimation problem. We apply these modeling techniques to the recovery of cloud height from multiple viewing angles provided by the MISR instrument on the Terra Satellite. Our efforts are focused on a two layer cloud ensemble where both layers are relatively planar, the bottom layer is optically thick and textured, and the top layer is optically thin. Our results demonstrate that with relative ease, we get comparable estimates to the M2 stereo matcher which is the same algorithm used in the current MISR standard product (details can be found in [IEEE Transactions on Geoscience and Remote Sensing 40 (2002) 1547--1559]). Moreover, our techniques provide the possibility of modeling all of the MISR data in a unified way for cloud height estimation. Research is underway to extend this framework for fast, quality global estimates of cloud height.Comment: Published in at http://dx.doi.org/10.1214/09-AOAS243 the Annals of Applied Statistics (http://www.imstat.org/aoas/) by the Institute of Mathematical Statistics (http://www.imstat.org

Evaluation of laser bacterial anti-fouling of transparent nanocrystalline yttria-stabilized-zirconia cranial implant.

Background and objectiveThe development and feasibility of a novel nanocrystalline yttria-stabilized-zirconia (nc-YSZ) cranial implant has been recently established. The purpose of what we now call "window to the brain (WttB)" implant (or platform), is to improve patient care by providing a technique for delivery and/or collection of light into/from the brain, on demand, over large areas, and on a chronically recurring basis without the need for repeated craniotomies. WttB holds the transformative potential for enhancing light-based diagnosis and treatment of a wide variety of brain pathologies including cerebral edema, traumatic brain injury, stroke, glioma, and neurodegenerative diseases. However, bacterial adhesion to the cranial implant is the leading factor for biofilm formation (fouling), infection, and treatment failure. Escherichia coli (E. coli), in particular, is the most common isolate in gram-negative bacillary meningitis after cranial surgery or trauma. The transparency of our WttB implant may provide a unique opportunity for non-invasive treatment of bacterial infection under the implant using medical lasers.Study design/materials and methodsA drop of a diluted overnight culture of BL21-293 E. coli expressing luciferase was seeded between the nc-YSZ implant and the agar plate. This was followed by immediate irradiation with selected laser. After each laser treatment the nc-YSZ was removed, and cultures were incubated for 24 hours at 37 °C. The study examined continuous wave (CW) and pulsed wave (PW) modes of near-infrared (NIR) 810 nm laser wavelength with a power output ranging from 1 to 3 W. During irradiation, the temperature distribution of nc-YSZ surface was monitored using an infrared thermal camera. Relative luminescence unit (RLU) was used to evaluate the viability of bacteria after the NIR laser treatment.ResultsAnalysis of RLU suggests that the viability of E. coli biofilm formation was reduced with NIR laser treatment when compared to the control group (P < 0.01) and loss of viability depends on both laser fluence and operation mode (CW or PW). The results demonstrate that while CW laser reduces the biofilm formation more than PW laser with the same power, the higher surface temperature of the implant generated by CW laser limits its medical efficacy. In contrast, with the right parameters, PW laser produces a more moderate photothermal effect which can be equally effective at controlling bacterial growth.ConclusionsOur results show that E. coli biofilm formation across the thickness of the nc-YSZ implant can be disrupted using NIR laser treatment. The results of this in vitro study suggest that using nc-YSZ as a cranial implant in vivo may also allow for locally selective, non-invasive, chronic treatment of bacterial layers (fouling) that might form under cranial implants, without causing adverse thermal damage to the underlying host tissue when appropriate laser parameters are used. Lasers Surg. Med. 48:782-789, 2016. © 2016 Wiley Periodicals, Inc

