2,866 research outputs found
N-heterocyclic germylenes: structural characterisation of some heavy analogues of the ubiquitous N-heterocyclic carbenes
The X-ray crystal structures of three N-heterocyclic germylenes (NHGes) have been elucidated including the previously unknown 1,3-bis(2,6-dimethylphenyl)diazagermol-2-ylidene (1). In addition, the X-ray crystal structures of the previously synthesised 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene (2) and 1,3-bis(2,6-diisopropylphenyl)diazagermol-2-ylidene (3) are also reported. The discrete molecular structures of compounds 1 to 3 are comparable, with Ge-N bond lengths in the range 1.835-1.875 Å, while the N-Ge-N bond angles range between 83.6 and 85.2°. Compound 2 was compared to the analogous N-heterocyclic carbene species, 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes). The major geometrical difference observed, as expected, was the bond angle around the divalent group 14 atom. The N-Ge-N bond angle was 83.6° for compound 2 versus the N-C-N bond angle of 101.4° for IMes. The Sn equivalent of (1), 1,3-bis(2,6-dimethylphenyl)diazastannol-2-ylidene (4), has also been synthesised and its crystal structure is reported here. In order to test their suitability as ligands, compounds 1 to 3 were reacted with a wide range of transition metal complexes. No NHGes containing metal complexes were observed. In all cases the NHGe either degraded or gave no reaction
Engineering evaluations and studies. Report for Ku-band studies, exhibit A
System performance aspects of the Ku band radar communication hardware and investigations into the Ku band/payload interfaces are discussed. The communications track problem caused by the excessive signal dynamic range at the servo input was investigated. The management/handover logic is discussed and a simplified description of the transmitter enable logic function is presented. Output noise produced by a voltage-controlled oscillator chip used in the SPA return-link channel 3 mid-bit detector is discussed. The deployed assembly (DA) and EA-2 critical design review data are evaluated. Cross coupling effects on antenna servo stability were examined. A series of meetings on the acceptance test specification for the deployed assembly is summarized
Nipigon River Landslide
A massive landslide occurred on the Nipigon River, north of the Town of Nipigon, Ontario, Canada in the early morning hours of April 23, 1990 and involved an estimated 300,000 cu m of soil. Although there was no loss of life, there were significant environmental and economic impacts. Discussed in this paper are the investigations carried out after the slide, the events prior to and the factors contributing to, the slide
An Inverse Compton Scattering Origin of X-ray Flares from Sgr A*
The X-ray and near-IR emission from Sgr A* is dominated by flaring, while a
quiescent component dominates the emission at radio and sub-mm wavelengths. The
spectral energy distribution of the quiescent emission from Sgr A* peaks at
sub-mm wavelengths and is modeled as synchrotron radiation from a thermal
population of electrons in the accretion flow, with electron temperatures
ranging up to \,MeV. Here we investigate the mechanism by which
X-ray flare emission is produced through the interaction of the quiescent and
flaring components of Sgr A*. The X-ray flare emission has been interpreted as
inverse Compton, self-synchrotron-Compton, or synchrotron emission. We present
results of simultaneous X-ray and near-IR observations and show evidence that
X-ray peak flare emission lags behind near-IR flare emission with a time delay
ranging from a few to tens of minutes. Our Inverse Compton scattering modeling
places constraints on the electron density and temperature distributions of the
accretion flow and on the locations where flares are produced. In the context
of this model, the strong X-ray counterparts to near-IR flares arising from the
inner disk should show no significant time delay, whereas near-IR flares in the
outer disk should show a broadened and delayed X-ray flare.Comment: 22 pages, 6 figures, 2 tables, AJ (in press
Geometry of River Networks I: Scaling, Fluctuations, and Deviations
This article is the first in a series of three papers investigating the
detailed geometry of river networks. Large-scale river networks mark an
important class of two-dimensional branching networks, being not only of
intrinsic interest but also a pervasive natural phenomenon. In the description
of river network structure, scaling laws are uniformly observed. Reported
values of scaling exponents vary suggesting that no unique set of scaling
exponents exists. To improve this current understanding of scaling in river
networks and to provide a fuller description of branching network structure, we
report here a theoretical and empirical study of fluctuations about and
deviations from scaling. We examine data for continent-scale river networks
such as the Mississippi and the Amazon and draw inspiration from a simple model
of directed, random networks. We center our investigations on the scaling of
the length of sub-basin's dominant stream with its area, a characterization of
basin shape known as Hack's law. We generalize this relationship to a joint
probability density and show that fluctuations about scaling are substantial.
