Computational Electromagnetics Applied to Scattering Observed by Polarimetric Weather Radar

The primary topics of this dissertation are issues existing in the current ensemble scattering procedures. These procedures are failing to quantitatively reproduce polarimetric signatures from resolution volumes filled with ensembles of resonant size precipitation, biota, and anthropogenic scatterers. Sources of these failures are traced to the constraints on the topology that is admissible to the different modeling procedures. The dissertation evaluates in a systematic manner the current modeling procedures focusing on limitation sources and their effects on the overall process of polarimetric variable simulation. It re-evaluates limitations of the widely used T-Matrix approach and discusses sources of instability. Based on the identified limitations, a novel computational electromagnetics (CEM) approach to scatterer modeling and polarimetric variable calculation is introduced to mitigate the current limitations. Detailed overview of the process as well as guidance on applying the CEM to the polarimetric variable calculation is presented. This is the first systematic exploration of a specific CEM solver to modeling of polarimetric radar signatures from precipitation and biota. Finally, to demonstrate meteorological application the CEM approach is evaluated by comparison with some polarimetric radar observations of hail. Of main significance is modeling of large and giant hail having surface protuberances, or rough, irregular shape. Additionally, radar observations of biota and radar cross section (RCS) measurements are considered for aeroecology applications. As an example, the precise size and shape model of Brazilian Free-tailed bat (Tadarida brasiliensis) is created and compared to the RCS measurements, as well as to radar observations of bat emergence in Texas plains

Design and Development of Complex Phase Steels with Improved Combination of Strength and Stretch-Flangeability

© 2020 by the authors.This study presents the design and development of a hot-rolled bainitic steel, presenting a good combination of strength and stretch-flangeability, for automotive applications. Ti, Nb, and Mo were added in the steel composition in order to control austenite grain sizes, enhance precipitation hardening, and promote the formation of bainite. This study focuses on the effect of process parameters on final microstructures and mechanical properties. These parameters are the finishing rolling temperature, which conditions the austenite microstructure before its decomposition, and the coiling temperature, which conditions the nature and morphology of the ferritic phases transformed. A preliminary study allowed to determine the austenite grain growth behavior during reheating, the recrystallization kinetics, and the continuous cooling transformation curves of the studied steel. Then, a first set of parameters was tested at a semi-industrial scale, which confirmed that the best elongation properties were obtained for homogeneous bainitic lath/granular microstructures, that can be produced by choosing a coiling temperature of 500 ∘C . When choosing those parameters for the final industrial trial, the microstructure obtained consisted of a homogeneous lath/granular bainite mixture that presented a Ultimate Tensile Strength of 830 MPa and a Hole Expansion Ratio exceeding 70%.The authors gratefully acknowledge the funding received from the European Commission, Research Fund for Coal and Steel, under grant agreement 709803 (NANOFORM).Publisher’s versio

Co(III), Ni(II), and Cu(II) complexes with tetradentate Schiff base ligand: Synthesis, Characterization, Electrochemical Behavior, Binding assessment and In vitro cytotoxicity activity

Two new Schiff base cobalt(III) ([Co(LH)Cl2], 1) and nickel(II) ([Ni(LH)ClO4], 2) complexes with a diimine-dioxime ligand, (4,9-diaza-3,10-diethyl-3,9-dodecadiene-2,11-dione bis oxime (LH2)), were synthesized and characterized. The compounds were obtained in MeOH from corresponding metal salts and LH2 in molar ratio 1:1 and further characterized by mass spectrometry, IR spectroscopy, electrochemistry, and elemental analysis. Previously reported copper(II) analog, ([Cu2(LH)2]·(ClO4)2, 3) was joined to 1 and 2, and the three metal analogs, 1-3, were further investigated in terms of their electrochemical behavior. The binding studies of the complexes with deoxyribonucleic acid (DNA) and human serum albumin (HSA) were carried out using both spectrophotometric and electrochemical methods. All three complexes exhibit binding affinity towards the DNA chain through intercalative interaction. The binding reaction with HSA showed for 1 and 3 complexes decrease in the peak current obtained in the case of complexes before the addition of HSA, while resulted compound obtained from Ni complex – HSA possesses the same electroactivity as starting complex. Furthermore, the cytotoxicity of LH2 as well as its metal complexes, and cisplatin were evaluated on CT-26 mouse colon carcinoma and human LS174T cancer cell lines employing MTT assay. The copper(II) complex exhibited very promising anticancer activity compared with cisplatin