Pure States, Mixed States and Hawking Problem in Generalized Quantum Mechanics

This paper is the continuation of a study into the information paradox problem started by the author in his earlier works. As previously, the key instrument is a deformed density matrix in quantum mechanics of the early universe. It is assumed that the latter represents quantum mechanics with fundamental length. It is demonstrated that the obtained results agree well with the canonical viewpoint that in the processes involving black holes pure states go to the mixed ones in the assumption that all measurements are performed by the observer in a well-known quantum mechanics. Also it is shown that high entropy for Planck remnants of black holes appearing in the assumption of the Generalized Uncertainty Relations may be explained within the scope of the density matrix entropy introduced by the author previously. It is noted that the suggested paradigm is consistent with the Holographic Principle. Because of this, a conjecture is made about the possibility for obtaining the Generalized Uncertainty Relations from the covariant entropy bound at high energies in the same way as R. Bousso has derived Heisenberg uncertainty principle for the flat space.Comment: 12 pages,no figures,some corrections,new reference

A paradigm shift for socioeconomic justice and health: from focusing on inequalities to aiming at sustainable equity

OBJECTIVES: To measure the \u27best possible health for all\u27, incorporating sustainability, and to establish the magnitude of global health inequity. STUDY DESIGN: Observational, retrospective. METHODS: We identified countries with three criteria: (1) a healthy population-life expectancy above world average; (2) living conditions feasible to replicate worldwide-per-capita gross domestic product (GDP-pc) below the world average; and (3) sustainability-per-capita carbon dioxide emissions lower than the planetary pollution boundary. Using these healthy, feasible, and sustainable (HFS) countries as the gold standard, we estimated the burden of global health inequity (BGHiE) in terms of excess deaths, analyzing time-trends (1950-2012) by age, sex, and geographic location. Finally, we defined a global income \u27equity zone\u27 and quantified the economic gap needed to achieve global sustainable health equity. RESULTS: A total of 14 countries worldwide met the HFS criteria. Since 1970, there has been a BGHiE of approximately 17 million avoidable deaths per year ( approximately 40% of all deaths), with 36 life-years-lost per excess death. Young children and women bore a higher BGHiE, and, in recent years, the highest proportion of avoidable deaths occurred in Africa, India, and the Russian Federation. By 2012, the most efficient HFS countries had a GDP-pc/year of USD$2,165, which we proposed as the lower equity zone threshold. The estimated USD$2.58 trillion economic gap represents 3.6% of the world\u27s GDP-twenty times larger than current total global foreign aid. CONCLUSIONS: Sustainable health equity metrics provide a benchmark tool to guide efforts toward transforming overall living conditions, as a means to achieve the \u27best possible health for all.\u2

Dynamics for a 2-vertex Quantum Gravity Model

We use the recently introduced U(N) framework for loop quantum gravity to study the dynamics of spin network states on the simplest class of graphs: two vertices linked with an arbitrary number N of edges. Such graphs represent two regions, in and out, separated by a boundary surface. We study the algebraic structure of the Hilbert space of spin networks from the U(N) perspective. In particular, we describe the algebra of operators acting on that space and discuss their relation to the standard holonomy operator of loop quantum gravity. Furthermore, we show that it is possible to make the restriction to the isotropic/homogeneous sector of the model by imposing the invariance under a global U(N) symmetry. We then propose a U(N) invariant Hamiltonian operator and study the induced dynamics. Finally, we explore the analogies between this model and loop quantum cosmology and sketch some possible generalizations of it.Comment: 28 pages, v2: typos correcte

Monotonic Prefix Consistency in Distributed Systems

We study the issue of data consistency in distributed systems. Specifically, we consider a distributed system that replicates its data at multiple sites, which is prone to partitions, and which is assumed to be available (in the sense that queries are always eventually answered). In such a setting, strong consistency, where all replicas of the system apply synchronously every operation, is not possible to implement. However, many weaker consistency criteria that allow a greater number of behaviors than strong consistency, are implementable in available distributed systems. We focus on determining the strongest consistency criterion that can be implemented in a convergent and available distributed system that tolerates partitions. We focus on objects where the set of operations can be split into updates and queries. We show that no criterion stronger than Monotonic Prefix Consistency (MPC) can be implemented.Comment: Submitted pape