We find strong deviations from scaling at small scales which can be explained
by the existence of linear network structure. At intermediate scales, we find
slow drifts in exponent values indicating that scaling is only approximately
obeyed and that universality remains indeterminate. At large scales, we observe
a breakdown in scaling due to decreasing sample space and correlations with
overall basin shape. The extent of approximate scaling is significantly
restricted by these deviations and will not be improved by increases in network
resolution.Comment: 16 pages, 13 figures, Revtex4, submitted to PR
Space Shuttle program communication and tracking systems interface analysis
The Space Shuttle Program Communications and Tracking Systems Interface Analysis began April 18, 1983. During this time, the shuttle communication and tracking systems began flight testing. Two areas of analysis documented were a result of observations made during flight tests. These analyses involved the Ku-band communication system. First, there was a detailed analysis of the interface between the solar max data format and the Ku-band communication system including the TDRSS ground station. The second analysis involving the Ku-band communication system was an analysis of the frequency lock loop of the Gunn oscillator used to generate the transmit frequency. The stability of the frequency lock loop was investigated and changes to the design were reviewed to alleviate the potential loss of data due the loop losing lock and entering the reacquisition mode. Other areas of investigation were the S-band antenna analysis and RF coverage analysis
Flares and variability from Sagittarius A*: five nights of simultaneous multi-wavelength observations
Aims. We report on simultaneous observations and modeling of mid-infrared
(MIR), near-infrared (NIR), and submillimeter (submm) emission of the source
Sgr A* associated with the supermassive black hole at the center of our Galaxy.
Our goal was to monitor the activity of Sgr A* at different wavelengths in
order to constrain the emitting processes and gain insight into the nature of
the close environment of Sgr A*. Methods. We used the MIR instrument VISIR in
the BURST imaging mode, the adaptive optics assisted NIR camera NACO, and the
sub-mm antenna APEX to monitor Sgr A* over several nights in July 2007.
Results. The observations reveal remarkable variability in the NIR and sub-mm
during the five nights of observation. No source was detected in the MIR, but
we derived the lowest upper limit for a flare at 8.59 microns (22.4 mJy with
A_8.59mu = 1.6+/- 0.5). This observational constraint makes us discard the
observed NIR emission as coming from a thermal component emitting at sub-mm
frequencies. Moreover, comparison of the sub-mm and NIR variability shows that
the highest NIR fluxes (flares) are coincident with the lowest sub-mm levels of
our five-night campaign involving three flares. We explain this behavior by a
loss of electrons to the system and/or by a decrease in the magnetic field, as
might conceivably occur in scenarios involving fast outflows and/or magnetic
reconnection.Comment: 10 pages, 7 figures, published in A&
Geometry of River Networks II: Distributions of Component Size and Number
The structure of a river network may be seen as a discrete set of nested
sub-networks built out of individual stream segments. These network components
are assigned an integral stream order via a hierarchical and discrete ordering
method. Exponential relationships, known as Horton's laws, between stream order
and ensemble-averaged quantities pertaining to network components are observed.
We extend these observations to incorporate fluctuations and all higher moments
by developing functional relationships between distributions. The relationships
determined are drawn from a combination of theoretical analysis, analysis of
real river networks including the Mississippi, Amazon and Nile, and numerical
simulations on a model of directed, random networks. Underlying distributions
of stream segment lengths are identified as exponential. Combinations of these
distributions form single-humped distributions with exponential tails, the sums
of which are in turn shown to give power law distributions of stream lengths.
Distributions of basin area and stream segment frequency are also addressed.
The calculations identify a single length-scale as a measure of size
fluctuations in network components. This article is the second in a series of
three addressing the geometry of river networks.Comment: 16 pages, 13 figures, 4 tables, Revtex4, submitted to PR
Positivity of the English language
Over the last million years, human language has emerged and evolved as a
fundamental instrument of social communication and semiotic representation.
People use language in part to convey emotional information, leading to the
central and contingent questions: (1) What is the emotional spectrum of natural
language? and (2) Are natural languages neutrally, positively, or negatively
biased? Here, we report that the human-perceived positivity of over 10,000 of
the most frequently used English words exhibits a clear positive bias. More
deeply, we characterize and quantify distributions of word positivity for four
large and distinct corpora, demonstrating that their form is broadly invariant
with respect to frequency of word use.Comment: Manuscript: 9 pages, 3 tables, 5 figures; Supplementary Information:
12 pages, 3 tables, 8 figure
Engineering evaluations and studies. Volume 3: Exhibit C
High rate multiplexes asymmetry and jitter, data-dependent amplitude variations, and transition density are discussed
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