11 research outputs found

    Experimental investigation of the U-Zr-Al ternary phase diagram: Isothermal sections at 673 K and 1073 K.

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    International audienceIsothermal sections at 673 K and 1073 K of the ternary U-Zr-Al system were established in the whole concn. range, by means of powder X-ray diffraction, SEM-energy dispersive X-ray spectroscopy and DTA. All measured compns. and unit-cell refinements were performed at room temp. from quenched samples annealed at 1073 K and 673 K for four and eight weeks resp. For both temps., the Al-rich corner of the phase diagram is characterized by extended homogeneity ranges due to mutual exchange between U and Zr in UAl3 (cubic, AuCu3-type) and in the Laves phase UAl2 (cubic, MgCu2-type). Minute U soly. in ZrAl2 (hexagonal, MgZn2-type) and in Zr2Al (hexagonal, Ni2In-type) was evaluated to be of the order of 1 at.% U. For the other binary compds., the soly. of the third component was found negligible. At 1073 K, the solid soln. based on γU (cubic, W-type) which covers the U-Zr binary axis up to 95.5 at.% Zr, allows also some limited soly. of Al [max. of 5 at.%]. For Al-content below 66 at.%, most of the phase relations comprise equil. between the Zr-Al binaries and the γ(U,Zr,Al) solid soln. At 673 K, the U-Zr axis is found in agreement with the literature data and no Al soly. could be detected in αU, αZr and UZr2 (δ phase). The phase relations are mainly established between Zr-Al binaries and αU. For monolithic UMo fuel with a Zr diffusion barrier foil cladded with Al, the main interaction product is expected to involve the U-based alloy with the Zr-Al binary compds. and the pseudo-binary U1-xZrxAl2 and U1-xZrxAl3 phases

    Fabrication et usinage des guides en verre de tellurite pour l'optique non-linéaire intégrée

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    Fabrication et usinage des guides en verre de tellurite pour l'optique non-linéaire intégrée

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    Microstructured chalcogenide optical fibers from As2S3 glass: towards new IR broadband sources

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    International audienceThe aim of this paper is to present an overview of the recent achievements of our group in the fabrication and optical characterizations of As2S3 microstructured optical fibers (MOFs). Firstly, we study the synthesis of high purity arsenic sulfide glasses. Then we describe the use of a versatile process using mechanical drilling for the preparation of preforms and then the drawing of MOFs including suspended core fibers. Low losses MOFs are obtained by this way, with background level of losses reaching less than 0.5 dB/m. Optical characterizations of these fibers are then reported, especially dispersion measurements. The feasibility of all-optical regeneration based on a Mamyshev regenerator is investigated, and the generation of a broadband spectrum between 1 µm and 2.6 µm by femto second pumping around 1.5 µm is presented

    Recent developments in chalcogenide photonic crystal fibres

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    Elaboration of low-losses highly non linear chalcogenide optical fibers for the generation of efficient non linear effects in the infrared remains a challenge. In recent years, much work has been devoted to the study of microstructured optical fibers (MOFs) with different designs and various elaboration processes. Their background losses were typically of several dB/m. © 2011 IEEE
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