Conceiving Mary's Agency: Towards a Barthian Mariology

This essay argues for the possibility of a ‘Barthian’ Mariology particularly through an analysis of human agency. I first show that Karl Barth's articulation of Mary in I/2 of the Church Dogmatics marginalizes Mary's agency in part due to his anti-Roman Catholic polemic and his gender binary. I then correct Barth with Barth by showing how his mature Christology advances an account of human agency commensurate with Mariology. With this Christological account of human agency established, I construct a genuinely ‘Barthian’ Mariology that shows her as the eschatological and prototypical human agent

Compositional data analysis as a potential tool to study the (paleo)ecology of calcareous nannoplankton from the central portuguese submarine canyons (W off Portugal)

Submarine canyons are deep and steep incisions on the continental margins. The physical forcing mechanisms linked with these marine systems, such as the enhancement of upwelling and bottom sediment resuspension, are expected to provide a nutrient source that will increase phytoplankton density (Hickey, 1995, Kampf,2006). Coccolithophores are the predominant phytoplanktonic group within the calcareous nannoplankton and their sensitivity to a variety of surface water environmental parameters makes them important markers of oceanographic processes and proxies of sea surface water masses and temperatures, productivity and past climate changes (e.g. Ziveri et al., 2004; Silva et al., 2008). In the present work we propose to test compositional analysis (Buccianti & Esposito, 2004; Pawlowsky-Glahn & Egozcue, 2006) as a tool to: a) achieve a clearer distinction between opportunistic coastal-neritic species (r-strategists) and typical oceanic species (k-strategists) in the central Portuguese margin, and b) to identify a coccolith assemblage that might reflect favorable environmental conditions found in the vicinity of the canyon that promotes the productivity of calcareous nannoplankton. Our main difficulty will be in distinguishing the ecological signal from the effects of other environmental factors mentioned before (i.e. advection, dissolution, bottom resuspension). One way to infer the species’ ecological inter-relationships is by determining species relative percentages. The main concern is how the closure problem and the inconsistency of percentage determinations will affect our results. Compositional analysis was designed to provide more reliable and thus representative results, since the inference made on the coccolith assemblage features from which the data are drawn is correctly performed from a theoretical point of view (Buccianti & Esposito, 2004). Here, we present the first insights from applying compositional data analysis to coccolith assemblages from 85 surface sediment samples collected from the central Portuguese margin

Development of an open-tubular trypsin reactor for on-line digestion of proteins

A study was initiated to construct a micro-reactor for protein digestion based on trypsin-coated fused-silica capillaries. Initially, surface plasmon resonance was used both for optimization of the surface chemistry applied in the preparation and for monitoring the amount of enzyme that was immobilized. The highest amount of trypsin was immobilized on dextran-coated SPR surfaces which allowed the covalent coupling of 11 ng mm−2 trypsin. Fused-silica capillaries were modified in a similar manner and the resulting open-tubular trypsin-reactors having a pH optimum of pH 8.5, display a high activity when operated at 37 °C and are stable for at least two weeks when used continuously. Trypsin auto-digestion fragments, sample carry-over, and loss of signal due to adsorption of the protein were not observed. On-line digestion without prior protein denaturation, followed by micro-LC separation and photodiode array detection, was tested with horse-heart cytochrome C and horse skeletal-muscle myoglobin. The complete digestion of 20 pmol μL−1 horse cytochrome C was observed when the average residence time of the protein sample in a 140 cm ×50 μm capillary immobilized enzyme reactor (IMER) was 165 s. Mass spectrometric identification of the injected protein on the basis of the tryptic peptides proved possible. Protein digestion was favorable with respect to reaction time and fragments formed when compared with other on-line and off-line procedures. These results and the easy preparation of this micro-reactor provide possibilities for miniaturized enzyme-reactors for on-line peptide mapping and inhibitor screening

Structure and development of carbonate mounds along the NE Atlantic margin

Giant carbonate mounds between 500-1200 m water depth along both the SE and SW margins of Rockall Trough rise 5 to 300 m above the surrounding seafloor and have diameters at their basis of up to 5 km. Buried mounds, at relatively shallow depth below the seafloor are also found. Both individual and complex clusters of mounds can be recognized. Smaller and individual, sometimes buried mounds are found at the upper slope. On the SW Rockall Trough margin, higher, steeper and individual mounds are found deeper downslope (900-1100 m). At the middle slope the mounds merge into a complex structure and form complex clusters with a very irregular upper surface and an apparent lack of internal reflectors (600-1000 m depth). These clusters are oriented perpendicular and slightly oblique to the prevailing bathymetry, and show on TOBI profiles as linear ridges. Further results of the TOBI survey in summer 2002 show that the distribution of mounds along the flanks of SW Rockall Trough is considerably more widespread than previously considered, and also that the mounds appear to form constructional elements on a large plateau. Erosional channels between mounds identify the strong interaction between mound shape and strong bottom currents along the slopes of mounds. On the upper flank the mounds are delineated by a field of large gravelly sediment waves of 500m wavelength oriented parallel to the margin in the central part and more curved to the north. On their lower flank slide scars do locally occur

