2,403 research outputs found

    Threshold Optical Nonlinearity of Dielectric Nanocomposite

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    Learning what matters - Sampling interesting patterns

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    In the field of exploratory data mining, local structure in data can be described by patterns and discovered by mining algorithms. Although many solutions have been proposed to address the redundancy problems in pattern mining, most of them either provide succinct pattern sets or take the interests of the user into account-but not both. Consequently, the analyst has to invest substantial effort in identifying those patterns that are relevant to her specific interests and goals. To address this problem, we propose a novel approach that combines pattern sampling with interactive data mining. In particular, we introduce the LetSIP algorithm, which builds upon recent advances in 1) weighted sampling in SAT and 2) learning to rank in interactive pattern mining. Specifically, it exploits user feedback to directly learn the parameters of the sampling distribution that represents the user's interests. We compare the performance of the proposed algorithm to the state-of-the-art in interactive pattern mining by emulating the interests of a user. The resulting system allows efficient and interleaved learning and sampling, thus user-specific anytime data exploration. Finally, LetSIP demonstrates favourable trade-offs concerning both quality-diversity and exploitation-exploration when compared to existing methods.Comment: PAKDD 2017, extended versio

    Comparative legal analysis of mediation in Russia and the EU

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    The purpose of this article is to identify the specifics of mediation procedures, review them as extrajudicial method of conflict resolution. As the methodological basis of the research we use the synergistic, phenomenological and dialectical analysis techniques to examine the main aspects of the mediation as well as identify its principal features. As a result of the study, the authors concluded that in Russia it is necessary to take into account the international experience of mediation, legislation to support the mediation process and in some cases give it forceful character, to develop cooperation with the courts and notaries with the mediators.peer-reviewe

    Evidence for an Excited Hyperon State in pp -> p K^+ Y^{0*}

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    Indications for the production of a neutral excited hyperon in the reaction pp -> p K^+ Y^{0*} are observed in an experiment performed with the ANKE spectrometer at COSY-J\"ulich at a beam momentum of 3.65 GeV/c. Two final states were investigated simultaneously, viz. Y^{0*} -> pi^+X^- and pi^-X^+, and consistent results were obtained in spite of the quite different experimental conditions. The parameters of the hyperon state are M(Y^{0*})= (1480 +/- 15) MeV/c^2 and Gamma(Y^{0*})= (60 +/- 15) MeV/c^2. The production cross section is of the order of few hundred nanobarns. Since the isospin of the Y^{0*} has not been determined here, it could either be an observation of the Sigma(1480), a one-star resonance of the PDG tables, or alternatively a Lambda hyperon. Relativistic quark models for the baryon spectrum do not predict any excited hyperon in this mass range and so the Y^{0*} may be of exotic nature.Comment: 4 pages, 3 figures, accepted for publication in Phys.Rev.Let

    Observation of inverse diproton photodisintegration at intermediate energies

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    The reaction pp->{pp}_s\gamma, where {pp}_s is a proton pair with an excitation energy E_{pp}<3 MeV, has been observed with the ANKE spectrometer at COSY-Juelich for proton beam energies of T_p=0.353, 0.500, and 0.550 GeV. This is equivalent to photodisintegration of a free 1S_0 diproton for photon energies E\gamma ~ T_p/2. The differential cross sections measured for c.m. angles 0 deg.<\theta_{pp}<20 deg. exhibit a steep increase with angle that is compatible with E1 and E2 multipole contributions. The ratio of the measured cross sections to those of np->d\gamma is on the 10^{-3}-10^{-2} level. The increase of the pp->{pp}_s\gamma cross section with T_p might reflect the influence of the Delta(1232) excitation.Comment: 4 pages + 4 figure

