Structure determination of PF3 adsorption on Cu(100) using X-ray standing waves

The local structure of the Cu(100)c(4x2)-PF3 adsorption phase has been investigated through the use of normal-incidence X-ray standing waves (NIXSW), monitored by P 1s and F 1s photoemission, together with P K-edge near-edge X-ray absorption fine structure (NEXAFS). NEXAFS shows the molecule to be oriented with its C3v symmetry axis essentially perpendicular to the surface, while the P NIXSW data show the molecule to be adsorbed in atop sites 2.37±0.04 Å above the surface, this distance corresponding to the Cu-P nearest-neighbour distance in the absence of any surface relaxation. F NIXSW indicates a surprisingly small height difference of the P and F atoms above the surface 0.44±0.06 Å, compared with the value expected for an undistorted gas-phase geometry of 0.77 Å, implying significant increases in the F-P-F bond angles. In addition, however, the F NIXSW data indicate that the molecules have a well-defined azimuthal orientation with a molecular mirror plane aligned in a substrate mirror plane, and with a small (5-10°) tilt of the molecule in this plane such that the two symmetrically-equivalent F atoms in each molecule are tilted down towards the surface

奥付

This paper demonstrates the application of a numerical continuation method to dynamic piecewise aeroelastic systems. The aeroelastic system is initially converted into a state space form and then into a set of equations which solve the system as the motion moves between different linear zones in a free-play motion. Once an initial condition is found that satisfies these sets of equations, a continuation method is used to find all other possible solutions of the same period for a variation in any parameter. This process can then be repeated for different order systems, allowing the limit cycle behaviour of the whole system to be built up. The solutions found using this method have been shown to be the same as those found using a more traditional Runge-Kutta type of approach with a considerable time saving and added flexibility through multiple parameter variation

Physical Optimization of Quantum Error Correction Circuits

Quantum error correcting codes have been developed to protect a quantum computer from decoherence due to a noisy environment. In this paper, we present two methods for optimizing the physical implementation of such error correction schemes. First, we discuss an optimal quantum circuit implementation of the smallest error-correcting code (the three bit code). Quantum circuits are physically implemented by serial pulses, i.e. by switching on and off external parameters in the Hamiltonian one after another. In contrast to this, we introduce a new parallel switching method that allows faster gate operation by switching all external parameters simultaneously. These two methods are applied to electron spins in coupled quantum dots subject to a Heisenberg coupling H=J(t) S_1*S_2 which can generate the universal quantum gate `square-root-of-swap'. Using parallel pulses, the encoding for three-bit quantum error correction in a Heisenberg system can be accelerated by a factor of about two. We point out that parallel switching has potential applications for arbitrary quantum computer architectures.Comment: 13 pages, 6 figure

The value of interdisciplinary collaboration in human geography and bioethics [version 1; peer review: 1 approved, 1 approved with reservations]

Human geography and bioethics both take pride in their interdisciplinary approaches. Relatively little cross-pollination has occurred between human geography and bioethics. This paper takes three cases to highlight the generative potentials of both disciplines, dedicating time and space to learning from each other. Through doing so, we highlight these potentials by focusing on how navigating public spaces subverts the expected uses of particular spaces. We demonstrate that these are entangled with questions of responsibility that both geographers and bioethicists might find helpful. Human geographers and bioethicists can, and should, look for non-naïve ways to care for space, and we hope for this paper to be an example of where to start in the collaborative future of our disciplines

Tunable cw UV laser with <35 kHz absolute frequency instability for precision spectroscopy of Sr Rydberg states

We present a solid-state laser system that generates over 200 mW of continuous-wave, narrowband light, tunable from 316.3 nm – 317.7 nm and 318.0 nm – 319.3 nm. The laser is based on commercially available fiber amplifiers and optical frequency doubling technology, along with sum frequency generation in a periodically poled stoichiometric lithium tantalate crystal. The laser frequency is stabilized to an atomic-referenced high finesse optical transfer cavity. Using a GPS-referenced optical frequency comb we measure a long term frequency instability of < 35 kHz for timescales between 10−3 s and 103 s. As an application we perform spectroscopy of Sr Rydberg states from n = 37 – 81, demonstrating mode-hop-free scans of 24 GHz. In a cold atomic sample we measure Doppler-limited linewidths of 350 kHz

Seasonal Antarctic pressure variability during the twentieth century from spatially complete reconstructions and CAM5 simulations

