292 research outputs found
Spin-gap opening accompanied by a strong magnetoelastic response in the S=1 magnetic dimer system Ba3BiRu2O9
Neutron diffraction, magnetization, resistivity, and heat capacity
measurements on the 6H-perovskite Ba3BiRu2O9 reveal simultaneous magnetic and
structural dimerization driven by strong magnetoelastic coupling. An
isostructural but strongly displacive first-order transition on cooling through
T*=176 K is associated with a change in the nature of direct Ru-Ru bonds within
Ru2O9 face-sharing octahedra. Above T*, Ba3BiRu2O9 is an S=1 magnetic dimer
system with intradimer exchange interactions J0/kB=320 K and interdimer
exchange interactions J'/kB=-160 K. Below T*, a spin-gapped state emerges with
\Delta\approx220 K. Ab initio calculations confirm antiferromagnetic exchange
within dimers, but the transition is not accompanied by long range-magnetic
order.Comment: 5 pages, 5 figures, accepted by Physical Review
Crystal growth, Structure Determination and Magnetism of a New Hexagonal Rhodate: Ba9Rh8O24
Single crystals of Ba9Rh8O24, grown from a molten potassium carbonate flux, crystallize in the spacegroup R¯3c with lattice parameters of a = 10.0899(4) and c = 41.462(2) Å. Magnetic measurements on oriented single crystals reveal the existence of magnetic anisotrop
Efficacy of bifenthrin-impregnated bednets against Anopheles funestus and pyrethroid-resistant Anopheles gambiae in North Cameroon
BACKGROUND: Recent field studies indicated that insecticide-treated bednets (ITNs) maintain their efficacy despite a high frequency of the knock-down resistance (kdr) gene in Anopheles gambiae populations. It was essential to evaluate ITNs efficacy in areas with metabolic-based resistance. METHODS: Bifenthrin was used in this experiment because it is considered a promising candidate for bednets impregnation. Nets were treated at 50 mg/m(2), a dose that has high insecticidal activity on kdr mosquitoes and at 5 mg/m(2), a dose that kills 95% of susceptible mosquitoes under laboratory conditions with 3 minutes exposure. Bednets were holed to mimic physical damage. The trial was conducted in three experimental huts from Pitoa, North-Cameroon where Anopheles gambiae displays metabolic resistance and cohabits with An. funestus. RESULTS: Bifenthrin at 50 mg/m(2 )significantly reduced anophelines' entry rate (>80%). This was not observed at 5 mg/m(2). Both treatments increased exophily in An. gambiae, and to a lesser extent in An. funestus. With bifenthrin at high dosage, over 60% reduction in blood feeding and 75–90% mortality rates were observed in both vectors. Despite presence of holes, only a single An. gambiae and two An. funestus females were collected inside the treated net, and all were found dead. The same trends were observed with low dosage bifenthrin though in most cases, no significant difference was found with the untreated control net. CONCLUSION: Bifenthrin-impregnated bednets at 50 mg/m(2 )were efficient in the reduction of human-vector contact in Pitoa. Considerable personal protection was gained against An. funestus and metabolic pyrethroid resistant An. gambiae populations
Structure Determination of Ba\u3csub\u3e8\u3c/sub\u3eCoRh\u3csub\u3e6\u3c/sub\u3eO\u3csub\u3e21\u3c/sub\u3e, a New Member of the 2H-Perovskite Related Oxides
Single crystals of Ba8CoRh6O21 were grown out of a potassium carbonate flux. The structure was solved by a general method using the superspace group approach. The superspace group employed was R3m(00γ)0s with a = 10.0431(1) Å, c1 = 2.5946(1) Å and c2 = 4.5405(1) Å, V = 226.60(1) Å3. Ba8CoRh6O21 represents the first example of an m = 5, n = 3 member of the A3n+3mA\u27nB3m+nO9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting of six consecutive RhO6 octahedra followed by one distorted CoO6 trigonal prism. These chains in turn are separated from each other by [Ba]∞ chains
Financial Threat during the Economic Crisis: Connections with the Social Representation of the Economic Crisis and the Willingness to Act
