587 research outputs found

    Anodic Oxidations of Medium Ring Cycloalkanecarboxylic Acids.

    Get PDF

    A qualitatively model to describe the influence of boundaries on the energy density by considering the energy leakage, and its extension on the system ventilation and fire fighting systems

    Get PDF
    Abstract In this paper constitutive models based on physical laws are derived that allow the energy flows and the release of energy to be described and predicted for fires in enclosed spaces and tunnels in particular. The models are generally formulated but are also specifically formulated for practical applications, e.g. for considering the effect of limited burning due to insufficient oxygen supply or the effect of fire fighting systems. The solutions agree with the experimentally obtained results in (Carvel et al, 2001 and Carvel et al, 2005). Accordingly, the methods and solutions derived here can be considered adequately validated

    Sensible heat loss from Muskoxen (Ovibos moschatus) feeding in winter: small calves are not at a thermal disadvantage compared with adult cows

    Get PDF
    Muskoxen (Ovibos moschatus) are large (\u3e200 kg adult body mass) mammalian herbivores that overwinter in the polar regions. Calves are around one-third the body mass of mature females and may be expected to suffer greater thermal stresses in winter compared with adults because the ratio of surface area to volume (SA : vol) is much greater for calves than for adults. We found that during feeding bouts, when animals are fully exposed to environmental conditions, calves did lose sensible (dry) heat more readily than adults (W m(-2)) in still air conditions. However, calves and cows lost less than 2%-6% of their estimated daily digestible energy intake as conductive, convective, and radiant heat losses accumulated during feeding bouts. More important, calves did not lose relatively more heat than larger adults in terms of sensible losses as part of their daily energy intake. Coat surface temperatures were only 2 degrees-5 degrees C above ambient even when air temperature fell to -40 degrees C. Body temperatures recorded deep within the ear canal near the tympanum fluctuated in both cows and calves. Muskoxen combine peripheral heterothermy and an exceptional winter coat to minimize sensible heat loss in winter. These mechanisms appear to have circumvented some of the thermal problems normally associated with a high SA : vol ratio in calves, which reflects the strong selection to conserve energy in winter

    Gamification techniques for raising cyber security awareness

    Get PDF
    Due to the prevalence of online services in modern society, such as internet banking and social media, it is important for users to have an understanding of basic security measures in order to keep themselves safe online. However, users often do not know how to make their online interactions secure, which demonstrates an educational need in this area. Gamification has grown in popularity in recent years and has been used to teach people about a range of subjects. This paper presents an exploratory study investigating the use of gamification techniques to educate average users about password security, with the aim of raising overall security awareness. To explore the impact of such techniques, a role-playing quiz application (RPG) was developed for the Android platform to educate users about password security. Results gained from the work highlightedthat users enjoyed learning via the use of the password application, and felt they benefitted from the inclusion of gamification techniques. Future work seeks to expand the prototype into a full solution, covering a range of security awareness issues

    The Influence of Dust Formation Modelling on Na I and K I Line Profiles in Substellar Atmospheres

    Full text link
    We aim to understand the correlation between cloud formation and alkali line formation in substellar atmospheres.We perform line profile calculations for Na I and K I based on the coupling of our kinetic model for the formation and composition of dust grains with 1D radiative transfer calculations in atmosphere models for brown dwarfs and giant gas planets. The Na I and K I line profiles sensibly depend on the way clouds are treated in substellar atmosphere simulations. The kinetic dust formation model results in the highest pseudo-continuum compared to the limiting cases.Comment: 5 pages, Accepted for publication in MNRA

    The Smelling Principle of Vetiver Oil, Unveiled by Chemical Synthesis

    Get PDF
    Vetiver oil, produced on a multiton‐scale from the roots of vetiver grass, is one of the finest and most popular perfumery materials, appearing in over a third of all fragrances. It is a complex mixture of hundreds of molecules and the specific odorant, responsible for its characteristic suave and sweet transparent, woody‐ambery smell, has remained a mystery until today. Herein, we prove by an eleven‐step chemical synthesis, employing a novel asymmetric organocatalytic Mukaiyama–Michael addition, that (+)‐2‐epi‐ziza‐6(13)en‐3‐one is the active smelling principle of vetiver oil. Its olfactory evaluation reveals a remarkable odor threshold of 29 picograms per liter air, responsible for the special sensuous aura it lends to perfumes and the quasi‐pheromone‐like effect it has on perfumers and consumers alike

    Beam-Normal Single Spin Asymmetry in Elastic Electron Scattering off 28^{28}Si and 90^{90}Zr

    Full text link
    We report on a new measurement of the beam-normal single spin asymmetry AnA_{\mathrm{n}} in the elastic scattering of 570 MeV transversely polarized electrons off 28^{28}Si and 90^{90}Zr at Q2=0.04GeV2/c2Q^{2}=0.04\, \mathrm{GeV}^2/c^2. The studied kinematics allow for a comprehensive comparison with former results on 12^{12}C. No significant mass dependence of the beam-normal single spin asymmetry is observed in the mass regime from 12^{12}C to 90^{90}Zr.Comment: Submitted for publication to Physics Letters

    The Computational Complexity of Knot and Link Problems

    Full text link
    We consider the problem of deciding whether a polygonal knot in 3-dimensional Euclidean space is unknotted, capable of being continuously deformed without self-intersection so that it lies in a plane. We show that this problem, {\sc unknotting problem} is in {\bf NP}. We also consider the problem, {\sc unknotting problem} of determining whether two or more such polygons can be split, or continuously deformed without self-intersection so that they occupy both sides of a plane without intersecting it. We show that it also is in NP. Finally, we show that the problem of determining the genus of a polygonal knot (a generalization of the problem of determining whether it is unknotted) is in {\bf PSPACE}. We also give exponential worst-case running time bounds for deterministic algorithms to solve each of these problems. These algorithms are based on the use of normal surfaces and decision procedures due to W. Haken, with recent extensions by W. Jaco and J. L. Tollefson.Comment: 32 pages, 1 figur
    corecore