Clean and Dirty Superconductivity in Pure, Al doped, and Neutron Irradiated MgB2: a Far-Infrared Study

The effects of Al substitution and neutron irradiation on the conduction regime (clean or dirty) of the $\pi$- and $\sigma$-band of MgB$_{2}$ have been investigated by means of far-infrared spectroscopy. The intensity reflected by well characterized polycrystalline samples was measured up to 100 cm$^{- 1}$ in both normal and superconducting state. The analysis of the superconducting to normal reflectivity ratios shows that only the effect of the opening of the small gap in the dirty $\pi$-band can be clearly observed in pure MgB$_{2}$, consistently with previous results. In Al-doped samples the dirty character of the $\pi$-band is increased, while no definitive conclusion on the conduction regime of the $\sigma$-band can be drawn. On the contrary, results obtained for the irradiated sample show that the irradiation-induced disorder drives the $\sigma$-band in the dirty regime, making the large gap in $\sigma$-band observable for the first time in far-infrared measurements.Comment: 11 pages, 1 figur

Interplay of the electronic and lattice degrees of freedom in A_{1-x}Fe_{2-y}Se_{2} superconductors under pressure

The local structure and electronic properties of Rb$_{1-x}$Fe$_{2-y}$Se$_2$ are investigated by means of site selective polarized x-ray absorption spectroscopy at the iron and selenium K-edges as a function of pressure. A combination of dispersive geometry and novel nanodiamond anvil pressure-cell has permitted to reveal a step-like decrease in the Fe-Se bond distance at $p\simeq11$ GPa. The position of the Fe K-edge pre-peak, which is directly related to the position of the chemical potential, remains nearly constant until $\sim6$ GPa, followed by an increase until $p\simeq 11$ GPa. Here, as in the local structure, a step-like decrease of the chemical potential is seen. Thus, the present results provide compelling evidence that the origin of the reemerging superconductivity in $A_{1-x}$Fe$_{2-y}$Se$_2$ in vicinity of a quantum critical transition is caused mainly by the changes in the electronic structure

Molecular ions in L1544. II. The ionization degree

The maps presented in Paper I are here used to infer the variation of the column densities of HCO+, DCO+, N2H+, and N2D+ as a function of distance from the dust peak. These results are interpreted with the aid of a crude chemical model which predicts the abundances of these species as a function of radius in a spherically symmetric model with radial density distribution inferred from the observations of dust emission at millimeter wavelengths and dust absorption in the infrared. Our main observational finding is that the N(N2D+)/N(N2H+) column density ratio is of order 0.2 towards the L1544 dust peak as compared to N(DCO+)/N(HCO+) = 0.04. We conclude that this result as well as the general finding that N2H+ and N2D+ correlate well with the dust is caused by CO being depleted to a much higher degree than molecular nitrogen in the high density core of L1544. Depletion also favors deuterium enhancement and thus N2D+, which traces the dense and highly CO-depleted core nucleus, is much more enhanced than DCO+. Our models do not uniquely define the chemistry in the high density depleted nucleus of L1544 but they do suggest that the ionization degree is a few times 10^{-9} and that the ambipolar diffusion time scale is locally similar to the free fall time. It seems likely that the lower limit which one obtains to ionization degree by summing all observable molecular ions is not a great underestimate of the true ionization degree. We predict that atomic oxygen is abundant in the dense core and, if so, H3O+ may be the main ion in the central highly depleted region of the core.Comment: 31 pages, 8 figures, to be published in Ap

Rotational and high-resolution infrared spectrum of HC3_3N: global ro-vibrational analysis and improved line catalogue for astrophysical observations