    ΠΠΠΠ›Π˜Π’Π˜Π§Π•Π‘ΠšΠ˜Π• Π’ΠžΠ—ΠœΠžΠ–ΠΠžΠ‘Π’Π˜ Π‘ΠŸΠ•ΠšΠ’Π ΠžΠœΠ•Π’Π Π Π’Π«Π‘ΠžΠšΠžΠ“Πž Π ΠΠ—Π Π•Π¨Π•ΠΠ˜Π― «ГРАНД-2000Β» Π’ Π”Π£Π“ΠžΠ’ΠžΠœ АВОМНО-ЭМИББИОННОМ ΠΠΠΠ›Π˜Π—Π•

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    The analytical characteristics of the new Grand-2000 high-resolution spectrometer with BLPP-4000 photodetectors were evaluated. The device was tested as part of the Grand-Potok complex, which consists of a spectrometer and an electric arc facility and is designed to analyze powder samples continuously brought into the plasma atomizer (free-burning arc in air). The characteristics of the new spectrometer were compared with those of the Grand spectrometer, which is widely employed in analytical laboratories. It is shown that the use of the Grand-2000 spectrometer to determine the concentration of elements in geological and industrial powder samples does not lead to an obvious improvement in the results. The threefold increase in the spectral resolution of the new spectrometer reduces spectral influences from interfering elements, but the relative systematic error both decreases and increases for different samples. This may indicate the influence of unaccounted-for factors, for example, non-optimal spectra processing algorithms for this device. The results obtained suggest good prospects for the use of the Grand-2000 spectrometer to determine the concentration of elements in samples with a complex spectrum, but they also indicate the need for further studies to determine the optimal parameters for processing spectra. In addition, the Grand-2000 spectrometer can be used to supplement and refine the existing database of the wavelengths of spectral lines.Keywords: MAES, spectrometer, arc atomic emission spectrometry, spectral resolution, geological powder samples, Grand, Grand-2000Β DOI: http://dx.doi.org/10.15826/analitika.2021.25.4.009A.A. Dzyuba1,2, S.V. Dodonov3, and V.A. Labusov1,2,3Β 1Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Koptyuga, 1, Novosibirsk, 630090 Russian Federation2VMK-OptoΓ©lektronika, pr. Akademika Koptyuga, Novosibirsk, 630090,Β Russian FederationΒ 3Novosibirsk State Technical University, pr. K. Marksa, 20, Novosibirsk, 