Novel nitrogen-based organosulfur electrodes for advanced intermediate temperature batteries

Advanced secondary batteries operating at intermediate temperatures (100 to 200 C) have attracted considerable interest due to their inherent advantages (reduced corrosion and safety risks) over higher temperature systems. Current work in this laboratory has involved research on a class of intermediate temperature Na/beta double prime- alumina/RSSR batteries conceptually similar to Na/S cells, but operating within a temperature range of 100 to 150 C, and having an organosulfur rather than inorganic sulfur positive electrode. The organosulfur electrodes are based on the reversible, two electron eduction of organodisulfides to the corresponding thiolate anions, RSSR + 2 electrons yield 2RS(-), where R is an organic moiety. Among the advantages of such a generic redox couple for battery research is the ability to tailor the physical, chemical, and electrochemical properties of the RSSR molecule through choice of the organic moiety. The viscosity, liquidus range, dielectric constant, equivalent weight, and redox potential can in fact be verified in a largely predictable manner. The current work concerns the use of multiple nitrogen organosulfur molecules, chosen for application in Na/RSSR cells for their expected oxidizing character. In fact, a Na/RSSR cell containing one of these materials, the sodium salt of 5-mercapto 1-methyltetrazole, yielded the highest open circuit voltage obtained yet in the laboratory; 3.0 volts in the charged state and 2.6 volts at 100 percent discharge. Accordingly, the cycling behavior of a series of multiple nitrogen organodisulfides as well as polymeric organodisulfides are presented in this manuscript

La Formation de Jupille, nouvelle formation dans le Dévonien inférieur de la Haute-Ardenne (Belgique)

The Jupille Formation, new formation in the lower Devonian of the High-Ardenne (Belgium). A new formation named Jupille is proposed to better characterize in the High-Ardenne area the rocks interbedded between the La Roche (or Villé if La Roche is missing) and Pèrnelle Formations, at the transition between the Pragian/Emsian stages (Lower Devonian). This formation is made up of series of grey, blue grey or greenish grey sandstone layers interbedded in blue grey siltstones and slates similar to those of the La Roche Formation. Locally, the sandstones grades to quartzites. Tool marks, current ripples, lenticular and oblique or hummocky cross-stratifications and load casts (pseudonodules) are present in the sandstone layers

Lipase-catalyzed Solvent-free Synthesis of Polyglycerol 10 (PG-10) Esters

Polyglycerol fatty acid esters, which have been widely used as emulsifiers in food, medicine and cosmetics industries, were the subject of solvent-free enzymatic synthesis in this study. There have been previous reports on enzymatic synthesis of various polyglycerol esters; however, this investigation extends the synthesis to PG-10 esters. The effects of substrate molar ratio, addition of emulsifiers to enhance mixing, and addition of molecular sieves or N2 flushing for water removal, was investigated. The solvent-free synthesis using N2 flushing leads to complete conversion of fatty acid, yielding a completely acid free product. The synthesis is validated for polyglycerol laurate and polyglycerol caprylate, both useful products in the cosmetic industry. This work is licensed under a Creative Commons Attribution 4.0 International License

Keplerian discs around post-AGB stars: a common phenomenon?

Aims: We aim at showing that the broad-band SED characteristics of our sample of post-AGB stars are best interpreted, assuming the circumstellar dust is stored in Keplerian rotating passive discs. Methods: We present a homogeneous and systematic study of the Spectral Energy Distributions (SEDs) of a sample of 51 post-AGB objects. The selection criteria to define the whole sample were tuned to cover the broad-band characteristics of known binary post-AGB stars. The whole sample includes 20 dusty RV Tauri stars from the General Catalogue of Variable Stars (GCVS). We supplemented our own Geneva optical photometry with literature data to cover a broad range of fluxes from the UV to the far-IR. Results: All the SEDs display very similar characteristics: a large IR excess with a dust excess starting near the sublimation temperature, irrespective of the effective temperature of the central star. Moreover, when available, the long wavelength fluxes show a black-body slope indicative of the presence of a component of large mm sized grains. Conclusions: We argue that in all systems, gravitationally bound dusty discs are present. The discs must be puffed-up to cover a large opening angle for the central star and we argue that the discs have some similarity with the passive discs detected around young stellar objects. We interpret the presence of a disc to be a signature for binarity of the central object, but this will need confirmation by long-term monitoring of the radial velocities. We argue that dusty RV Tauri stars are those binaries which happen to be in the Population II instability strip.Comment: 29 pages, 5 figures, accepted for publication in A&

Anisotropic distribution functions for spherical galaxies

A method is presented for finding anisotropic distribution functions for stellar systems with known, spherically symmetric, densities, which depends only on the two classical integrals of the energy and the magnitude of the angular momentum. It requires the density to be expressed as a sum of products of functions of the potential and of the radial coordinate. The solution corresponding to this type of density is in turn a sum of products of functions of the energy and of the magnitude of the angular momentum. The products of the density and its radial and transverse velocity dispersions can be also expressed as a sum of products of functions of the potential and of the radial coordinate. Several examples are given, including some of new anisotropic distribution functions. This device can be extended further to the related problem of finding two-integral distribution functions for axisymmetric galaxies.Comment: 5 figure