As most permanent observations in Antarctica started in the 1950s, understanding Antarctic climate variations throughout the twentieth century remains a challenge. To address this issue, the non-summer multi-decadal variability in pressure reconstructions poleward of 60°S is evaluated and assessed in conjunction with climate model simulations throughout the twentieth and early twenty-first centuries to understand historical atmospheric circulation variability over Antarctica. Austral autumn and winter seasons show broadly similar patterns, with negative anomalies in the early twentieth century (1905–1934), positive pressure anomalies in the middle twentieth century (1950–1980), and negative pressure anomalies in the most recent period (1984–2013), consistent with concurrent trends in the SAM index. In autumn, the anomalies are significant in the context of estimates of interannual variability and reconstruction uncertainty across most of the Antarctic continent, and the reconstructed patterns agree best with model-generated patterns when the simulation includes the forced response to tropical sea surface temperatures and external radiative forcing. In winter and spring, the reconstructed anomalies are less significant and are consistent with internal atmospheric variability alone. The specific role of tropical SST variability on pressure trends in these seasons is difficult to assess due to low reconstruction skill in the region of strongest tropical teleconnections, the large internal atmospheric variability, and uncertainty in the SST patterns themselves. Indirect estimates of pressure variability, whether through sea ice reconstructions, proxy records, or improved models and data assimilation schemes, will help to further constrain the magnitude of internal variability relative to the forced responses expected from SST trends and external radiative forcing

A Collapse Surface for Perforated Plates with Triangular Patterns for Ligament Efficiencies Between 0.05 and 0.50

Collapse surfaces are developed for thick perforated plates containing a triangular penetration pattern with ligament efficiencies of 0.05, 0.10, 0.15, 0.2, 0.3, and 0.5 using elastic-perfectly plastic FEA analysis. The FEA data was fit to a fourth-order collapse function which is appropriate for the development of an equivalent solid elastic-perfectly plastic plasticity model for perforated plates with triangular penetration patterns. This type of model can be conveniently used to develop a limit load capability for perforated plate analysis. It was shown that the fourth-order function is reasonable for ligament efficiencies between 0.15 to 0.5. Comparing the fourth-order collapse function to FEA data suggests that an alternate collapse function is needed for ligament efficiencies less than 0.15. A linear interpolation method was shown to be appropriate for ligament efficiencies between 0.15 and 0.5

