986 research outputs found

    India's Climate Policy: Squaring the Circle

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    The Durban Platform process towards a new global climate agreement has thrown open for debate all issues, including those earlier settled in the Kyoto Protocol. Any new compact must ensure sharply reduced global emissions as required by science, while adhering to principles of equity between nations regarding utilisation of the atmospheric commons. India faces serious difficulties in reconciling international expectations and domestic developmental priorities. India's recent economic growth, increased emissions and great power ambitions suggest greater need and capacity for mitigation whereas its continuing burden of income and energy poverty severely inhibits additional commitments. This article examines the factors driving India's negotiating position. It argues that an equitable development perspective within India, a clearer appreciation of climate science and its likely impacts, and a more balanced view of its diplomatic interests especially in the global South, would yield a more coherent position than a US or first world?driven agenda and inevitable defensive reactions

    Going-Concern Audit Report Recipients Before and After SAS No. 59

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    In an attempt to provide information to make an evaluation on whether the requirements under SAS No. 59 have had any significant effect on auditor reporting decisions, a study was conducted that examined companies receiving going-concern modified reports before and after the implementation of SAS No. 59. We wanted to assess whether auditors were issuing going-concern modified reports to clients exhibiting different levels of financial stress and also whether the bankruptcy rate of such companies was different after the adoption of SAS No. 59

    Classification of tropospheric ozone profiles over Johannesburg based on MOZAIC aircraft data

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    International audienceEach ozone profile is a unique response to the photochemical and dynamic processes operating in the troposphere and hence is critical to our understanding of processes and their relative contributions to the tropospheric ozone budget. Traditionally, mean profiles, together with some measure of variability, averaged by season or year at a particular location have been presented as a climatology. However, the mean profile is difficult to interpret because of the counteracting influences present in the micro-structure. On the other hand, case study analysis, whilst revealing, only applies to isolated conditions. In a search for pattern and order within ozone profiles, a classification based on a cluster analysis technique has been applied in this study. Ozone profiles are grouped according to the magnitude and altitude of ozone concentration. This technique has been tested with 56 ozone profiles at Johannesburg, South Africa, recorded by aircraft as part of the MOZAIC (Measurement of Ozone and Water Vapor aboard Airbus In-service Aircraft) program. Six distinct groups of ozone profiles have been identified and their characteristics described. The widely recognized spring maximum in tropospheric ozone is identified through the classification, but a new summertime mid-tropospheric enhancement due to the penetration of tropical air masses from continental regions in central Africa has been identified. Back trajectory modeling is used to provide evidence of the different origins of ozone enhancements in each of the classes. Continental areas over central Africa are shown to be responsible for the low to mid-tropospheric enhancement in spring and the mid-tropospheric peak in summer, whereas the winter low-tropospheric enhancement is attributed to local sources. The dominance of westerly winds through the troposphere associated with the passage of a mid-latitude cyclone gives rise to reduced ozone values

    Revisiting seismic hazard assessment for Peninsular Malaysia using deterministic and probabilistic approaches

