The Feasibility of Reclaiming Shell Material from Investment Casting

This report examines the feasibility of investment shell component reclamation. Shell material components and their compositions are investigated with an industry survey, a study of the available literature, and analysis of specimen shell materials. physical properties and factors related to the reclamation and reuse of shell materials are described. Well known mineral processing methods are capable of producing concentrates of the various shell components. The theory and techniques of some applicable processes are discussed to assist with the development of reclamation operations. The recommended methods are; comminution by roll crushing, component concentration by screening, gravity settling or heavy medium separation. Aluminosilicate stucco (a major component of many investment shells) can be recovered in a form suitable for reuse as backup stucco. Zircon (a minor component in many shell compositions) -can be concentrated in an impure form, and subsequent caustic liberation treatments can remove the intermixed silica phases. Reuse of such zircon in investment casting may be possible but will require careful qualification testing. Fused and crystalline silica (major components of most shell compositions) are not reusable for investment casting. The feasibility of reclamation will be influenced by individual foundry choices of materials, composition and shell practice.HWRIC Project No. RRT-10NTIS PB92-16219

A proposal for regularly updated review/survey articles: "Perpetual Reviews"

We advocate the publication of review/survey articles that will be updated regularly, both in traditional journals and novel venues. We call these "perpetual reviews." This idea naturally builds on the dissemination and archival capabilities present in the modern internet, and indeed perpetual reviews exist already in some forms. Perpetual review articles allow authors to maintain over time the relevance of non-research scholarship that requires a significant investment of effort. Further, such reviews published in a purely electronic format without space constraints can also permit more pedagogical scholarship and clearer treatment of technical issues that remain obscure in a brief treatment.Comment: This is a draft white paper and we seek comments from the communit

The Parasitoid Complex of First Generation \u3ci\u3eOstrinia Nubilalis\u3c/i\u3e (Lepidoptera: Pyralidae) Larvae in Northwest Ohio

A survey of first generation European corn borer (Ostrinia nubilalis) larvae was conducted during 1997 in six cornfields located in northwestern Ohio in order to determine the larval parasitoid complex utilizing this host. Collected larvae were held under constant conditions until the larvae completed development or parasitoids emerged. The following species were recorded: Eriborus terebrans (Hymenoptera: Ichneumonidae), Macrocentrus grandii (Hymenoptera: Braconidae), Sympiesis viridula (Hymenoptera: Eulophidae), and Lixophaga sp. (Diptera: Tachinidae), Levels of parasitism in the different fields ranged from 14.3 to 83.3%. Future research will include surveys of additional fields and sampling of O. nubilalis over the entire season in the northwest Ohio region

Network Structure, Efficiency, and Performance in WikiProjects

The internet has enabled collaborations at a scale never before possible, but the best practices for organizing such large collaborations are still not clear. Wikipedia is a visible and successful example of such a collaboration which might offer insight into what makes large-scale, decentralized collaborations successful. We analyze the relationship between the structural properties of WikiProject coeditor networks and the performance and efficiency of those projects. We confirm the existence of an overall performance-efficiency trade-off, while observing that some projects are higher than others in both performance and efficiency, suggesting the existence factors correlating positively with both. Namely, we find an association between low-degree coeditor networks and both high performance and high efficiency. We also confirm results seen in previous numerical and small-scale lab studies: higher performance with less skewed node distributions, and higher performance with shorter path lengths. We use agent-based models to explore possible mechanisms for degree-dependent performance and efficiency. We present a novel local-majority learning strategy designed to satisfy properties of real-world collaborations. The local-majority strategy as well as a localized conformity-based strategy both show degree-dependent performance and efficiency, but in opposite directions, suggesting that these factors depend on both network structure and learning strategy. Our results suggest possible benefits to decentralized collaborations made of smaller, more tightly-knit teams, and that these benefits may be modulated by the particular learning strategies in use.Comment: 11 pages, 5 figures, to appear in ICWSM 201

Social Context Modulates Tolerance For Pragmatic Violations In Binary But Not Graded Judgments

A common method for investigating pragmatic processing and its development in children is to have participants make binary judgments of underinformative (UI) statements such as Some elephants are mammals. Rejection of such statements indicates that a (not-all) scalar implicature has been computed. Acceptance of UI statements is typically taken as evidence that the perceiver has not computed an implicature. Under this assumption, the results of binary judgment studies in children and adults suggest that computing an implicature may be cognitively costly. For instance, children under 7 years of age are systematically more likely to accept UI statements compared to adults. This makes sense if children have fewer processing resources than adults. However, Katsos and Bishop (2011) found that young children are able to detect violations of informativeness when given graded rather than binary response options. They propose that children simply have a greater tolerance for pragmatic violations than do adults. The present work examines whether this pragmatic tolerance plays a role in adult binary judgment tasks. We manipulated social attributes of a speaker in an attempt to influence how accepting a perceiver might be of the speaker’s utterances. This manipulation affected acceptability rates for binary judgments (Experiment 1) but not for graded judgments (Experiment 2). These results raise concerns about the widespread use of binary choice tasks for investigating pragmatic processing and undermine the existing evidence suggesting that computing scalar implicatures is costly

Development of Novel Density Functionals for Thermochemical Kinetics

A new density functional theory (DFT) exchange-correlation functional for the exploration of reaction mechanisms is proposed. This new functional, denoted BMK (Boese-Martin for Kinetics), has an accuracy in the 2 kcal/mol range for transition state barriers but, unlike previous attempts at such a functional, this improved accuracy does not come at the expense of equilibrium properties. This makes it a general-purpose functional whose domain of applicability has been extended to transition states, rather than a specialized functional for kinetics. The improvement in BMK rests on the inclusion of the kinetic energy density together with a large value of the exact exchange mixing coefficient. For this functional, the kinetic energy density appears to correct `back' the excess exact exchange mixing for ground-state properties, possibly simulating variable exchange.Comment: J. Chem. Phys., in press (303431JCP, scheduled for August 15, 2004 issue); supplementary data available at http://theochem.weizmann.ac.il/web/papers/BMK.htm

Contract Governance and the Canadian Public Sector

This essay examines the changing character of public sector work in the Canadian federal public service context. It is based on an empirical examination of various forms of contractual relations currently operative within the Canadian state and on a comparative approach of other western liberal state reform initiatives. We argue that contract governance is an ongoing process involving distinct interrelations between the public and private sectors. In this context, we identify various forms of contract governance and flexibility schemes that have been enfolded and refolded into the conventional structures of governance, and unfolded into a liminal space between the state and civil society through the establishment of nonstandard work and the creation of alternative service delivery programmes

Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs

The modular synthesis of a series of nitrogen-rich polydentate ligands that feature a common pincer-type framework is reported. These ligands allow for site-selective installation of palladium and platinum to give rise to bi- and trimetallic complexes that have d^(8)–d^(8) interactions