630073, Russian FederationΠ‘ Ρ†Π΅Π»ΡŒΡŽ сниТСния количСства ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½Ρ‹Ρ… Π½Π°Π»ΠΎΠΆΠ΅Π½ΠΈΠΉ Π½Π° аналитичСскиС Π»ΠΈΠ½ΠΈΠΈ опрСдСляСмых элСмСнтов ΠΏΡ€ΠΈ прямом Π°Π½Π°Π»ΠΈΠ·Π΅ гСологичСских ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ² ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ Π΄ΡƒΠ³ΠΎΠ²ΠΎΠΉ Π°Ρ‚ΠΎΠΌΠ½ΠΎ-эмиссионной спСктромСтрии создан спСктромСтр высокого Ρ€Π°Π·Ρ€Π΅ΡˆΠ΅Π½ΠΈΡ Β«Π“Ρ€Π°Π½Π΄-2000Β». Он содСрТит Π΄Π²Π° ΠΏΠ°Ρ€Π°Π»Π»Π΅Π»ΡŒΠ½ΠΎ Ρ€Π°Π±ΠΎΡ‚Π°ΡŽΡ‰ΠΈΡ… ΠΏΠΎΠ»ΠΈΡ…Ρ€ΠΎΠΌΠ°Ρ‚ΠΎΡ€Π° ΠΏΠΎ схСмС ПашСна-Π ΡƒΠ½Π³Π΅. Π‘ΠΏΠ΅ΠΊΡ‚Ρ€Ρ‹ Π² Π΄ΠΈΠ°ΠΏΠ°Π·ΠΎΠ½Π΅ 190-780 Π½ΠΌ Ρ€Π΅Π³ΠΈΡΡ‚Ρ€ΠΈΡ€ΡƒΡŽΡ‚ΡΡ Π°Π½Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π°ΠΌΠΈ МАЭБ. ΠŸΠ΅Ρ€Π²Ρ‹ΠΉ ΠΏΠΎΠ»ΠΈΡ…Ρ€ΠΎΠΌΠ°Ρ‚ΠΎΡ€, Π²Ρ‹ΠΏΠΎΠ»Π½Π΅Π½Π½Ρ‹ΠΉ Π½Π° основС Π²ΠΎΠ³Π½ΡƒΡ‚ΠΎΠΉ Π΄ΠΈΡ„Ρ€Π°ΠΊΡ†ΠΈΠΎΠ½Π½ΠΎΠΉ Ρ€Π΅ΡˆΡ‘Ρ‚ΠΊΠΈ 2400 ΡˆΡ‚Ρ€ΠΈΡ…ΠΎΠ²/ΠΌΠΌ с радиусом ΠΊΡ€ΠΈΠ²ΠΈΠ·Π½Ρ‹ повСрхности ΠΏΠΎΠ΄Π»ΠΎΠΆΠΊΠΈ Π΄Π²Π° ΠΌΠ΅Ρ‚Ρ€Π°, рСгистрируСт ΠΎΠ±Π»Π°ΡΡ‚ΡŒ 190–350 Π½ΠΌ с Ρ€Π°Π·Ρ€Π΅ΡˆΠ΅Π½ΠΈΠ΅ΠΌ 4 ΠΏΠΌ. ЦСль Ρ€Π°Π±ΠΎΡ‚Ρ‹ – ΠΎΡ†Π΅Π½ΠΊΠ° аналитичСских возмоТностСй спСктромСтра Β«Π“Ρ€Π°Π½Π΄-2000Β» с Π»ΠΈΠ½Π΅ΠΉΠΊΠ°ΠΌΠΈ Ρ„ΠΎΡ‚ΠΎΠ΄Π΅Ρ‚Π΅ΠΊΡ‚ΠΎΡ€ΠΎΠ² Π‘Π›ΠŸΠŸ-4000 ΠΏΡƒΡ‚Ρ‘ΠΌ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½ΠΎΠ³ΠΎ сравнСния с ΡˆΠΈΡ€ΠΎΠΊΠΎ ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΠ΅ΠΌΡ‹ΠΌ спСктромСтром Β«Π“Ρ€Π°Π½Π΄Β» с Π»ΠΈΠ½Π΅ΠΉΠΊΠ°ΠΌΠΈ Π‘Π›ΠŸΠŸ-2000 Π² составС комплСкса Β«Π“Ρ€Π°Π½Π΄-ΠŸΠΎΡ‚ΠΎΠΊΒ» с элСктродуговой установкой для Π°Π½Π°Π»ΠΈΠ·Π° ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²Ρ‹Ρ… ΠΏΡ€ΠΎΠ± ΠΏΠΎ способу просыпки-вдувания. Показано, Ρ‡Ρ‚ΠΎ использованиС спСктромСтра Β«Π“Ρ€Π°Π½Π΄-2000Β» ΠΏΡ€ΠΈ Ρ€Π΅ΡˆΠ΅Π½ΠΈΠΈ Π·Π°Π΄Π°Ρ‡ΠΈ опрСдСлСния массовых Π΄ΠΎΠ»Π΅ΠΉ элСмСнтов Π² гСологичСских ΠΈ Ρ‚Π΅Ρ…Π½ΠΎΠ³Π΅Π½Π½Ρ‹Ρ… ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²Ρ‹Ρ… ΠΏΡ€ΠΎΠ±Π°Ρ… Π½Π΅ ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ ΠΊ ΠΎΡ‡Π΅Π²ΠΈΠ΄Π½ΠΎΠΌΡƒ ΡƒΠ»ΡƒΡ‡ΡˆΠ΅Π½ΠΈΡŽ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π°. Π•Π³ΠΎ Ρ‚Ρ€Π΅Ρ…ΠΊΡ€Π°Ρ‚Π½ΠΎΠ΅ прСимущСство ΠΏΠΎ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΌΡƒ Ρ€Π°Π·Ρ€Π΅ΡˆΠ΅Π½ΠΈΡŽ ΡƒΠΌΠ΅Π½ΡŒΡˆΠ°Π΅Ρ‚ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½Ρ‹Π΅ ΠΏΠΎΠΌΠ΅Ρ…ΠΈ со стороны ΠΌΠ΅ΡˆΠ°ΡŽΡ‰ΠΈΡ… элСмСнтов, Π½ΠΎ это ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ ΠΊΠ°ΠΊ ΠΊ ΡƒΠΌΠ΅Π½ΡŒΡˆΠ΅Π½ΠΈΡŽ, Ρ‚Π°ΠΊ ΠΈ ΠΊ ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΡŽ значСния ΠΎΡ‚Π½ΠΎΡΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ систСматичСской ΠΏΠΎΠ³Ρ€Π΅ΡˆΠ½ΠΎΡΡ‚ΠΈ ΠΏΠΎ ΠΌΠΎΠ΄ΡƒΠ»ΡŽ, Ρ‡Ρ‚ΠΎ ΠΌΠΎΠΆΠ΅Ρ‚ Π³ΠΎΠ²ΠΎΡ€ΠΈΡ‚ΡŒ ΠΎ Π΄ΠΎΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΠ½Ρ‹Ρ… Π½Π΅ΡƒΡ‡Ρ‚Π΅Π½Π½Ρ‹Ρ… Π²Π»ΠΈΡΡŽΡ‰ΠΈΡ… Ρ„Π°ΠΊΡ‚ΠΎΡ€Π°Ρ…, Π½Π°ΠΏΡ€ΠΈΠΌΠ΅Ρ€, Π½Π΅ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Ρ… для Π΄Π°Π½Π½ΠΎΠ³ΠΎ ΠΏΡ€ΠΈΠ±ΠΎΡ€Π° Π°Π»Π³ΠΎΡ€ΠΈΡ‚ΠΌΠΎΠ² ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠΈ спСктров. ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Π΅ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ ΠΏΠΎΠΊΠ°Π·Ρ‹Π²Π°ΡŽΡ‚ Ρ…ΠΎΡ€ΠΎΡˆΠΈΠ΅ пСрспСктивы ΠΏΡ€ΠΈ использовании спСктромСтра Β«Π“Ρ€Π°Π½Π΄-2000Β» для опрСдСлСния массовых Π΄ΠΎΠ»Π΅ΠΉ элСмСнтов Π² ΠΏΡ€ΠΎΠ±Π°Ρ… со слоТным спСктром, Π½ΠΎ Ρ‚Π°ΠΊΠΆΠ΅ ΡƒΠΊΠ°Π·Ρ‹Π²Π°ΡŽΡ‚ Π½Π° Π½Π΅ΠΎΠ±Ρ…ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ провСдСния Π΄ΠΎΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΠ½Ρ‹Ρ… исслСдований для опрСдСлСния ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Ρ… ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠΈ спСктров. ΠšΡ€ΠΎΠΌΠ΅ Ρ‚ΠΎΠ³ΠΎ, выявлСна Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡ‚ΡŒ примСнСния спСктромСтр Β«Π“Ρ€Π°Π½Π΄-2000Β» для уточнСния ΠΈ ΠΊΠΎΡ€Ρ€Π΅ΠΊΡ‚ΠΈΡ€ΠΎΠ²ΠΊΠΈ ΡΡƒΡ‰Π΅ΡΡ‚Π²ΡƒΡŽΡ‰Π΅ΠΉ Π±Π°Π·Ρ‹ Π΄Π°Π½Π½Ρ‹Ρ… Π΄Π»ΠΈΠ½ Π²ΠΎΠ»Π½ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½Ρ‹Ρ… Π»ΠΈΠ½ΠΈΠΉ.ΠšΠ»ΡŽΡ‡Π΅Π²Ρ‹Π΅ слова: ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½Ρ‹ΠΉ комплСкс Β«Π“Ρ€Π°Π½Π΄-ΠŸΠΎΡ‚ΠΎΠΊΒ», Β«Π“Ρ€Π°Π½Π΄-2000Β», Π±Ρ‹ΡΡ‚Ρ€ΠΎΠ΄Π΅ΠΉΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΠΉ Π°Π½Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€ МАЭБ, ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠ΅ Ρ€Π°Π·Ρ€Π΅ΡˆΠ΅Π½ΠΈΠ΅, гСологичСскиС ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²Ρ‹Π΅ ΠΏΡ€ΠΎΠ±Ρ‹, Π°Ρ‚ΠΎΠΌΠ½ΠΎ-эмиссионная спСктромСтрияDOI: http://dx.doi.org/10.15826/analitika.2021.25.4.00