Design and Development of Complex Phase Steels with Improved Combination of Strength and Stretch-Flangeability

International audienceThis study presents the design and development of a hot-rolled bainitic steel, presenting a good combination of strength and stretch-flangeability, for automotive applications. Ti, Nb, and Mo were added in the steel composition in order to control austenite grain sizes, enhance precipitation hardening, and promote the formation of bainite. This study focuses on the effect of process parameters on final microstructures and mechanical properties. These parameters are the finishing rolling temperature, which conditions the austenite microstructure before its decomposition, and the coiling temperature, which conditions the nature and morphology of the ferritic phases transformed. A preliminary study allowed to determine the austenite grain growth behavior during reheating, the recrystallization kinetics, and the continuous cooling transformation curves of the studied steel. Then, a first set of parameters was tested at a semi-industrial scale, which confirmed that the best elongation properties were obtained for homogeneous bainitic lath/granular microstructures, that can be produced by choosing a coiling temperature of 500 ∘ C . When choosing those parameters for the final industrial trial, the microstructure obtained consisted of a homogeneous lath/granular bainite mixture that presented a Ultimate Tensile Strength of 830 MPa and a Hole Expansion Ratio exceeding 70%

Precipitation and grain growth modelling in Ti-Nb microalloyed steels

International audienceMechanical properties of microalloyed steels are enhanced by fine precipitates, that ensure grain growth control during subsequent heat treatment. This study aims at predicting austenite grain growth kinetics coupling a precipitation model and a grain growth model. These models were applied to a titanium and niobium microalloyed steel. The precipitate size distributions were first characterized by TEM and SEM and prior austenite grain boundaries were revealed by thermal etching after various isothermal treatments. From CALPHAD database, a solubility product was determined for (Ti,Nb)C precipitates. A numerical model based on the classical nucleation and growth theories was used to predict the time evolution of (Ti,Nb)C size distributions during various isothermal heat treatments. The precipitation model was validated from TEM/SEM analysis. The resulting precipitate size distributions served as entry parameters to a simple grain growth model based on Zener pinning. The pinning pressure was calculated using the whole size distribution. The resulting austenite grain growth kinetics were in good agreement with the experimental data obtained for all investigated heat treatments

Precipitation and grain growth modelling in Ti-Nb microalloyed steels

International audienceMechanical properties of microalloyed steels are enhanced by fine precipitates, that ensure grain growth control during subsequent heat treatment. This study aims at predicting austenite grain growth kinetics coupling a precipitation model and a grain growth model. These models were applied to a titanium and niobium microalloyed steel. The precipitate size distributions were first characterized by TEM and SEM and prior austenite grain boundaries were revealed by thermal etching after various isothermal treatments. From CALPHAD database, a solubility product was determined for (Ti,Nb)C precipitates. A numerical model based on the classical nucleation and growth theories was used to predict the time evolution of (Ti,Nb)C size distributions during various isothermal heat treatments. The precipitation model was validated from TEM/SEM analysis. The resulting precipitate size distributions served as entry parameters to a simple grain growth model based on Zener pinning. The pinning pressure was calculated using the whole size distribution. The resulting austenite grain growth kinetics were in good agreement with the experimental data obtained for all investigated heat treatments

Towards the Next Generation Operational Meteorological Radar

AbstractThis article summarizes research and risk reduction that will inform acquisition decisions regarding NOAA’s future national operational weather radar network. A key alternative being evaluated is polarimetric phased-array radar (PAR). Research indicates PAR can plausibly achieve fast, adaptive volumetric scanning, with associated benefits for severe-weather warning performance. We assess these benefits using storm observations and analyses, observing system simulation experiments, and real radar-data assimilation studies. Changes in the number and/or locations of radars in the future network could improve coverage at low altitude. Analysis of benefits that might be so realized indicates the possibility for additional improvement in severe-weather and flash-flood warning performance, with associated reduction in casualties. Simulations are used to evaluate techniques for rapid volumetric scanning and assess data quality characteristics of PAR. Finally, we describe progress in developing methods to compensate for polarimetric variable estimate biases introduced by electronic beam-steering. A research-to-operations (R2O) strategy for the PAR alternative for the WSR-88D replacement network is presented.National Ocean and Atmospheric Administration (NOAA