113 research outputs found
Photoelectrochemical Characterization and Durability Analysis of GaInPN Epilayers
Epilayer samples of GaInPN with a stoichiometry of Ga.962In.038P.976N.024 and Ga.95In.05P.975N.025 were grown by metallorganic chemical vapor deposition and were photoelectrochemically characterized to determine their potential to photoelectrolyze water.
The materials had direct transition bandgap energies of _2.0 eV, as determined by photocurrent spectroscopy; however, the measured flatband potentials were several hundred millivolts too negative for unbiased water splitting. Stability was assessed by operating the electrodes as photocathodes for 24 h and qualitatively evaluated by probing the amount of surface etching with a stylus profilometer. Quantitative evaluation was done by measuring the concentration of gallium in the corrosion test electrolyte using inductively coupled plasma mass spectrometry. Results were compared to similarly treated GaP and GaInP2 samples for context
Perfect state distinguishability and computational speedups with postselected closed timelike curves
Bennett and Schumacher's postselected quantum teleportation is a model of
closed timelike curves (CTCs) that leads to results physically different from
Deutsch's model. We show that even a single qubit passing through a
postselected CTC (P-CTC) is sufficient to do any postselected quantum
measurement, and we discuss an important difference between "Deutschian" CTCs
(D-CTCs) and P-CTCs in which the future existence of a P-CTC might affect the
present outcome of an experiment. Then, based on a suggestion of Bennett and
Smith, we explicitly show how a party assisted by P-CTCs can distinguish a set
of linearly independent quantum states, and we prove that it is not possible
for such a party to distinguish a set of linearly dependent states. The power
of P-CTCs is thus weaker than that of D-CTCs because the Holevo bound still
applies to circuits using them regardless of their ability to conspire in
violating the uncertainty principle. We then discuss how different notions of a
quantum mixture that are indistinguishable in linear quantum mechanics lead to
dramatically differing conclusions in a nonlinear quantum mechanics involving
P-CTCs. Finally, we give explicit circuit constructions that can efficiently
factor integers, efficiently solve any decision problem in the intersection of
NP and coNP, and probabilistically solve any decision problem in NP. These
circuits accomplish these tasks with just one qubit traveling back in time, and
they exploit the ability of postselected closed timelike curves to create
grandfather paradoxes for invalid answers.Comment: 15 pages, 4 figures; Foundations of Physics (2011
HIV/AIDS, declining family resources and the community safety net
Families play central roles in the HIV/AIDS pandemic, caring for both orphaned children and the ill. This extra caregiving depletes two family resources essential for supporting children: time and money. We use recent data from published studies in sub-Saharan Africa to illustrate deficits and document community responses. In Botswana, parents caring for the chronically ill had less time for their preschool children (74 versus 96 hours per month) and were almost twice as likely to leave children home alone (53% versus 27%); these children experienced greater health and academic problems. Caregiving often prevented adults from working full time or earning their previous level of income; 47% of orphan caregivers and 64% of HIV/AIDS caregivers reported financial difficulties due to caregiving. Communities can play an important role in helping families provide adequate childcare and financial support. Unfortunately, while communities commonly offer informal assistance, the value of such support is not adequate to match the magnitude of need: 75% of children's families in Malawi received assistance from their social network, but averaging only US$81 annually. We suggest communities can strengthen the capacity of families by implementing affordable quality childcare for 0â6 year olds, after-school programming for older children and youth, supportive care for ill children and parents, microlending to enhance earnings, training to increase access to quality jobs, decent working conditions, social insurance for the informal sector, and income and food transfers when families are unable to make ends meet
Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry
Photoelectrochemical water splitting is a promising route for the renewable production of hydrogen fuel. This work presents the results of a technical and economic feasibility analysis conducted for four hypothetical, centralized, large-scale hydrogen production plants based on this technology. The four reactor types considered were a single bed particle suspension system, a dual bed particle suspension system, a fixed panel array, and a tracking concentrator array. The current performance of semiconductor absorbers and electrocatalysts were considered to compute reasonable solar-to-hydrogen conversion efficiencies for each of the four systems. The U.S. Department of Energy H2A model was employed to calculate the levelized cost of hydrogen output at the plant gate at 300 psi for a 10 tonne per day production scale. All capital expenditures and operating costs for the reactors and auxiliaries (compressors, control systems, etc.) were considered. The final cost varied from 10.40 per kg H2 with the particle bed systems having lower costs than the panel-based systems. However, safety concerns due to the cogeneration of O_2 and H_2 in a single bed system and long molecular transport lengths in the dual bed system lead to greater uncertainty in their operation. A sensitivity analysis revealed that improvement in the solar-to-hydrogen efficiency of the panel-based systems could substantially drive down their costs. A key finding is that the production costs are consistent with the Department of Energy's targeted threshold cost of 4.00 per kg H_2 for dispensed hydrogen, demonstrating that photoelectrochemical water splitting could be a viable route for hydrogen production in the future if material performance targets can be met
Entanglement purification of unknown quantum states
A concern has been expressed that ``the Jaynes principle can produce fake
entanglement'' [R. Horodecki et al., Phys. Rev. A {\bf 59}, 1799 (1999)]. In
this paper we discuss the general problem of distilling maximally entangled
states from copies of a bipartite quantum system about which only partial
information is known, for instance in the form of a given expectation value. We
point out that there is indeed a problem with applying the Jaynes principle of
maximum entropy to more than one copy of a system, but the nature of this
problem is classical and was discussed extensively by Jaynes. Under the
additional assumption that the state of the copies of the
quantum system is exchangeable, one can write down a simple general expression
for . We show how to modify two standard entanglement purification
protocols, one-way hashing and recurrence, so that they can be applied to
exchangeable states. We thus give an explicit algorithm for distilling
entanglement from an unknown or partially known quantum state.Comment: 20 pages RevTeX 3.0 + 1 figure (encapsulated Postscript) Submitted to
Physical Review
Additive and interaction effects at three amino acid positions in HLA-DQ and HLA-DR molecules drive type 1 diabetes risk.
