Landbrugets Redskaber og Maskiner. 1894.

Landbrugets Redskaber og Maskiner. 1894

Den økonomiske Grænse for de forskjellige Bevægkræfters Anvendelse i Landbrugets Tjeneste.

Den økonomiske Grænse for de forskjellige Bevægkræfters Anvendelse i Landbrugets Tjeneste

Beretning om Arbejdsprøve med Kværne, Knusemaskiner og Oliekagebrydere i Randers, samt en Efterprøve med Kværne og Knusemaskiner i Nakskov.

Beretning om Arbejdsprøve med Kværne, Knusemaskiner og Oliekagebrydere i Randers, samt en Efterprøve med Kværne og Knusemaskiner i Nakskov

Arbejdsprøve med Radsaamaskiner, Geduingsspredemaskiner og Godningsmoller.

Arbejdsprøve med Radsaamaskiner, Geduingsspredemaskiner og Godningsmoller

Landbrugets Redskaber og Maskiner 1892.

Landbrugets Redskaber og Maskiner 1892

Landbrugets Bedskaber og Maskiner 1895.

Landbrugets Bedskaber og Maskiner 1895

Beretning om den paa Borreby i Marts 1893 afholdte Prøve med Petroleums lokomobiler til Tærskning

Beretning om den paa Borreby i Marts 1893 afholdte Prøve med Petroleums lokomobiler til Tærsknin

Landbrugets Eedstaber og Maskiner 1896.Af Statskonsulent.

Landbrugets Eedstaber og Maskiner 1896.Af Statskonsulent

A new electrochemical method for the determination of chondroitin sulfate based on its supramolecular interaction with cupferron-lead(II) complex

In this paper, the interaction of cupferron (Cup) and lead (II) complex [Cup-Pb (II)] with chondroitin sulfate (CS) was investigated by linear sweep voltammetric method. In the selected medium of pH 5.5 (acetic acid-hexamine buffer solution), Cup can interact with Pb (II) to form a stable complex of [Cup-Pb(II)], which has a sensitive second order derivative polarographic reductive peak at -0.64V (vs.SCE). After the addition of CS into Cup-Pb (II) complex solution, the reductive peak current decreased without any shift of the peak potential and no new peak appeared, which indicated that an unelectroactive supramolecular complex of CS with [Cup-Pb(II)] was formed. The binding reaction conditions were carefully investigated. Under the optimal conditions, the interaction mechanism was discussed. The decrease of reductive peak current was directly proportional to the CS concentration, thus a new quantitative determination method for CS was established with the linear regression equation as ΔIp″(nA)=36.97 C/mg L-1+12.45 (n=10, γ=0.995). The effects of other substances on the determination were carefully investigated and three synthetic samples were determined with satisfactory results. The binding constant (βs) and the binding number (m) of CS with [Cup-Pb(II)] complex were calculated from the voltammetric data with the results as βs=1.89×1010 and m≈2.5

Bone mineral accrual and gain in skeletal width in pre-pubertal school children is independent of the mode of school transportation – one-year data from the prospective observational pediatric osteoporosis prevention (POP) study

Background: Walking and cycling to school could be an important regular source of physical activity in growing children. The aim of this 12 months prospective observational study was thus to evaluate the effect of self-transportation to school on bone mineral accrual and gain in bone width in pre-pubertal children, both traits independently contributing to bone strength. Methods: Ninety-seven girls and 133 boys aged 7-9 years were recruited as a part of the Malmo Pediatric Osteoporosis Prevention (POP) Study in order to evaluate the influence of self-selected school transportation for the accrual of bone mineral and bone width. Children who walked or cycled to school were compared with children who went by bus or car. Bone mineral content (BMC) was measured by dual energy X-ray absorptiometry (DXA) in the lumbar spine (L2-L4), third lumbar vertebra (L3) and hip, and bone width was calculated at L3 and femoral neck (FN). Changes during the first 12 months were compared between the groups. Subjective duration of physical activity was estimated by a questionnaire and objective level of everyday physical activity at follow-up by accelerometers worn for four consecutive days. All children remained in Tanner stage 1 throughout the study. Comparisons were made by independent student's t-tests between means, ANCOVA and Fisher's exact tests. Results: There were no differences in baseline or annual changes in BMC or bone width when the transportation groups were compared. No differences were detected in objectively measured daily level of physical activity by accelerometer. All children reached above 60 minutes of moderate to intense daily physical activity per day, the international recommended level of daily physical activity according to the United Kingdom Expert Consensus Group. Conclusion: The everyday physical activity in these pre-pubertal children seems to be so high that the school transportation contributes little to their total level of physical activity. As a result, the choice of school transportation seems not to influence the accrual of bone mineral or gain in bone size during a I2-month follow-up period