568 research outputs found
Viscosity of Colloidal Suspensions
Simple expressions are given for the Newtonian viscosity as
well as the viscoelastic behavior of the viscosity of
neutral monodisperse hard sphere colloidal suspensions as a function of volume
fraction and frequency over the entire fluid range, i.e., for
volume fractions . These expressions are based on an
approximate theory which considers the viscosity as composed as the sum of two
relevant physical processes: , where is the
infinite frequency (or very short time) viscosity, with the solvent
viscosity, the equilibrium hard sphere radial distribution
function at contact, and the contribution due to the
diffusion of the colloidal particles out of cages formed by their neighbors, on
the P\'{e}clet time scale , the dominant physical process in
concentrated colloidal suspensions. The Newtonian viscosity agrees very well with the extensive experiments of Van
der Werff et al and others. Also, the asymptotic behavior for large is
of the form , in agreement
with these experiments, but the theoretical coefficient differs by a
constant factor from the exact coefficient, computed from the
Green-Kubo formula for . This still enables us to predict
for practical purposes the visco-elastic behavior of monodisperse spherical
colloidal suspensions for all volume fractions by a simple time rescaling.Comment: 51 page
Sound-propagation gap in fluid mixtures
We discuss the behavior of the extended sound modes of a dense binary
hard-sphere mixture. In a dense simple hard-sphere fluid the Enskog theory
predicts a gap in the sound propagation at large wave vectors. In a binary
mixture the gap is only present for low concentrations of one of the two
species. At intermediate concentrations sound modes are always propagating.
This behavior is not affected by the mass difference of the two species, but it
only depends on the packing fractions. The gap is absent when the packing
fractions are comparable and the mixture structurally resembles a metallic
glass.Comment: Published; withdrawn since ordering in archive gives misleading
impression of new publicatio
Dynamic structure factors of a dense mixture
We compute the dynamic structure factors of a dense binary liquid mixture.
These describe dynamics on molecular length scales, where structural relaxation
is important. We find that the presence of a few large particles in a dense
fluid of small particles slows down the dynamics considerably. We also observe
a deep narrowing of the spectrum for a disordered mixture composed of a nearly
equal packing of the two species. In contrast, a few small particles diffuse
easily in the background of a dense fluid of large particles. We expect our
results to describe neutron scattering from a dense mixture
Bounds for present value functions with stochastic interest rates and stochastic volatility.
The distribution of the present value of a series of cash flows under stochastic interest rates has been investigated by many researchers. One of the main problems in this context is the fact that the calculation of exact analytical results for this type of distributions turns out to be rather complicated, and is known only for special cases. An interesting solution to this difficulty consists of determining computable upper bounds, as close as possible to the real distribution.In the present contribution, we want to show how it is possible to compute such bounds for the present value of cash flows when not only the interest rates but also volatilities are stochastic. We derive results for the stop loss premium and distribution of these bounds.Distribution; Value; Cash flow; Interest rates; Researchers; Problems;
Theorem on the Distribution of Short-Time Particle Displacements with Physical Applications
The distribution of the initial short-time displacements of particles is
considered for a class of classical systems under rather general conditions on
the dynamics and with Gaussian initial velocity distributions, while the
positions could have an arbitrary distribution. This class of systems contains
canonical equilibrium of a Hamiltonian system as a special case. We prove that
for this class of systems the nth order cumulants of the initial short-time
displacements behave as the 2n-th power of time for all n>2, rather than
exhibiting an nth power scaling. This has direct applications to the initial
short-time behavior of the Van Hove self-correlation function, to its
non-equilibrium generalizations the Green's functions for mass transport, and
to the non-Gaussian parameters used in supercooled liquids and glasses.Comment: A less ambiguous mathematical notation for cumulants was adopted and
several passages were reformulated and clarified. 40 pages, 1 figure.
Accepted by J. Stat. Phy
Short-wavelength collective modes in a binary hard-sphere mixture
We use hard-sphere generalized hydrodynamic equations to discuss the extended
hydrodynamic modes of a binary mixture. The theory presented here is analytic
and it provides us with a simple description of the collective excitations of a
dense binary mixture at molecular length scales. The behavior we predict is in
qualitative agreement with molecular-dynamics results for soft-sphere mixtures.
This study provides some insight into the role of compositional disorder in
forming glassy configurations.Comment: Published; withdrawn since already published. Ordering in the archive
gives misleading impression of new publicatio
Hermitian clifford analysis
This paper gives an overview of some basic results on Hermitian Clifford analysis, a refinement of classical Clifford analysis dealing with functions in the kernel of two mutually adjoint Dirac operators invariant under the action of the unitary group. The set of these functions, called Hermitian monogenic, contains the set of holomorphic functions in several complex variables. The paper discusses, among other results, the Fischer decomposition, the Cauchy–Kovalevskaya extension problem, the axiomatic radial algebra, and also some algebraic analysis of the system associated with Hermitian monogenic functions. While the Cauchy–Kovalevskaya extension problem can be carried out for the Hermitian monogenic system, this system imposes severe constraints on the initial Cauchy data. There exists a subsystem of the Hermitian monogenic system in which these constraints can be avoided. This subsystem, called submonogenic system, will also be discussed in the paper
Square root singularity in the viscosity of neutral colloidal suspensions at large frequencies
The asymptotic frequency , dependence of the dynamic viscosity of
neutral hard sphere colloidal suspensions is shown to be of the form , where has been determined as a
function of the volume fraction , for all concentrations in the fluid
range, is the solvent viscosity and the P\'{e}clet time. For
a soft potential it is shown that, to leading order steepness, the asymptotic
behavior is the same as that for the hard sphere potential and a condition for
the cross-over behavior to is given. Our result for the hard
sphere potential generalizes a result of Cichocki and Felderhof obtained at low
concentrations and agrees well with the experiments of van der Werff et al, if
the usual Stokes-Einstein diffusion coefficient in the Smoluchowski
operator is consistently replaced by the short-time self diffusion coefficient
for non-dilute colloidal suspensions.Comment: 18 pages LaTeX, 1 postscript figur
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