Fingering Instabilities on Reaction Fronts in the CO Oxidation Reaction on Pt(100)

Fingering instabilities arising from local perturbations to planar reaction fronts in the CO oxidation reaction on Pt(100) are presented. CO oxidation represents a heterogeneous nonlinear system with the necessary kinetic and diffusive transport properties to support the development of fingered wave fronts. External forcing was utilized to create CO wave fronts on an otherwise monostable, O-covered surface, which, upon destabilization, gave rise to fingers of adsorbed CO extending into the O adlayer ahead of the reaction front. Finger spreading and tip-splitting were observed as the finger pattern evolved towards an intrinsic wavelength, independent of the length of the reaction front, calculated to be approximately 40 μm. Our data also show the presence of a shielding process, where at wavelengths less than twice the observed intrinsic value, additional fingers were created on the reaction front through a tip-splitting bifurcation of an existing finger. At wavelengths greater than twice the intrinsic value, additional fingers formed in the troughs between adjacent fingers, apparently unaffected by the presence of the larger surrounding fingers

Development of Simplified Models of Regional Groundwater and Surface Water Flow Processes based on Computational Experiments with Comprehensive Models

The development of complex decision support model systems for the analysis of regional water policies for regions with intense socio-economic development affecting and being affected by the water resources system is of increasing importance. One of the most illustrative examples are regions with open-pit lignite mining. Such model systems have to be based on appropriate submodels, e.g. for water quantity processes. The paper describes submodels for groundwater and surface water flow with special regard to open-pit lignite mining regions. Starting with a problem definition in Section 2 the methodological background is given. The state-of-the-art of comprehensive models of regional water flow processes based on groundwater flow models and of stochastic long-term management modeling are described in details. Section 3 gives the methodological approach for model reduction. The application of this approach is illustrated in Section 4 for the modeling of mine drainage and groundwater tables, for the modeling of remaining pit management and of groundwater-surface water interactions. In the appendix computer programs of some submodels are given being suitable for a more general application

The Differential Diagnosis of Congenital Disorders that Include Psychosis

Summary: Neuropsychiatrists should be aware of congenital disorders that can present with psychosis, however rarely. Recommends a differential diagnosticapproach based on estimated prevalence of the disorders and their most prominent associated neuropsychiatric features

School Counselor Knowledge, Beliefs, and Practices Related to the Implementation of Standards-Based Comprehensive School Counseling in the United States

As school counselors have adapted to changing policy and social structures, their beliefs, knowledge, and practices have evolved. Over the past two decades, a body of survey research has examined school counselors’ beliefs, knowledge, and practices, though no systematic review exists. In this review, we synthesize and evaluate survey research on the knowledge, beliefs, and practices relevant to the implementation of a standards-based comprehensive school counseling model in the United States. We identify the most salient findings, evaluate the research, identify the most rigorous studies, discuss their findings, and provide recommendations for future research. Considering the recent changes to how funding is distributed to states and schools within the Every Student Succeeds Act of 2015, such research is both timely and necessary to help clarify and increase the role school counselors play in helping schools achieve the goals of legislation

Statistically Guided Synthesis of MoV- Based Mixed Oxide Catalysts for Ethane Partial Oxidation

The catalytic performance of Mo8V2Nb1-based mixed-oxide catalysts for ethane partial oxidation is highly sensitive to the doping of elements with redox and acid functionality. Specifically, control over product distributions to ethylene and acetic acid can be afforded via the specific pairing of redox elements (Pd, Ni, Ti) and acid elements (K, Cs, Te) and the levels at which these elements are doped. The redox element, acid element, redox/acid ratio, and dopant/host ratio were investigated using a three-level, four-factor factorial screening design to establish relationships between catalyst composition, structure, and product distribution for ethane partial oxidation. Results show that the balance between redox and acid functionality and overall dopant level is important for maximizing the formation of each product while maintaining the structural integrity of the host metal oxide. Overall, ethylene yield was maximized for a Mo8V2Nb1Ni0.0025Te0.5 composition, while acetic acid yield was maximized for a Mo8V2Nb1Ti0.005Te1 catalyst

Statistically Guided Synthesis of MoV-Based Mixed-Oxide Catalysts for Ethane Partial Oxidation

The catalytic performance of Mo8V2Nb1-based mixed-oxide catalysts for ethane partial oxidation is highly sensitive to the doping of elements with redox and acid functionality. Specifically, control over product distributions to ethylene and acetic acid can be afforded via the specific pairing of redox elements (Pd, Ni, Ti) and acid elements (K, Cs, Te) and the levels at which these elements are doped. The redox element, acid element, redox/acid ratio, and dopant/host ratio were investigated using a three-level, four-factor factorial screening design to establish relationships between catalyst composition, structure, and product distribution for ethane partial oxidation. Results show that the balance between redox and acid functionality and overall dopant level is important for maximizing the formation of each product while maintaining the structural integrity of the host metal oxide. Overall, ethylene yield was maximized for a Mo8V2Nb1Ni0.0025Te0.5 composition, while acetic acid yield was maximized for a Mo8V2Nb1Ti0.005Te1 catalyst

High- and low-mobility stages in the synaptic vesicle cycle.

Synaptic vesicles need to be mobile to reach their release sites during synaptic activity. We investigated vesicle mobility throughout the synaptic vesicle cycle using both conventional and subdiffraction-resolution stimulated emission depletion fluorescence microscopy. Vesicle tracking revealed that recently endocytosed synaptic vesicles are highly mobile for a substantial time period after endocytosis. They later undergo a maturation process and integrate into vesicle clusters where they exhibit little mobility. Despite the differences in mobility, both recently endocytosed and mature vesicles are exchanged between synapses. Electrical stimulation does not seem to affect the mobility of the two types of vesicles. After exocytosis, the vesicle material is mobile in the plasma membrane, although the movement appears to be somewhat limited. Increasing the proportion of fused vesicles (by stimulating exocytosis while simultaneously blocking endocytosis) leads to substantially higher mobility. We conclude that both high- and low-mobility states are characteristic of synaptic vesicle movement

Self-Healing Catalysts: CO\u3csub\u3e3\u3c/sub\u3eO\u3csub\u3e4\u3c/sub\u3e Nanorods for Fischer-Tropsch Synthesis

We combine kinetic and spectroscopic data to demonstrate the concept of a self-healing catalyst, which effectively eliminates the need for catalyst regeneration. The observed self-healing is triggered by controlling the crystallographic orientation at the catalyst surface

MOBILE MAPPING OF THE LA CORONA LAVATUBE ON LANZAROTE

Abstract. Planetary surfaces consist of rough terrain and cave-like environments. Future planetary exploration demands for accurate mapping. However, recent backpack mobile mapping systems are mostly tested in structured, indoor environments. This paper evaluates the use of a backpack mobile mapping system in a cave-like environment. The experiments demonstrate the abilities of an continuous-time optimization approach by mapping part of a lavatube of the La Corona volcano system on Lanzarote. We compare two strategies for trajectory estimation relying either on 2D or 3D laser scanners and show that a 3D laser scanner substantially improved the final results.</p