Parameterized partial element equivalent circuit method for sensitivity analysis of multiport systems

This paper presents a new technique to perform parameterized sensitivity analyses of systems that depend on multiple design parameters, such as layout and substrate features. It uses the electromagnetic (EM) method called partial element equivalent circuit to compute state space matrices at a set of design space points. These EM matrices are interpolated as functions of the design parameters. The proposed interpolation scheme allows the computation of the derivatives of the matrices, which are needed to perform the sensitivity analysis. An extensive study of the required stability and passivity properties of the system involved in the parameterized sensitivity analysis is presented. Pertinent numerical results demonstrate the robustness, accuracy, and efficiency of the proposed methodology

Stochastic collocation for uncertainty quantification of systems described by neutral delayed differential equations

International audienceA technique is presented for variability analysis of large circuits described by neutral delayed differential equations. It is based on a delayed formulation of the partial equivalent element method coupled with stochastic collocation schemes. Pertinent numerical results validate the proposed technique

Microplastics in <i>Sepia officinalis</I> caught on the central Adriatic coast: preliminary results

Microplastics (µPs) represent an emerging problem for the marine environment given their wide bioavailability for all aquatic organisms, from zooplankton to top predators. This work aimed to evaluate a method of extracting microplastics from the gastrointestinal tract of 122 Sepia officinalis caught from the Adriatic Sea (along Abruzzo region coasts) to measure its quantity in a poorly investigated species. The extraction method used for gastrointestinal content was performed using 10% potassium hydroxide. In 98/122 (80.32-95% CI=73.27-87.37%) wild animals microplastics were detected with a mean concentration of 6.82±5.52 µPs/subject. Among the fragments, as supported by various authors, those of black color were the most represented ones; however, also blue fibers and transparent spheres were isolated. This study, in agreement with previous ones, poses further attention to the wide microplastic diffusion in the marine environment (surface, columns, sediments, and animals). The obtained results provide the basis for future investigations on this public health concern

Ultrafast charge dynamics in an amino acid induced by attosecond pulses

In the past few years, attosecond techniques have been implemented for the investigation of ultrafast dynamics in molecules. The generation of isolated attosecond pulses characterized by a relatively high photon flux has opened up new possibilities in the study of molecular dynamics. In this paper, we report on experimental and theoretical results of ultrafast charge dynamics in a biochemically relevant molecule, namely, the amino acid phenylalanine. The data represent the first experimental demonstration of the generation and observation of a charge migration process in a complexmolecule, where electron dynamics precede nuclear motion. The application of attosecond technology to the investigation of electron dynamics in biologically relevant molecules represents a multidisciplinary work, which can open new research frontiers: those in which few-femtosecond and even subfemtosecond electron processes determine the fate of biomolecules. It can also open new perspectives for the development of new technologies, for example, in molecular electronics, where electron processes on an ultrafast temporal scale are essential to trigger and control the electron current on the scale of the molecule

Attosecond Pump-Probe Spectroscopy of Charge Dynamics in Tryptophan

Attosecond pump–probe experiments performed in small molecules have allowed tracking charge dynamics in the natural time scale of electron motion. That this is also possible in biologically relevant molecules is still a matter of debate, because the large number of available nuclear degrees of freedom might destroy the coherent charge dynamics induced by the attosecond pulse. Here we investigate extreme ultraviolet-induced charge dynamics in the amino acid tryptophan. We find that, although nuclear motion and nonadiabatic effects introduce some decoherence in the moving electron wave packet, these do not significantly modify the coherence induced by the attosecond pulse during the early stages of the dynamics, at least for molecules in their equilibrium geometry. Our conclusions are based on elaborate theoretical calculations and the experimental observation of sub-4 fs dynamics, which can only be reasonably assigned to electronic motion. Hence, attosecond pump–probe spectroscopy appears as a promising approach to induce and image charge dynamics in complex molecules