HC$_3$N is an ubiquitous molecule in interstellar environments, from external galaxies, to Galactic interstellar clouds, star forming regions, and planetary atmospheres. Observations of its rotational and vibrational transitions provide important information on the physical and chemical structure of the above environments. We present the most complete global analysis of the spectroscopic data of HC$_3$N. We have recorded the high-resolution infrared spectrum from 450 to 1350 cm$^{-1}$, a region dominated by the intense $\nu_5$ and $\nu_6$ fundamental bands, located at 660 and 500 cm$^{-1}$, respectively, and their associated hot bands. Pure rotational transitions in the ground and vibrationally excited states have been recorded in the millimetre and sub-millimetre regions in order to extend the frequency range so far considered in previous investigations. All the transitions from the literature and from this work involving energy levels lower than 1000 cm$^{-1}$ have been fitted together to an effective Hamiltonian. Because of the presence of various anharmonic resonances, the Hamiltonian includes a number of interaction constants, in addition to the conventional rotational and vibrational l-type resonance terms. The data set contains about 3400 ro-vibrational lines of 13 bands and some 1500 pure rotational lines belonging to 12 vibrational states. More than 120 spectroscopic constants have been determined directly from the fit, without any assumption deduced from theoretical calculations or comparisons with similar molecules. An extensive list of highly accurate rest frequencies has been produced to assist astronomical searches and data interpretation. These improved data, have enabled a refined analysis of the ALMA observations towards Sgr B2(N2).Comment: 35 pages, 14 figures, accepted for pubblication in ApJ Supplemen

Confinement effects on glass forming liquids probed by DMA

Many molecular glass forming liquids show a shift of the glass transition T-g to lower temperatures when the liquid is confined into mesoporous host matrices. Two contrary explanations for this effect are given in literature: First, confinement induced acceleration of the dynamics of the molecules leads to an effective downshift of T-g increasing with decreasing pore size. Second, due to thermal mismatch between the liquid and the surrounding host matrix, negative pressure develops inside the pores with decreasing temperature, which also shifts T-g to lower temperatures. Here we present dynamic mechanical analysis measurements of the glass forming liquid salol in Vycor and Gelsil with pore sizes of d=2.6, 5.0 and 7.5 nm. The dynamic complex elastic susceptibility data can be consistently described with the assumption of two relaxation processes inside the pores: A surface induced slowed down relaxation due to interaction with rough pore interfaces and a second relaxation within the core of the pores. This core relaxation time is reduced with decreasing pore size d, leading to a downshift of T-g proportional to 1/d in perfect agreement with recent differential scanning calorimetry (DSC) measurements. Thermal expansion measurements of empty and salol filled mesoporous samples revealed that the contribution of negative pressure to the downshift of T-g is small (<30%) and the main effect is due to the suppression of dynamically correlated regions of size xi when the pore size xi approaches

Ecosystem carbon 7 dioxide fluxes after disturbance in forests of North America

Disturbances are important for renewal of North American forests. Here we summarize more than 180 site years of eddy covariance measurements of carbon dioxide flux made at forest chronosequences in North America. The disturbances included stand-replacing fire (Alaska, Arizona, Manitoba, and Saskatchewan) and harvest (British Columbia, Florida, New Brunswick, Oregon, Quebec, Saskatchewan, and Wisconsin) events, insect infestations (gypsy moth, forest tent caterpillar, and mountain pine beetle), Hurricane Wilma, and silvicultural thinning (Arizona, California, and New Brunswick). Net ecosystem production (NEP) showed a carbon loss from all ecosystems following a stand-replacing disturbance, becoming a carbon sink by 20 years for all ecosystems and by 10 years for most. Maximum carbon losses following disturbance (g C m−2y−1) ranged from 1270 in Florida to 200 in boreal ecosystems. Similarly, for forests less than 100 years old, maximum uptake (g C m−2y−1) was 1180 in Florida mangroves and 210 in boreal ecosystems. More temperate forests had intermediate fluxes. Boreal ecosystems were relatively time invariant after 20 years, whereas western ecosystems tended to increase in carbon gain over time. This was driven mostly by gross photosynthetic production (GPP) because total ecosystem respiration (ER) and heterotrophic respiration were relatively invariant with age. GPP/ER was as low as 0.2 immediately following stand-replacing disturbance reaching a constant value of 1.2 after 20 years. NEP following insect defoliations and silvicultural thinning showed lesser changes than stand-replacing events, with decreases in the year of disturbance followed by rapid recovery. NEP decreased in a mangrove ecosystem following Hurricane Wilma because of a decrease in GPP and an increase in ER

Herpes Simplex Virus 1 and Chlamydophila (Chlamydia) pneumoniae promote Ab 1-42 amyloid processing in murine astrocytes linking an infectious process to Alzheimer\u27s disease