Triaxial orbit based galaxy models with an application to the (apparent) decoupled core galaxy NGC 4365

We present a flexible and efficient method to construct triaxial dynamical models of galaxies with a central black hole, using Schwarzschild's orbital superposition approach. Our method is general and can deal with realistic luminosity distributions, which project to surface brightness distributions that may show position angle twists and ellipticity variations. The models are fit to measurements of the full line-of-sight velocity distribution (wherever available). We verify that our method is able to reproduce theoretical predictions of a three-integral triaxial Abel model. In a companion paper (van de Ven, de Zeeuw & van den Bosch), we demonstrate that the method recovers the phase-space distribution function. We apply our method to two-dimensional observations of the E3 galaxy NGC 4365, obtained with the integral-field spectrograph SAURON, and study its internal structure, showing that the observed kinematically decoupled core is not physically distinct from the main body and the inner region is close to oblate axisymmetric.Comment: 21 Pages, 14 (Colour) Figures, Companion paper is arXiv:0712.0309 Accepted to MNRAS. Full resolution version at http://www.strw.leidenuniv.nl/~bosch/papers/RvdBosch_triaxmethod.pd

Testing Newtonian Gravity with AAOmega: Mass-to-Light Profiles of Four Globular Clusters

Testing Newtonian gravity in the weak-acceleration regime is vital to our understanding of the nature of the gravitational interaction. It has recently been claimed that the velocity dispersion profiles of several globular clusters flatten out at large radii, reminiscent of galaxy rotation curves, even though globular clusters are thought to contain little or no dark matter. We investigate this claim, using AAOmega observations of four globular clusters, namely M22, M30, M53 and M68. M30, one such cluster that has had this claim made for its velocity dispersion, was included for comparison with previous studies. We find no statistically significant flattening of the velocity dispersion at large radii for any of our target clusters and therefore we infer the observed dynamics do not require that globular clusters are dark matter dominated, or a modification of gravity. Furthermore, by applying a simple dynamical model we determine the radial mass-to-light profiles for each cluster. The isothermal rotations of each cluster are also measured, with M22 exhibiting clear rotation, M68 possible rotation and M30 and M53 lacking any rotation, within the uncertainties.Comment: 7 pages, 4 figures and two tables. Accepted by MNRA

Strong dust processing in circumstellar discs around 6 RV Tauri stars. Are dusty RV Tauri stars all binaries?

We present extended Spectral Energy Distributions (SEDs) of seven classical RV Tauri stars, using newly obtained submillimetre continuum measurements and Geneva optical photometry supplemented with literature data. The broad-band SEDs show a large IR excess with a black-body slope at long wavelengths in six of the seven stars, R Sct being the noticeable exception. This long wavelength slope is best explained assuming the presence of a dust component of large grains in the circumstellar material. We show that the most likely distribution of the circumstellar dust around the six systems is that the dust resides in a disc. Moreover, very small outflow velocities are needed to explain the presence of dust near the sublimation temperature and we speculate that the discs are Keplerian. The structure and evolution of these compact discs are as yet not understood but a likely prerequisite for their formation is that the dusty RV Tauri stars are binaries.Comment: 10 pages, will be published in A&

The mass and anisotropy profiles of galaxy clusters from the projected phase space density: testing the method on simulated data

We present a new method of constraining the mass and velocity anisotropy profiles of galaxy clusters from kinematic data. The method is based on a model of the phase space density which allows the anisotropy to vary with radius between two asymptotic values. The characteristic scale of transition between these asymptotes is fixed and tuned to a typical anisotropy profile resulting from cosmological simulations. The model is parametrized by two values of anisotropy, at the centre of the cluster and at infinity, and two parameters of the NFW density profile, the scale radius and the scale mass. In order to test the performance of the method in reconstructing the true cluster parameters we analyze mock kinematic data for 20 relaxed galaxy clusters generated from a cosmological simulation of the standard LCDM model. We use Bayesian methods of inference and the analysis is carried out following the Markov Chain Monte Carlo approach. The parameters of the mass profile are reproduced quite well, but we note that the mass is typically underestimated by 15 percent, probably due to the presence of small velocity substructures. The constraints on the anisotropy profile for a single cluster are in general barely conclusive. Although the central asymptotic value is determined accurately, the outer one is subject to significant systematic errors caused by substructures at large clustercentric distance. The anisotropy profile is much better constrained if one performs joint analysis of at least a few clusters. In this case it is possible to reproduce the radial variation of the anisotropy over two decades in radius inside the virial sphere.Comment: 11 pages, 10 figures, accepted for publication in MNRA