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    Seismic hazard assessments, both deterministic and probabilistic, for Peninsular Malaysia have been carried out using peak ground acceleration (PGA) data recorded between 2004 and 2016 by the Malaysian Meteorological Department using triaxial accelerometers placed at 19 seismic stations on the peninsula. Seismicity source modelling for the deterministic seismic hazard assessment (DSHA) used historical point sources whereas in the probabilistic (PSHA) approach, line and areal sources were used. The earthquake sources comprised the Sumatran subduction zone (SSZ), Sumatran fault zone (SFZ) and local intraplate (LI) faults. Gutenberg–Richter law b value for the various zones identified within the SSZ ranged between 0.56 and 1.06 (mean = 0.82) and for the zones within the SFZ, between 0.57 and 1.03 (mean = 0.89). Suitable ground motion prediction equations (GMPEs) for Peninsular Malaysia along with other pertinent information were used for constructing a logic tree for PSHA of the region. The DSHA critical-worst scenario suggests PGAs of 0.07–0.80&thinsp;ms−2 (0.7–8.2 percent g), whilst the PSHA suggests mean PGAs of 0.11–0.55&thinsp;ms−2 (0.5–5.4 percent g) and 0.20–1.02&thinsp;ms−2 (1.9–10.1 percent g) at 10&thinsp;% and 2&thinsp;% probability of exceedance in 50 years, respectively. DSHA and PSHA, despite using different source models and methodologies, both conclude that the central-western cities of Peninsular Malaysia, located between 2 and 4°&thinsp;N, are most susceptible to high PGAs, due to neighbouring active Sumatran sources, SFZ and SSZ. Of the two Sumatran sources, surprisingly, the relatively less active SFZ source with low magnitude seismicity appeared as the major contributor due to its proximity. However, potential hazards due to SSZ mega-earthquakes should not be dismissed. Finally, DSHA performed using the limited LI seismic data from the Bukit Tinggi fault at a reasonable moment magnitude (Mw) value of 5.0 predicted a PGA of  ∼ 0.40&thinsp;ms−2 at Kuala Lumpur.</p

    Identification of H2_2CCC as a diffuse interstellar band carrier

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    We present strong evidence that the broad, diffuse interstellar bands (DIBs) at 4881 and 5450\,\AA are caused by the B\,^1B1_1\,\leftarrow\,X\,^1A1_1 transition of H2_2CCC (l-C3_3H2_2). The large widths of the bands are due to the short lifetime of the B\,^1B1_1 electronic state. The bands are predicted from absorption measurements in a neon matrix and observed by cavity ring-down in the gas phase and show exact matches to the profiles and wavelengths of the two broad DIBs. The strength of the 5450\,\AA DIB leads to a l-C3_3H2_2 column density of 5×1014\sim5\times10^{14} cm2^{-2} towards HD\,183143 and 2×1014\sim2\times10^{14}\,cm2^{-2} to HD\,206267. Despite similar values of EE(BVB-V), the 4881 and 5450\,\AA DIBs in HD\,204827 are less than one third their strength in HD\,183143, while the column density of interstellar C3_3 is unusually high for HD\,204827 but undetectable for HD\,183143. This can be understood if C3_3 has been depleted by hydrogenation to species such as l-C3_3H2_2 towards HD\,183143. There are also three rotationally resolved sets of triplets of l-C3_3H2_2 in the 6150-6330\,\AA region. Simulations, based on the derived spectroscopic constants and convolved with the expected instrumental and interstellar line broadening, show credible coincidences with sharp, weak DIBs for the two observable sets of triplets. The region of the third set is too obscured by the α\alpha-band of telluric O2_2.Comment: 22 pages, 9 figure

    Probing the unusual anion mobility of LiBH_4 confined in highly ordered nanoporous carbon frameworks via solid state NMR and quasielastic neutron scattering

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    Particle size and particle–framework interactions have profound effects on the kinetics, reaction pathways, and even thermodynamics of complex hydrides incorporated in frameworks possessing nanoscale features. Tuning these properties may hold the key to the utilization of complex hydrides in practical applications for hydrogen storage. Using carefully synthesized, highly-ordered, nanoporous carbons (NPCs), we have previously shown quantitative differences in the kinetics and reaction pathways of LiBH_4 when incorporated into the frameworks. In this paper, we probe the anion mobility of LiBH_4 confined in NPC frameworks by a combination of solid state NMR and quasielastic neutron scattering (QENS) and present some new insights into the nanoconfinement effect. NMR and QENS spectra of LiBH_4 confined in a 4 nm pore NPC suggest that the BH_4− anions nearer the LiBH_4–carbon pore interface exhibit much more rapid translational and reorientational motions compared to those in the LiBH_4 interior. Moreover, an overly broadened BH_4− torsional vibration band reveals a disorder-induced array of BH_4− rotational potentials. XRD results are consistent with a lack of LiBH_4 long-range order in the pores. Consistent with differential scanning calorimetry measurements, neither NMR nor QENS detects a clear solid–solid phase transition as observed in the bulk, indicating that borohydride–framework interactions and/or nanosize effects have large roles in confined LiBH_4

