508 research outputs found
Properties of HxTaS2
The preparation of Hx TaS2 (0 \u3c x \u3c 0.87) is described. The compounds are only marginally stable at room temperature, slowly evolving H2S and H2 (and possibly Hp in air). Magnetic susceptibility data show that a low temperature transformation in 2H ... TaS2 (at so•K) is suppressed with the addition of hydrogen, and· at the same time the superconducting transition temperature T c rises from 0.8 to ~4.2•K at x = 0.11. Heat capacity measurements near this concentration show the superconductivity to be a bulk effect. Finally, by correlation of this data with susceptibility and T c measurements in other intercalation compounds, we suggest that the rise of T c (at low electron transfer) is due to suppression of the low temperature transformation and not due to an excitonic mechanism of superconductivity
Structural and dynamical surface properties of phosphatidylethanolamine containing membranes
AbstractThe hydration of solid dimyristoylphosphatidylethanolamine (DMPE) produces a negligible shift in the asymmetric stretching frequency of the phosphate groups in contrast to dimyristoylphosphatidylcholine (DMPC). This suggests that the hydration of DMPE is not a consequence of the disruption of the solid lattice of the phosphate groups as occurs in DMPC. The strong lateral interactions between NH3 and PO2− groups present in the solid PEs remain when the lipids are fully hydrated and seem to be a limiting factor for the hydration of the phosphate group hindering the reorientation of the polar heads. The lower mobility is reflected in a higher energy to translocate the phosphoethanolamine (P–N) dipoles in an electrical field. This energy is decreased in the presence of increasing ratios of PCs of saturated chains in phosphoethanolamine monolayer. The association of PC and PE in the membrane affecting the reorientation of the P–N groups is dependent of the chain–chain interaction. The dipole potentials of PCs and PEs mixtures show different behaviors according to the saturation of the acyl chain. This was correlated with the area in monolayers and the hydration of the P–N groups. In spite of the low hydration, DMPE is still able to adsorb fully hydrated proteins, although in a lower rate than DMPC at the same surface pressure. This indicates that PE interfaces posses an excess of surface free energy to drive protein interaction. The relation of this free energy with the low water content is discussed
Transport and Magnetic Properties of FexVse2 (x = 0 - 0.33)
We present our results of the effect of Fe intercalation on the structural,
transport and magnetic properties of 1T-VSe2. Intercalation of iron, suppresses
the 110K charge density wave (CDW) transition of the 1T-VSe2. For the higher
concentration of iron, formation of a new kind of first order transition at
160K takes place, which go on stronger for the 33% Fe intercalation.
Thermopower of the FexVSe2 compounds (x = 0 - 0.33), however do not show any
anomaly around the transition. The intercalation of Fe does not trigger any
magnetism in the weak paramagnetic 1T-VSe2, and Fe is the low spin state of
Fe3+.Comment: 7 pages, 8 figures, 2 table
Ethics of primate use
This article provides an overview of the ethical issues raised by the use of
non-human primates (NHPs) in research involving scientific procedures which
may cause pain, suffering, distress or lasting harm. It is not an exhaustive
review of the literature and views on this subject, and it does not present
any conclusions about the moral acceptability or otherwise of NHP research.
Rather the aim has been to identify the ethical issues involved and to
provide guidance on how these might be addressed, in particular by carefully
examining the scientific rationale for NHP use, implementing fully the 3Rs
principle of Russell and Burch (1959) and applying a robust "harm-benefit
assessment" to research proposals involving NHPs
Giant Thermoelectric Effect from Transmission Supernodes
We predict an enormous order-dependent quantum enhancement of thermoelectric
effects in the vicinity of a higher-order `supernode' in the transmission
spectrum of a nanoscale junction. Single-molecule junctions based on
3,3'-biphenyl and polyphenyl ether (PPE) are investigated in detail. The
nonequilibrium thermodynamic efficiency and power output of a thermoelectric
heat engine based on a 1,3-benzene junction are calculated using many-body
theory, and compared to the predictions of the figure-of-merit ZT.Comment: 5 pages, 6 figure
- …