    Measurement of the isospin-filtering dd -> 4He K+ K- reaction at Q=39 MeV

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    The total cross section for the dd -> 4He K+ K- reaction has been measured at a beam momentum of 3.7 GeV/c, corresponding to an excess energy of 39 MeV, which is the maximum possible at the Cooler Synchrotron COSY-J\"{u}lich. A deuterium cluster-jet target and the ANKE forward magnetic spectrometer, placed inside the storage ring, have been employed in this investigation. We find a total cross section of sigma(tot) < 14 pb, which brings into question the viability of investigating the dd -> 4He a0(980) reaction as a means of studying isospin violation.Comment: Five pages with three eps figure

    The energy dependence of the pp->K+ n Sigma+ reaction close to threshold

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    The production of the Sigma+ hyperon through the pp->K+nSigma+ reaction has been investigated at four energies close to threshold, 1.826, 1.920, 1.958, and 2.020 GeV. At low energies, correlated K+pi+ pairs can only originate from Sigma+ production so that their measurement allows the total cross section for the reaction to be determined. The results obtained are completely consistent with the values extracted from the study of the K+-proton correlation spectra obtained in the same experiment. These spectra, as well as the inclusive K+ momentum distributions, also provide conservative upper limits on the Sigma+ production rates. The measurements show a Sigma+ production cross section that varies roughly like phase space and, in particular, none of the three experimental approaches used supports the anomalously high near-threshold pp->K+ nSigma+ total cross section previously reported [T. Rozek et al., Phys. Lett. B 643, 251 (2006)].Comment: Submitted to PR

    BASIC EXPOSURE TIME OPTIMIZATION OF A SOLID-STATE RADIATION DETECTOR IN SCINTILLATION ATOMIC EMISSION SPECTROMETRY

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    An experimental study of the signal-to-noise ratio in scintillation atomic-emission spectrometry was performed to optimize basic exposure time of the solid-state detectors using as an example a BLPP-2000 photodiode array produced by VMK-Optoelektronika. Obtained dependences of the signal-to-noise ratio on this exposure time confirm the corresponding formula that takes into account the following parameters: the shape and duration of scintillations of spectral lines; the number of photoelectrons generated by scintillations; dark current and background photocurrent; read noise, synchronization mode. Single-channel recording of simulated flashes of a light-emitting diode and simultaneous dual-channel recording of scintillations of the gold Au 267.595-nm line from the injection of powdered geological samples into an electric arc were used. An equation was derived to estimate the optimal exposure time. The calculated and experimental data for the BLPP 2000 array show that the optimal exposure time for recording the analyte microparticles of the size of interest is approximately equal to the length of their flashes.Β Keywords: time-resolved spectroscopy, atomic emission spectral analysis, powdered geological samples, scintillation, multi-element solid-state detectors, detection limit reduction, optimal exposure time(Russian)DOI:http://dx.doi.org/10.15826/analitika.2015.19.1.005A.A.Β Dzyuba1, 2 , 3, Β V.A.Β Labusov1, 2 , 3, S.A.Β Babin1. 21Institute of Automation and Electrometry, Novosibirsk, Russian Federation2VMK-Optoelektronika, Novosibirsk, Russian Federation3Novosibirsk State Technical University, Novosibirsk, Russian FederationAn experimental study of the signal-to-noise ratio in scintillation atomic-emission spectrometry was performed to optimize basic exposure time of the solid-state detectors using as an example a BLPP-2000 photodiode array produced by VMK-Optoelektronika. Obtained dependences of the signal-to-noise ratio on this exposure time confirm the corresponding formula that takes into account the following parameters: the shape and duration of scintillations of spectral lines; the number of photoelectrons generated by scintillations; dark current and background photocurrent; read noise, synchronization mode. Single-channel recording of simulated flashes of a light-emitting diode and simultaneous dual-channel recording of scintillations of the gold Au 267.595-nm line from the injection of powdered geological samples into an electric arc were used. An equation was derived to estimate the optimal exposure time. The calculated and experimental data for the BLPP 2000 array show that the optimal exposure time for recording the analyte microparticles of the size of interest is approximately equal to the length of their flashes.Β Keywords: time-resolved spectroscopy, atomic emission spectral analysis, powdered geological samples, scintillation, multi-element solid-state detectors, detection limit reduction, optimal exposure time.Β DOI:http://dx.doi.org/10.15826/analitika.2015.19.1.005