    Development and evaluation of gastro retentive floating tablets of anti hyperlipidemic drug

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    The aim of the present study was to develop Gastro retentive effervescent floating tablets (GREFT) containing 20 mg of simvastatin were developed by direct compression method using HPMC K4M, HPMC K15M, HPMC K100M with different drug to polymer ratio. Tablets were evaluated for their physical characteristics, viz., hardness, friability, drug content and floating properties. Further, tablets were studied for in vitro drug release characteristics for 12 h. The tablets exhibited controlled and prolonged drug release, with optimum hardness, consistent uniformity in weight and low friability. The formulation with F2 (HPMC K100M 1:3 ratio) showed 85.83 % drug release at the end of 12 h and exhibited optimum floating lag time. A decrease in release rate of the drug was observed on increasing polymer ratio and also by increasing viscosity grades of the polymer (HPMC). Drug release from effervescent floating matrix tablets was sustained over 12 h with buoyant properties. DSC study revealed that there is no drug excipient interaction. Based on the release kinetics, all formulations best fitted the Higuchi, first-order model and non-Fickian as the mechanism of drug release. Optimized formulation (F9) was selected based on the similarity factor (f2) (71.32) and invitro dissolution was used in radiographic studies by incorporating BaSO4. In vivo X-ray studies in human volunteers showed that the mean gastric residence time was 5.4 ± 0.32 h

    New Moments Based Fuzzy Similarity Measure for Text Detection in Distorted Social Media Images

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    A trend towards capturing or filming images using cellphone and sharing images on social media is a part and parcel of day to day activities of humans. When an image is forwarded several times in social media it may be distorted a lot due to several different devices. This work deals with text detection from such distorted images. In this work, we consider images pass through three mobile devices on WhatsApp social media, which results in four images (including the original image) Unlike the existing methods that aim at developing new ways, we utilize the results detected by the existing ones to improve performances. The proposed method extracts Hu moments and fuzzy logic from detected texts of images. The similarity between text detection results given by three existing text detection methods is studied for determining the best pair of texts. The same similarity estimation is then used in a novel way to remove extra background or non-texts and restoring missing text information. Experimental results on own dataset and benchmark datasets of natural scene images, namely, MSRA-TD500, ICDAR2017-MLT, Total-Text, CTW1500 dataset and COCO datasets, show that the proposed method outperforms the existing methods

    The RETRIEVE checklist for studies reporting the elicitation of stated preferences for child health related quality of life

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    Recent systematic reviews show varying methods for eliciting, modelling, and reporting preference-based values for child health-related quality-of-life (HRQoL) outcomes, producing value-sets with different characteristics. Checklists can improve standards of reporting; however, existing checklists do not address methodological issues for valuing child HRQoL. We aimed to develop a checklist for studies generating values for child HRQoL, including for disease-specific states and value-sets for generic child HRQoL instruments. A conceptual model provided a structure for grouping items into five modules. Potential items were sourced from an adult HRQoL checklist review, with additional items specific to children developed using recent reviews. Checklist items were reduced by eliminating duplication and overlap, then refined for relevance and clarity via an iterative process. Long and short checklist versions were produced for different user needs. The resulting long RETRIEVE contains 83 items, with modules for reporting methods (A-D) and characteristics of values (E), for researchers planning and reporting child health valuation studies. The short RETRIEVE contains 14 items for decision-makers or researchers choosing value-sets. Applying the RETRIEVE checklists to relevant studies suggests feasibility. RETRIEVE has the potential to improve completeness in the reporting of preference-based values for child HRQOL outcomes and to improve assessment of preference-based value-sets
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