Quantifying the origin of metallic glass formation

The waiting time to form a crystal in a unit volume of homogeneous undercooled liquid exhibits a pronounced minimum τ_X* at a ‘nose temperature’ T* located between the glass transition temperature T_g, and the crystal melting temperature, T_L. Turnbull argued that τ_X* should increase rapidly with the dimensionless ratio t_(rg)=T_g/T_L. Angell introduced a dimensionless ‘fragility parameter’, m, to characterize the fall of atomic mobility with temperature above T_g. Both t_(rg) and m are widely thought to play a significant role in determining τ_X*. Here we survey and assess reported data for T_L, T_g, t_(rg), m and τ_X* for a broad range of metallic glasses with widely varying τ_X*. By analysing this database, we derive a simple empirical expression for τ_X*(t_(rg), m) that depends exponentially on t_(rg) and m, and two fitting parameters. A statistical analysis shows that knowledge of t_(rg) and m alone is therefore sufficient to predict τ_X* within estimated experimental errors. Surprisingly, the liquid/crystal interfacial free energy does not appear in this expression for τ_X*

Cross-lingual document retrieval categorisation and navigation based on distributed services

The widespread use of the Internet across countries has increased the need for access to document collections that are often written in languages different from a user’s native language. In this paper we describe Clarity, a Cross Language Information Retrieval (CLIR) system for English, Finnish, Swedish, Latvian and Lithuanian. Clarity is a fully-fledged retrieval system that supports the user during the whole process of query formulation, text retrieval and document browsing. We address four of the major aspects of Clarity: (i) the user-driven methodology that formed the basis for the iterative design cycle and framework in the project, (ii) the system architecture that was developed to support the interaction and coordination of Clarity’s distributed services, (iii) the data resources and methods for query translation, and (iv) the support for Baltic languages. Clarity is an example of a distributed CLIR system built with minimal translation resources and, to our knowledge, the only such system that currently supports Baltic languages

The r-process nucleosynthesis: a continued challenge for nuclear physics and astrophysics

The identification of the astrophysical site and the specific conditions in which r-process nucleosynthesis takes place remain unsolved mysteries of astrophysics. The present paper emphasizes some important future challenges faced by nuclear physics in this problem, particularly in the determination of the radiative neutron capture rates by exotic nuclei close to the neutron drip line and the fission probabilities of heavy neutron-rich nuclei. These quantities are particularly relevant to determine the composition of the matter resulting from the decompression of initially cold neutron star matter. New detailed r-process calculations are performed and the final composition of ejected inner and outer neutron star crust material is estimated. We discuss the impact of the many uncertainties in the astrophysics and nuclear physics on the final composition of the ejected matter. The similarity between the predicted and the solar abundance pattern for A > 140 nuclei as well as the robustness of the prediction with varied input parameters makes this scenario one of the most promising that deserves further exploration.Comment: 8 pages, contribution to the Nuclei in the Cosmos Conference, to appear in Nucl. Phys.

Proton capture cross section of Sr isotopes and their importance for nucleosynthesis of proton-rich nuclides

The (p,$\gamma$) cross sections of three stable Sr isotopes have been measured in the astrophysically relevant energy range. These reactions are important for the $p$-process in stellar nucleosynthesis and, in addition, the reaction cross sections in the mass region up to 100 are also of importance concerning the $rp$-process associated with explosive hydrogen and helium burning. It is speculated that this $rp$-process could be responsible for a certain amount of $p$-nuclei in this mass region. The (p,$\gamma$) cross sections of $^{84,86,87}$Sr isotopes were determined using an activation technique. The measurements were carried out at the 5 MV Van de Graaff accelerator of the ATOMKI, Debrecen. The resulting cross sections are compared with the predictions of statistical model calculations. The predictions are in good agreement with the experimental results for $^{84}$Sr(p,$\gamma$)$^{85}$Y whereas the other two reactions exhibit differences that increase with mass number. The corresponding astrophysical reaction rates have also been computed.Comment: Phys. Rev. C in pres

Melanin Pigmentation and Inflammation in Human Gingiva

Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/141745/1/jper0701.pd

Control of individual electron-spin pairs in an electron-spin bath

The decoherence of a central electron spin due to the dynamics of a coupled electron-spin bath is a core problem in solid-state spin physics. Ensemble experiments have studied the central spin coherence in detail, but such experiments average out the underlying quantum dynamics of the bath. Here, we show the coherent back-action of an individual NV center on an electron-spin bath and use it to detect, prepare and control the dynamics of a pair of bath spins. We image the NV-pair system with sub-nanometer resolution and reveal a long dephasing time ($T_2^* = 44(9)$ ms) for a qubit encoded in the electron-spin pair. Our experiment reveals the microscopic quantum dynamics that underlie the central spin decoherence and provides new opportunities for controlling and sensing interacting spin systems

Charge transfer complex formation between organic interlayers drives light-soaking in large area perovskite solar cells

Light soaking (LS) is a well-known but poorly understood phenomenon in perovskite solar cells (PSCs) which significantly affects device efficiency and stability. LS is greatly reduced in large-area inverted PSCs when a PC61BM electron transport layer (ETL) is replaced with C60, where the ETL is commonly in contact with a thin bathocuproine (BCP) interlayer. Herein, we identify the key molecular origins of this LS effect using a combination of surface photovoltage, ambient photoemission spectroscopy, Raman spectroscopy, integrated with density functional theory simulations. We find that BCP forms a photoinduced charge-transfer (CT) complex with both C60 and PC61BM. The C60/BCP complex accelerates C60 dimer formation, leading to a favourable cascading energetic landscape for electron extraction and reduced recombination loss. In contrast, the PC61BM/BCP complex suppresses PC61BM dimer formation, meaning that PC61BM dimerisation is not the cause of LS. Instead, it is the slow light-induced formation of the PC61BM/BCP CT complex itself, and the new energetic transport levels associated with it, which cause the much slower and stronger LS effect of PC61BM based PSCs. These findings provide key understanding of photoinduced ETL/BCP interactions and their impact on the LS effect in PSCs

Proceedings of the Salford Postgraduate Annual Research Conference (SPARC) 2011

These proceedings bring together a selection of papers from the 2011 Salford Postgraduate Annual Research Conference(SPARC). It includes papers from PhD students in the arts and social sciences, business, computing, science and engineering, education, environment, built environment and health sciences. Contributions from Salford researchers are published here alongside papers from students at the Universities of Anglia Ruskin, Birmingham City, Chester,De Montfort, Exeter, Leeds, Liverpool, Liverpool John Moores and Manchester