Variation in the human leukocyte antigen (HLA) genes accounts for one-half of the genetic risk in type 1 diabetes (T1D). Amino acid changes in the HLA-DR and HLA-DQ molecules mediate most of the risk, but extensive linkage disequilibrium complicates the localization of independent effects. Using 18,832 case-control samples, we localized the signal to 3 amino acid positions in HLA-DQ and HLA-DR. HLA-DQÎČ1 position 57 (previously known; P = 1 Ă 10(-1,355)) by itself explained 15.2% of the total phenotypic variance. Independent effects at HLA-DRÎČ1 positions 13 (P = 1 Ă 10(-721)) and 71 (P = 1 Ă 10(-95)) increased the proportion of variance explained to 26.9%. The three positions together explained 90% of the phenotypic variance in the HLA-DRB1-HLA-DQA1-HLA-DQB1 locus. Additionally, we observed significant interactions for 11 of 21 pairs of common HLA-DRB1-HLA-DQA1-HLA-DQB1 haplotypes (P = 1.6 Ă 10(-64)). HLA-DRÎČ1 positions 13 and 71 implicate the P4 pocket in the antigen-binding groove, thus pointing to another critical protein structure for T1D risk, in addition to the HLA-DQ P9 pocket.This research utilizes resources provided by the Type 1 Diabetes Genetics Consortium, a collaborative clinical study sponsored by the National Institute of Diabetes and Digestive and Kidney Diseases (NIDDK), National Institute of Allergy and Infectious Diseases (NIAID), National Human Genome Research Institute (NHGRI), National Institute of Child Health and Human Development (NICHD), and Juvenile Diabetes Research Foundation International (JDRF) and supported by U01 DK062418. This work is supported in part by funding from the National Institutes of Health (5R01AR062886-02 (PIdB), 1R01AR063759 (SR), 5U01GM092691-05 (SR), 1UH2AR067677-01 (SR),
R01AR065183 (PIWdB)), a Doris Duke Clinical Scientist Development Award (SR), the Wellcome Trust (JAT) and the National Institute for Health Research (JAT and JMMH), and a Vernieuwingsimpuls VIDI Award (016.126.354) from the Netherlands Organization for Scientific Research (PIWdB). TLL was supported by the German Research Foundation (LE 2593/1-1 and LE 2593/2-1).This is the accepted manuscript. The final version is available at http://www.nature.com/ng/journal/v47/n8/full/ng.3353.html
Adaptation of mammalian host-pathogen interactions in a changing arctic environment
Many arctic mammals are adapted to live year-round in extreme environments with low winter temperatures and great seasonal variations in key variables (e.g. sunlight, food, temperature, moisture). The interaction between hosts and pathogens in high northern latitudes is not very well understood with respect to intra-annual cycles (seasons). The annual cycles of interacting pathogen and host biology is regulated in part by highly synchronized temperature and photoperiod changes during seasonal transitions (e.g., freezeup and breakup). With a warming climate, only one of these key biological cues will undergo drastic changes, while the other will remain fixed. This uncoupling can theoretically have drastic consequences on host-pathogen interactions. These poorly understood cues together with a changing climate by itself will challenge host populations that are adapted to pathogens under the historic and current climate regime. We will review adaptations of both host and pathogens to the extreme conditions at high latitudes and explore some potential consequences of rapid changes in the Arctic
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