UK Coal resource for new exploitation technologies. Final report

This focus of this report are the UK coal resources available for exploitation by the new technologies of Underground Coal Gasification, Coalbed Methane production and Carbon Dioxide Sequestration. It also briefly considers the potential for further underground and opencast mining and the extraction of methane from working and closed mines. The potential for mining was mainly considered because it has a bearing on the scope for the new exploitation technologies rather than to identify resources or potential mine development areas. The report covers the UK landward area and nearshore areas, although information on the extent of underground mining was not available for the nearshore areas. This work was carried out by the British Geological Survey, with the assistance of Wardell Armstrong and Imperial College, London. It represents a summary of the results of the Study of the UK Coal Resource for New Exploitation Technologies Project, carried out for the DTI Cleaner Coal Technology Programme (Contract No. C/01/00301/00/00) under the management of Future Energy Solutions (Agreement No. C/01/00301/00/00). Coalbed methane production can be subdivided into three categories: Methane drained from working mines, known as Coal Mine Methane (CMM), has been exploited in the UK since at least the 1950s. Currently all working mines except Daw Mill and Ellington drain methane. It is used to generate electricity at Harworth, Tower and Thoresby collieries and in boilers at Welbeck, Kellingley and Ricall/Whitemoor collieries. There is potential to increase the exploitation of CMM in the UK but this is mainly a question of economics. There is also an environmental case for further utilisation, as methane is an important greenhouse gas, 23 times more powerful than carbon dioxide on a mass basis. Methane drained from abandoned mines, known as Abandoned Mine Methane (AMM), is a methane-rich gas that is obtained from abandoned mines by applying suction to the workings. The fuel gas component consists primarily of methane desorbed from seams surrounding the mined seam(s). These unmined seams have been de-stressed and fractured by the collapse of overlying and underlying strata into the void left by the extracted seam(s). Currently AMM is being exploited at sites in North Staffordshire (Silverdale Colliery), the East Midlands (Bentinck, Shirebrook and Markham collieries) and Yorkshire (Hickleton, Monk Bretton and Wheldale collieries). The methane-rich gas is used for electricity generation or supplied to local industry for use in boilers and kilns. Over the last few years, the fledgling UK AMM industry has started to ascend a learning curve. However, it has suffered a major setback since the wholesale price of electricity fell under the New Electricity Trading Arrangements and AMM does not currently qualify as renewable energy in the UK. Coalbed methane produced via boreholes from virgin coal seams, known as Virgin Coalbed Methane (VCBM), has been the subject of significant exploration effort in Lancashire, North Wales, South Wales and Scotland. The best production of gas and water from a single well is understood to be from the project at Airth, north of Falkirk in Scotland. However, this is not economic at present. The main reason for the slow development of VCBM in the UK is perceived to be the widespread low permeability of UK coal seams, although little work has been carried out in the UK on coal permeability, or to truly identify the reasons for the lack of success. This must be overcome before the otherwise significant resource bases in the Clackmannan Syncline, Canonbie, Cumbria, South Lancashire, North Wales, North Staffordshire and South Wales coalfields can be exploited. A technological breakthrough is required to overcome the likely widespread low permeability in the UK Carboniferous coal seams. Otherwise, at best, production will probably be limited to niche opportunities in areas where high seam permeability exists. The criteria used to define and map the location of VCBM resources are as follows: • Coal seams greater than 0.4 m in thickness at depths >200 m • Seam gas content >1m3/tonne • 500 metres or more horizontal separation from underground coal workings • Vertical separation of 150m above and 40 m below a previously worked seam Vertical separation of >100 m from major unconformities of these areas is thought to be about ,900 x 109 m3 (about 29 years of UK natural gas consumption). he main criteria sed for the delineation and mapping of resource areas with potential for UCG were: eparation from underground coal workings and current omic and environmental grounds as described later in this report. he establishment of these criteria do not rule out UCG projects in shallower or thinner seams, if • Vertical separation of >100 m from major aquifers, and • Areas with a CMM resource (current underground coal mining licences) were excluded. Note that the presence of a CBM resource does not imply permeability in the coal seams or that the resource can be recovered economically now or at any time in the future. Using these criteria resource areas were defined and represented on the maps. The total VCBM resource 2 Underground coal gasification (UCG) is the process whereby the injection of oxygen and steam/water via a borehole results in the partial in-situ combustion of coal to produce a combustible gas mixture consisting of CO2, CH4, H2 and CO, the proportions depending on temperature, pressure conditions and the reactant gases injected. This product gas is then extracted via a producing well for use as an energy source. All previous trials of this technology in the UK took place in the 1950’s or before, e.g. Durham (1912), Newman Spinney (1949-1956) and Bayton (c.1955), although this country is well placed for UCG, with large reserves of indigenous coal both onshore and offshore. T u • Seams of 2 m thickness or greater • Seams at depths between 600 and 1200 m from the surface • 500 m or more horizontal and vertical scoal mining licences, and • Greater than 100 m from major aquifers While seams outside these depth and thicknesses criteria are known to support UCG, the criteria were chosen for this generic study on econ T local site specific factors support it. Mapping of the potential UCG resource has identified large areas suitable for UCG, particularly in Eastern England, Midland Valley of Scotland, North Wales, Cheshire Basin, South Lancashire, Canonbie, the Midlands and Warwickshire. Potential also exists in other coalfields but on a smaller scale; this is often limited by the extent of former underground coal mining activities. The total area where coals are suitable for gasification is approximately 2.8 x 109m2. Where the criteria for UCG are met, the minimum volume of coal available for gasification, calculated assuming only one 2 m thick seam meets the criteria across each area, is app63 roximately 5,698 x 10 m (~7 Btonnes). Using an verage of the total thickness of coals that meet the criteria across each area gives a more realistic source figure of 12,911 x 106m3 (~17 Btonnes). pass the expensive step of parating the CO2 from flue gases. If the main objective, however, is CO2 sequestration rather than ethane production then separation of the flue gases may be worthwhile. O2 on coal seams, is would render them unminable and ungasifiable (because the CO2 would be released). Any future ining of such coals would require re-capture and sequestration of the stored CO . ion, providing that other issues, such as low seam permeability, can be vercome. Large areas where coal is below 1,200 m occur in the UK, particularly in the Cheshire asin and Eastern England. In summary • and its potential application in the UK cannot be assessed. However, there are vast areas of coal at depths below 1,200 m that are possibly too deep for mining and in situ gasification

Implementation of a Deutsch-like quantum algorithm utilizing entanglement at the two-qubit level, on an NMR quantum information processor

We describe the experimental implementation of a recently proposed quantum algorithm involving quantum entanglement at the level of two qubits using NMR. The algorithm solves a generalisation of the Deutsch problem and distinguishes between even and odd functions using fewer function calls than is possible classically. The manipulation of entangled states of the two qubits is essential here, unlike the Deutsch-Jozsa algorithm and the Grover's search algorithm for two bits.Comment: 4 pages, two eps figure