    Basic exposure time optimization of a solid-state radiation detector in scintillation atomic emission spectrometry

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    Для ΠΎΠΏΡ‚ΠΈΠΌΠΈΠ·Π°Ρ†ΠΈΠΈ Π±Π°Π·ΠΎΠ²ΠΎΠΉ экспозиции Ρ‚Π²Π΅Ρ€Π΄ΠΎΡ‚Π΅Π»ΡŒΠ½ΠΎΠ³ΠΎ Π΄Π΅Ρ‚Π΅ΠΊΡ‚ΠΎΡ€Π° Π½Π° ΠΏΡ€ΠΈΠΌΠ΅Ρ€Π΅ ΠΎΠΏΡ‹Ρ‚Π½ΠΎΠΉ Π»ΠΈΠ½Π΅ΠΉΠΊΠΈ Π‘Π›ΠŸΠŸ-2000 производства Β«Π’ΠœΠš-ΠžΠΏΡ‚ΠΎΡΠ»Π΅ΠΊΡ‚Ρ€ΠΎΠ½ΠΈΠΊΠ°Β» ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΎ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½ΠΎΠ΅ исслСдованиС ΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ сигнал-ΡˆΡƒΠΌ ΠΏΡ€ΠΈ сцинтилляционном Π°Ρ‚ΠΎΠΌΠ½ΠΎ-эмиссионном ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΌ Π°Π½Π°Π»ΠΈΠ·Π΅. ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ зависимости ΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ сигнал-ΡˆΡƒΠΌ ΠΎΡ‚ Π²Ρ€Π΅ΠΌΠ΅Π½ΠΈ этой экспозиции, ΠΏΠΎΠ΄Ρ‚Π²Π΅Ρ€ΠΆΠ΄Π°ΡŽΡ‰ΠΈΠ΅ ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‰ΡƒΡŽ Ρ„ΠΎΡ€ΠΌΡƒΠ»Ρƒ, которая ΡƒΡ‡ΠΈΡ‚Ρ‹Π²Π°Π΅Ρ‚ ΡΠ»Π΅Π΄ΡƒΡŽΡ‰ΠΈΠ΅ ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€Ρ‹: Ρ„ΠΎΡ€ΠΌΠ° ΠΈ ΠΏΡ€ΠΎΠ΄ΠΎΠ»ΠΆΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ Π²ΡΠΏΡ‹ΡˆΠΊΠΈ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΉ Π»ΠΈΠ½ΠΈΠΈ; количСство фотоэлСктронов, ΠΏΠΎΡ€ΠΎΠΆΠ΄Π΅Π½Π½Ρ‹Ρ… Π²ΡΠΏΡ‹ΡˆΠΊΠΎΠΉ; Ρ‚Π΅ΠΌΠ½ΠΎΠ²ΠΎΠΉ Ρ‚ΠΎΠΊ ΠΈ Ρ„ΠΎΡ‚ΠΎΡ‚ΠΎΠΊ ΠΎΡ‚ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠ³ΠΎ Ρ„ΠΎΠ½Π°; ΡˆΡƒΠΌ чтСния, Ρ€Π΅ΠΆΠΈΠΌ синхронизации. ΠŸΡ€ΠΈ этом использовали ΠΎΠ΄Π½ΠΎΠΊΠ°Π½Π°Π»ΡŒΠ½ΡƒΡŽ Ρ€Π΅Π³ΠΈΡΡ‚Ρ€Π°Ρ†ΠΈΡŽ ΠΈΠΌΠΈΡ‚Π°Ρ†ΠΈΠΎΠ½Π½Ρ‹Ρ… Π²ΡΠΏΡ‹ΡˆΠ΅ΠΊ ΠΎΡ‚ свСтодиода, Π° Ρ‚Π°ΠΊΠΆΠ΅ ΠΎΠ΄Π½ΠΎΠ²Ρ€Π΅ΠΌΠ΅Π½Π½ΡƒΡŽ Π΄Π²ΡƒΡ…ΠΊΠ°Π½Π°Π»ΡŒΠ½ΡƒΡŽ Ρ€Π΅Π³ΠΈΡΡ‚Ρ€Π°Ρ†ΠΈΡŽ сцинтилляций Π·ΠΎΠ»ΠΎΡ‚Π° Π½Π° Π»ΠΈΠ½ΠΈΠΈ Au 267.595 Π½ΠΌ ΠΎΡ‚ просыпки ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²ΠΎΠΉ гСологичСской ΠΏΡ€ΠΎΠ±Ρ‹ Π² элСктричСской Π΄ΡƒΠ³Π΅. ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½ΠΎ ΡƒΡ€Π°Π²Π½Π΅Π½ΠΈΠ΅ для ΠΎΡ†Π΅Π½ΠΊΠΈ ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½ΠΎΠ³ΠΎ Π²Ρ€Π΅ΠΌΠ΅Π½ΠΈ экспозиции. Для Π»ΠΈΠ½Π΅ΠΉΠΊΠΈ Π‘Π›ΠŸΠŸ-2000 расчСт ΠΈ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Π΅ Π΄Π°Π½Π½Ρ‹Π΅ согласованно ΠΏΠΎΠΊΠ°Π·Ρ‹Π²Π°ΡŽΡ‚, Ρ‡Ρ‚ΠΎ ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Π°Ρ экспозиция для рСгистрации ΠΈΠ½Ρ‚Π΅Ρ€Π΅ΡΡƒΡŽΡ‰ΠΈΡ… ΠΏΠΎ Ρ€Π°Π·ΠΌΠ΅Ρ€Ρƒ микрочастиц Π°Π½Π°Π»ΠΈΡ‚Π° ΠΏΡ€ΠΈΠ±Π»ΠΈΠ·ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ Ρ€Π°Π²Π½Π° ΠΏΡ€ΠΎΠ΄ΠΎΠ»ΠΆΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΡΡ‚ΠΈ ΠΈΡ… Π²ΡΠΏΡ‹ΡˆΠ΅ΠΊ.An experimental study of the signal-to-noise ratio in scintillation atomic-emission spectrometry was performed to optimize basic exposure time of the solid-state detectors using as an example a BLPP-2000 photodiode array produced by VMK-Optoelektronika. Obtained dependences of the signal-to-noise ratio on this exposure time confirm the corresponding formula that takes into account the following parameters: the shape and duration of scintillations of spectral lines; the number of photoelectrons generated by scintillations; dark current and background photocurrent; read noise, synchronization mode. Single-channel recording of simulated flashes of a light-emitting diode and simultaneous dual-channel recording of scintillations of the gold Au 267.595-nm line from the injection of powdered geological samples into an electric arc were used. An equation was derived to estimate the optimal exposure time. The calculated and experimental data for the BLPP 2000 array show that the optimal exposure time for recording the analyte microparticles of the size of interest is approximately equal to the length of their flashes
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