195 research outputs found
Magnetic ordering of Mn sublattice, dense Kondo lattice behavior of Ce in (RPd3)8Mn (R = La, Ce)
We have synthesized two new interstitial compounds (RPd3)8Mn (R = La and Ce).
The Mn ions present in "dilute" concentration of just 3 molar percent form a
sublattice with an unusually large Mn-Mn near neighbor distance of ~ 85 nm.
While the existence of (RPd3)8M (where M is a p-block element) is already
documented in the literature, the present work reports for the first time the
formation of this phase with M being a 3d element. In (LaPd3)8Mn, the Mn
sub-lattice orders antiferromagnetically as inferred from the peaks in
low-field magnetization at 48 K and 23 K. The latter peak progressively shifts
towards lower temperatures in increasing magnetic field and disappears below
1.8 K in a field of ~ 8 kOe. On the other hand in (CePd3)8Mn the Mn sublattice
undergoes a ferromagnetic transition around 35 K. The Ce ions form a dense
Kondo-lattice and are in a paramagnetic state at least down to 1.5 K. A
strongly correlated electronic ground state arising from Kondo effect is
inferred from the large extrapolated value of C/T = 275 mJ/Ce-mol K^2 at T = 0
K. In contrast, the interstitial alloys RPd3Mnx (x = 0.03 and 0.06), also
synthesized for the first time, have a spin glass ground state due to the
random distribution of the Mn ions over the available "1b" sites in the parent
RPd3 crystal lattice.Comment: 18 figures and 20 pages of text documen
Magnetic behaviour of PrPd2B2C
We have synthesized a new quaternary borocarbide PrPdBC and
measured its magnetization, electrical resistivity and specific heat. The
compound crystallizes in the LuNiBC-type tetragonal structure
(space group {\it I4/mmm}). Above 100 K the magnetic susceptibility follows
Curie-Weiss behavior with effective moment = 3.60 , which
is very close to the value expected for Pr ions. We do not find evidence
for magnetic or superconducting transition down to 0.5 K. Specific heat
exhibits a broad Schottky type anomaly with a peak at 24 K, very likely related
to crystal electric field (CEF) excitation. The magnetic properties suggest the
presence of a singlet CEF ground state leading to a Van-Vleck paramagnetic
ground state.Comment: 2 pages, 2 figure
Magnetic anisotropy, unusual hysteresis and putative "up-up-down" magnetic structure in EuTAl4Si2 (T = Rh and Ir)
International audienceWe present detailed investigations on single crystals of quaternary EuRhAl4Si2 and EuIrAl4Si2. The two compounds order antiferromagnetically at TN1 = 11.7 and 14.7 K, respectively, each undergoing two magnetic transitions. The magnetic properties in the ordered state present a large anisotropy despite Eu2+being an S-state ion for which the single-ion anisotropy is expected to be weak. Two features in the magnetization measured along the c-axis are prominent. At 1.8 K, a ferromagnetic-like jump occurs at very low field to a value one third of the saturation magnetization (1/3 M0) followed by a wide plateau up to 2 T for Rh and 4 T for Ir-compound. At this field value, a sharp hysteretic spin-flop transition occurs to a fully saturated state (M0). Surprisingly, the magnetization does not return to origin when the field is reduced to zero in the return cycle, as expected in an antiferromagnet. Instead, a remnant magnetization 1/3 M0 is observed and the magnetic loop around the origin shows hysteresis. This suggests that the zero field magnetic structure has a ferromagnetic component, and we present a model with up to third neighbor exchange and dipolar interaction which reproduces the magnetization curves and hints to an “up-up-down” magnetic structure in zero field
Study of CeNi4Mn by neutron diffraction
We report neutron diffraction measurements on CeNi4Mn, which has recently
been identified as a soft ferromagnet (Tc ~ 140 K) with a sizeable
spin-transport polarization. Our data show conclusively that the Mn atoms
occupy a unique site (4c) in the unit cell, which has the symmetry of the cubic
MgCu4Sn-type structure. We infer a moment of 4.6 mu_B on Mn at 17 K, which is
oriented ferromagnetically along the {101} plane. The amplitude of the Mn
vibrational motion is found to be larger than that of Ce and Ni atoms at all
temperatures, thereby lending support to theoretical prediction of rattling
phonon modes in this compound.Comment: Accepted for publication in Solid State Commu
Correlations and scaling in one-dimensional heat conduction
We examine numerically the full spatio-temporal correlation functions for all
hydrodynamic quantities for the random collision model introduced recently. The
autocorrelation function of the heat current, through the Kubo formula, gives a
thermal conductivity exponent of 1/3 in agreement with the analytical
prediction and previous numerical work. Remarkably, this result depends
crucially on the choice of boundary conditions: for periodic boundary
conditions (as opposed to open boundary conditions with heat baths) the
exponent is approximately 1/2. This is expected to be a generic feature of
systems with singular transport coefficients. All primitive hydrodynamic
quantities scale with the dynamic critical exponent predicted analytically.Comment: 7 pages, 11 figure
- …