Attractions between charged colloids at water interfaces

The effective potential between charged colloids trapped at water interfaces is analyzed. It consists of a repulsive electrostatic and an attractive capillary part which asymptotically both show dipole--like behavior. For sufficiently large colloid charges, the capillary attraction dominates at large separations. The total effective potential exhibits a minimum at intermediate separations if the Debye screening length of water and the colloid radius are of comparable size.Comment: 8 pages, 1 figure, revised version (one paragraph added) accepted in JPC

Theory of capillary-induced interactions beyond the superposition approximation

Within a general theoretical framework we study the effective, deformation-induced interaction between two colloidal particles trapped at a fluid interface in the regime of small deformations. In many studies, this interaction has been computed with the ansatz that the actual interface configuration for the pair is given by the linear superposition of the interface deformations around the single particles. Here we assess the validity of this approach and compute the leading term of the effective interaction for large interparticle separation beyond this so-called superposition approximation. As an application, we consider the experimentally relevant case of interface deformations owing to the electrostatic field emanating from charged colloidal particles. In mechanical isolation, i.e., if the net force acting on the total system consisting of the particles plus the interface vanishes, the superposition approximation is actually invalid. The effective capillary interaction is governed by contributions beyond this approximation and turns out to be attractive. For sufficiently small surface charges on the colloids, such that linearization is strictly valid, and at asymptotically large separations, the effective interaction does not overcome the direct electrostatic repulsion between the colloidal particles.Comment: Minor typos correcte

Nonequilibrium critical dynamics of the three-dimensional gauge glass

We study the non-equilibrium aging behavior of the gauge glass model in three dimensions at the critical temperature. We perform Monte Carlo simulations with a Metropolis update, and correlation and response functions are calculated for different waiting times. We obtain a multiplicative aging scaling of the correlation and response functions, calculating the aging exponent $b$ and the nonequilibrium autocorrelation decay exponent $\lambda_c/z_c$. We also analyze the fluctuation-dissipation relationship at the critical temperature, obtaining the critical fluctuation-dissipation ratio $X_\infty$. By comparing our results with the aging scaling reported previously for a model of interacting flux lines in the vortex glass regime, we found that the exponents for both models are very different.Comment: 7 pages, 4 figures. Manuscript accpeted for publication in PR

Collective dynamics of chemically active particles trapped at a fluid interface

Chemically active colloids generate changes in the chemical composition of their surrounding solution and thereby induce flows in the ambient fluid which affect their dynamical evolution. Here we study the many-body dynamics of a monolayer of active particles trapped at a fluid-fluid interface. To this end we consider a mean-field model which incorporates the direct pair interaction (including also the capillary interaction which is caused specifically by the interfacial trapping) as well as the effect of hydrodynamic interactions (including the Marangoni flow induced by the response of the interface to the chemical activity). The values of the relevant physical parameters for typical experimental realizations of such systems are estimated and various scenarios, which are predicted by our approach for the dynamics of the monolayer, are discussed. In particular, we show that the chemically-induced Marangoni flow can prevent the clustering instability driven by the capillary attraction.Comment: 8 pages, 2 figure

Two dynamic exponents in the resistive transition of fully frustrated Josephson-junction arrays

We study the resistive transition in Josephson-junction arrays at $f=1/2$ flux quantum per plaquette by dynamical simulations of the resistively-shunted-junction model. The current-voltage scaling and critical dynamics of the phases are found to be well described by the same critical temperature and static exponents as for the chiral (vortex-lattice) transition. Although this behavior is consistent with a single transition scenario, where phase and chiral variables order simultaneously, two different dynamic exponents result for phase coherence and chiral order.Comment: 4 pages, 3 figures, to appear in Europhysics Letter

Anomalous scaling in a non local growth model in the Kardar-Parisi-Zhang universality class

We study the interface dynamics of a discrete model to quantitatively describe electrochemical deposition experiments. Extensive numerical simulations indicate that the interface dynamics is unstable at early times, but asymptotically displays the scaling of the Kardar-Parisi-Zhang universality class. During the time interval in which the surface is unstable, its power spectrum is anomalous; hence the behaviors at length scales smaller than or comparable with the system size are described by different roughness exponents. These results are expected to apply to a wide range of electrochemical deposition experiments.Comment: REVTEX (4 pages) and three figures (postscript), to be published in PRE (rapid communication, March, 1998