Seasonal carbon cycling in a Greenlandic fjord: an integrated pelagic and benthic study

Climate change is expected to have a pronounced effect on biogeochemical cycling in Arctic fjords, but current insight on the biogeochemical functioning of these systems is limited. Here, we present seasonal data on primary production, export of particulate organic carbon (POC), and the coupling to benthic biogeochemistry in Kobbefjord (SW Greenland). Primary production and associated POC export from the photic zone showed marked seasonality, with annual integrated values of 7.2 and 19.9 mol C m-2 yr-1, respectively. This discrepancy, the isotopic signature, and C:N ratio of the sedimentating material suggested substantial import of marine POC from outside the fjord. At least 52% of the POC export reached the sediment, but the seasonality in pelagic productivity was not reflected in the sediment biogeochemistry, showing only moderate variation. Benthic mineralization and burial of organic carbon amounted to 3.2 and 5.3 mol C m-2 yr-1, respectively. Sulfate reduction was the most prominent mineralization pathway, accounting for 69% of the benthic mineralization, while denitrification accounted for 2%. Overall, the carbon mineralization and burial in Kobbefjord were significantly higher than previously observed in other more northerly Arctic fjords. Data compilation from Arctic fjords suggests proportional increases in surface production, POC export, benthic mineralization and burial of organic material with increasing duration of the ice-free period. Thus, the projected decline in ice coverage in higher Arctic Greenlandic fjords will, as a first approximation, entail proportional increases in productivity, mineralization, and burial of organic carbon in the fjords, which will thus become similar to present-day southerly systems

Assessing the temporal scale of deep-sea mining impacts on sediment biogeochemistry

Deep-sea mining for polymetallic nodules is expected to have severe environmental impacts because not only nodules but also benthic fauna and the upper reactive sediment layer are removed through the mining operation and blanketed by resettling material from the suspended sediment plume. This study aims to provide a holistic assessment of the biogeochemical recovery after a disturbance event by applying prognostic simulations based on an updated diagenetic background model and validated against novel data on microbiological processes. It was found that the recovery strongly depends on the impact type; complete removal of the reactive surface sediment reduces benthic release of nutrients over centuries, while geochemical processes after resuspension and mixing of the surface sediment are near the pre-impact state 1 year after the disturbance. Furthermore, the geochemical impact in the DISturbance and reCOLonization (DISCOL) experiment area would be mitigated to some degree by a clay-bound Fe(II)-reaction layer, impeding the downward diffusion of oxygen, thus stabilizing the redox zonation of the sediment during transient post-impact recovery. The interdisciplinary (geochemical, numerical and biological) approach highlights the closely linked nature of benthic ecosystem functions, e.g. through bioturbation, microbial biomass and nutrient fluxes, which is also of great importance for the system recovery. It is, however, important to note that the nodule ecosystem may never recover to the pre-impact state without the essential hard substrate and will instead be dominated by different faunal communities, functions and services

Influence of diagenetic processes and terrestrial/anthropogenic sources in the REE contents of the Cascais submarine canyon (Iberian western coast)

ABSTRACT: Temporal variations of rare earth elements (REE) and their fractionation patterns, major elements, Pb and Hg were determined in two multicores collected at 445 and 2100 m water depth (mwd) in the Cascais submarine canyon (CSC). The PAAS-normalized REE patterns suggest mixing of Tagus estuarine and marine sediments, marked by MREE (Nd‐Dy series) enrichment and by positive Eu-anomaly, with marine sediments. The positive Eu/Eu* implies incorporation of detrital feldspar minerals derived from the estuary. Ce/Ce*, (La/Yb)PAAS and (Nd/Yb)PAAS show differences between the two cores. Core 252-35 from the shallower site is enriched in HREE (Ho‐Lu series) over LREE (La‐Pr series), a pattern also found in the Tagus estuary in the vicinity of an abandoned chemical complex, where the environment is affected by the legacy of massive-sulfide ores processing. There seems to be only limited down-canyon sediment transport to the deeper reaches where core 252-32 was collected. This deeper site shows Ce/Ce* peaks coinciding with low (La/Yb)PAAS values suggesting preferential diagenetic remobilization of LREE relative to HREE. Upcore Pb/Al and Hg/Corg trends observed in both cores indicate dispersion of the anthropogenic component from the estuary through the CSC, which is less obvious from the ∑REE/Al trends particularly in the deeper site. This may suggest the influence of diagenetic processes in the REE signal, associated with relatively low sediment accumulation rates.info:eu-repo/semantics/publishedVersio