Background: Several studies have suggested an infectious etiology for Alzheimer\u27s disease (AD). Previously, our laboratory identified Chlamydia pneumoniae (Cpn) from autopsied sporadic AD brains, as well as developed a BALB/c mouse model that demonstrated infection-induced amyloid plaques similar to those found in AD. Hypothesis: We propose that an additional pathogen such as herpes simplex virus type 1 (HSV1), also may be a contributing factor in toin the pathology seen in AD. HSV1, in addition to Cpn, may be triggering the abnormal cleavage of the beta amyloid precursor protein (bAPP) into Ab1-42 , thereby contributing to amyloid plaque formation. Our current study examines amyloid processing following infection of primary and C8-DIA murine astrocytes with Cpn and HSV1. Materials and Methods: Immunocytochemistry and western analysis was used to analyze the outcome of infection by these two pathogens. Results: Cpn infection resulted in an increase in cytoplasmic labeling of Ab 1-42 relative to uninfected cells, while increased nuclear labeling of Ab 1-42 was observed following HSV1 infection. Co-infections with Cpn and HSV1 resulted in amyloid labeling resembling that of HSV1 infection alone, though Ab 1-42 labeling appeared decreased specifically in Cpn-infected cells of the co-infected monolayers. Conclusions: These data suggest that infection of astrocytic cells by HSV1 and (Cpn) alter the processing of bAPP, thereby producing Ab1-42. Therefore, these studies, inaddition to the previous research reported by our laboratory, support an emerging linkage of the infectious processs to the neuropathology characteristic of Alzheimer\u27s disease.https://digitalcommons.pcom.edu/posters/1008/thumbnail.jp

Multi-gap superconductivity in a BaFe1.84Co0.16As2 film from optical measurements at terahertz frequencies

We measured the THz reflectance properties of a high quality epitaxial thin film of the Fe-based superconductor BaFe$_{1.84}$Co$_{0.16}$As$_2$ with T$_c$=22.5 K. The film was grown by pulsed laser deposition on a DyScO$_3$ substrate with an epitaxial SrTiO$_3$ intermediate layer. The measured $R_S/R_N$ spectrum, i.e. the reflectivity ratio between the superconducting and normal state reflectance, provides clear evidence of a superconducting gap $\Delta_A$ close to 15 cm$^{-1}$. A detailed data analysis shows that a two-band, two-gap model is absolutely necessary to obtain a good description of the measured $R_S/R_N$ spectrum. The low-energy $\Delta_A$ gap results to be well determined ($\Delta_A$=15.5$\pm$0.5 cm$^{-1}$), while the value of the high-energy gap $\Delta_B$ is more uncertain ($\Delta_B$=55$\pm$7 cm$^{-1}$). Our results provide evidence of a nodeless isotropic double-gap scenario, with the presence of two optical gaps corresponding to 2$\Delta/kT_c$ values close to 2 and 7.Comment: Published Versio

Fast, exact CMB power spectrum estimation for a certain class of observational strategies

We describe a class of observational strategies for probing the anisotropies in the cosmic microwave background (CMB) where the instrument scans on rings which can be combined into an n-torus, the {\em ring torus}. This class has the remarkable property that it allows exact maximum likelihood power spectrum estimation in of order $N^2$ operations (if the size of the data set is $N$) under circumstances which would previously have made this analysis intractable: correlated receiver noise, arbitrary asymmetric beam shapes and far side lobes, non-uniform distribution of integration time on the sky and partial sky coverage. This ease of computation gives us an important theoretical tool for understanding the impact of instrumental effects on CMB observables and hence for the design and analysis of the CMB observations of the future. There are members of this class which closely approximate the MAP and Planck satellite missions. We present a numerical example where we apply our ring torus methods to a simulated data set from a CMB mission covering a 20 degree patch on the sky to compute the maximum likelihood estimate of the power spectrum $C_\ell$ with unprecedented efficiency.Comment: RevTeX, 14 pages, 5 figures. A full resolution version of Figure 1 and additional materials are at http://feynman.princeton.edu/~bwandelt/RT