The 2008 economic crisis led numerous countries into economic hardship. Therefore, today, people feel financially threatened by this economic downturn. This threat can influence people’s willingness to act in order to cope with the economic situation. In this paper, the social representation theory helps to understand social knowledge associated with the economic crisis. The study is organized around two main objectives: (1) to compare the social representation of the economic crisis according to people’s level of financial threat, and (2) to study the mediating role of financial threat between people’s economic situations and their willingness to undertake economic actions (i.e., saving, consumption) and citizen’s activities (i.e., protests). French adults (N = 278) answered a free-association task based on the ‘economic crisis’ as the inductor, completed by financial threat, willingness to act, and a series of economic measures. First, results support the hypothesis of the existence of different social representations of the economic crisis according to the level of financial threat. Second, financial threat is also found to fully mediate the relationship between economic situation’s measures and the willingness to protest
Magnetic anomalies in the spin chain system, SrCuZnIrO
We report the results of ac and dc magnetization (M) and heat-capacity (C)
measurements on the solid solution, SrCuZnIrO. While the Zn
end member is known to form in a rhombohedral pseudo one-dimensional
KCdCl structure with an antiferromagnetic ordering temperature of
(T =) 19 K, the Cu end member has been reported to form in a monoclinically
distorted form with a Curie temperature of (T =) 19 K. The magnetism of the
Zn compound is found to be robust to synthetic conditions and is broadly
consistent with the behavior known in the literature. However, we find a lower
magnetic ordering temperature (T) for our Cu compound (~ 13 K), thereby
suggesting that T is sensitive to synthetic conditions. The Cu sample
appears to be in a spin-glass-like state at low temperatures, judged by a
frequency dependence of ac magnetic susceptibility and a broadening of the C
anomaly at the onset of magnetic ordering, in sharp contrast to earlier
proposals. Small applications of magnetic field, however, drive this system to
ferromagnetism as inferred from the M data. Small substitutions for Cu/Zn (x =
0.75 or 0.25) significantly depress magnetic ordering; in other words, T
varies non-monotonically with x (T ~ 6, 3 and 4 K for x = 0.25, 0.5, and
0.67 respectively). The plot of inverse susceptibility versus temperature is
non-linear in the paramagnetic state as if correlations within (or among) the
magnetic chains continuously vary with temperature. The results establishComment: 7 pages, 7 figures, Revte
On-site magnetization in open antiferromagnetic chains: a classical analysis versus NMR experiments in a spin-1 compound
The response of an open spin chain with isotropic antiferromagnetic
interactions to a uniform magnetic field is studied by classical Monte Carlo
simulations. It is observed how the induced on-site magnetization is non
uniform, due to the occurrence of edge staggered terms which decay
exponentially over a distance equal to the zero field correlation length of the
infinite chain. The total magnetic moment associated to each staggered term is
found to be about half of the original single-spin magnitude and to decrease as
the inverse of temperature (i.e. to behave as a Curie-like moment). The
numerical results are compared to recent NMR findings in spinless-doped
Y(2)BaNiO(5); the remarkable agreement found shows that, for temperatures above
the Haldane gap, the classical approach gives a correct picture of the boundary
effects observed in the Heisenberg S=1 chain.Comment: 4 pages, 4 eps figures; minor changes in the text; added reference
Hiérarchisation des insecticides potentiellement utilisables en lutte anti-vectorielle (LAV)
Anomalous spectral weight in photoemission spectra of the hole doped Haldane chain Y2-xSrxBaNiO5
In this paper, we present photoemission experiments on the hole doped Haldane
chain compound . By using the photon energy dependence of
the photoemission cross section, we identified the symmetry of the first
ionisation states (d type). Hole doping in this system leads to a significant
increase in the spectral weight at the top of the valence band without any
change in the vicinity of the Fermi energy. This behavior, not observed in
other charge transfer oxides at low doping level, could result from the
inhomogeneous character of the doped system and from a Ni 3d-O 2p hybridization
enhancement due to the shortening of the relevant Ni-O distance in the
localized hole-doped regions.Comment: 5 pages, 4 figure
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