Measurement and analysis of critical crack tip processes during fatigue crack growth

The mechanics of fatigue crack growth under constant-amplitudes and variable-amplitude loading were examined. Critical loading histories involving relatively simple overload and overload/underload cycles were studied to provide a basic understanding of the underlying physical processes controlling crack growth. The material used for this study was 7091-T7E69, a powder metallurgy aluminum alloy. Local crack-tip parameters were measured at various times before, during, and after the overloads, these include crack-tip opening loads and displacements, and crack-tip strain fields. The latter were useed, in combination with the materials cyclic and monotonic stress-strain properties, to compute crack-tip residual stresses. The experimental results are also compared with analytical predictions obtained using the FAST-2 computer code. The sensitivity of the analytical model to constant-amplitude fatigue crack growth rate properties and to through-thickness constrain are studied

Lifetime and polarization of the radiative decay of excitons, biexcitons and trions in CdSe nanocrystal quantum dots

Using the pseudopotential configuration-interaction method, we calculate the intrinsic lifetime and polarization of the radiative decay of single excitons (X), positive and negative trions (X+ and X−), and biexcitons (XX) in CdSe nanocrystal quantum dots. We investigate the effects of the inclusion of increasingly more complex many-body treatments, starting from the single-particle approach and culminating with the configuration-interaction scheme. Our configuration-interaction results for the size dependence of the single-exciton radiative lifetime at room temperature are in excellent agreement with recent experimental data. We also find the following. (i) Whereas the polarization of the bright exciton emission is always perpendicular to the hexagonal c axis, the polarization of the dark exciton switches from perpendicular to parallel to the hexagonal c axis in large dots, in agreement with experiment. (ii) The ratio of the radiative lifetimes of mono- and biexcitons (X):(XX) is ~1:1 in large dots (R=19.2 Å). This ratio increases with decreasing nanocrystal size, approaching 2 in small dots (R=10.3 Å). (iii) The calculated ratio (X+):(X−) between positive and negative trion lifetimes is close to 2 for all dot sizes considered

Alloying effects on the optical properties of Ge1−x_{1-x}Six_x nanocrystals from TDDFT and comparison with effective-medium theory

We present the optical spectra of Ge$_{1-x}$Si$_x$ alloy nanocrystals calculated with time-dependent density-functional theory in the adiabatic local-density ap proximation (TDLDA). The spectra change smoothly as a function of the compositio n $x$. On the Ge side of the composition range, the lowest excitations at the ab sorption edge are almost pure Kohn-Sham independent-particle HOMO-LUMO transitio ns, while for higher Si contents strong mixing of transitions is found. Within T DLDA the first peak is slightly higher in energy than in earlier independent-par ticle calculations. However, the absorption onset and in particular its composit ion dependence is similar to independent-particle results. Moreover, classical depolarization effects are responsible for a very strong suppression of the abs orption intensity. We show that they can be taken into account in a simpler way using Maxwell-Garnett classical effective-medium theory. Emission spectra are in vestigated by calculating the absorption of excited nanocrystals at their relaxe d geometry. The structural contribution to the Stokes shift is about 0.5 eV. Th e decomposition of the emission spectra in terms of independent-particle transit ions is similar to what is found for absorption. For the emission, very weak tra nsitions are found in Ge-rich clusters well below the strong absorption onset.Comment: submitted to Phys. Rev.

Resonant Energy Exchange between Atoms in Dispersing and Absorbing Surroundings

Within the framework of quantization of the macroscopic electromagnetic field, a master equation describing both the resonant dipole-dipole interaction (RDDI) and the resonant atom-field interaction (RAFI) in the presence of dispersing and absorbing macroscopic bodies is derived, with the relevant couplings being expressed in terms of the surroundings-assisted Green tensor. It is shown that under certain conditions the RDDI can be regarded as being governed by an effective Hamiltonian. The theory, which applies to both weak and strong atom-field coupling, is used to study the resonant energy exchange between two (two-level) atoms sharing initially a single excitation. In particular, it is shown that in the regime of weak atom-field coupling there is a time window, where the energy transfer follows a transfer-rate law of the type obtained by ordinary second-order perturbation theory. Finally, the spectrum of the light emitted during the energy transfer is studied and the line splittings are discussed.Comment: 9 pages, 5 figs, Proceedings of ICQO'2002, Raubichi, to appear in Optics and Spectroscop

Radiative Models of Sagittarius A* and M87 from Relativistic MHD Simulations

Ongoing millimeter VLBI observations with the Event Horizon Telescope allow unprecedented study of the innermost portion of black hole accretion flows. Interpreting the observations requires relativistic, time-dependent physical modeling. We discuss the comparison of radiative transfer calculations from general relativistic MHD simulations of Sagittarius A* and M87 with current and future mm-VLBI observations. This comparison allows estimates of the viewing geometry and physical conditions of the Sgr A* accretion flow. The viewing geometry for M87 is already constrained from observations of its large-scale jet, but, unlike Sgr A*, there is no consensus for its millimeter emission geometry or electron population. Despite this uncertainty, as long as the emission region is compact, robust predictions for the size of its jet launching region can be made. For both sources, the black hole shadow may be detected with future observations including ALMA and/or the LMT, which would constitute the first direct evidence for a black hole event horizon.Comment: 8 pages, 2 figures, submitted to the proceedings of AHAR 2011: The Central Kiloparse

Sustainable Water Infrastructure:Visions and Options for Sub-Saharan Africa

Developing a sustainable water infrastructure entails the planning and management of water systems to ensure the availability, access, quality, and affordability of water resources in the face of social, environmental, and economic challenges. Sub-Saharan Africa (SSA) is currently in an era where it must make significant changes to improve the sustainability of its water infrastructure. This paper reviews the factors affecting water infrastructure sustainability and the interventions taken globally to address these challenges. In parallel, it reflects on the relevance of these interventions to the context of Sub-Saharan Africa through the lens of the STEEP (societal, technological, economic, environmental, political) framework. The paper goes on to recommend an extended analysis that captures additional critical dimensions when applying the concept of sustainability. Furthermore, this paper sheds light on the practice of sustainable development and fosters a deeper understanding of the issues, thereby forming the basis for further research and the development of sustainable and resilient solutions for water infrastructure and water asset management more generally

Locating the intense interstellar scattering towards the inner Galaxy

We use VLBA+VLA observations to measure the sizes of the scatter-broadened images of 6 of the most heavily scattered known pulsars: 3 within the Galactic Centre (GC) and 3 elsewhere in the inner Galactic plane. By combining the measured sizes with temporal pulse broadening data from the literature and using the thin-screen approximation, we locate the scattering medium along the line of sight to these 6 pulsars. At least two scattering screens are needed to explain the observations of the GC sample. We show that the screen inferred by previous observations of SGR J1745-2900 and Sgr A*, which must be located far from the GC, falls off in strength on scales < 0.2 degree. A second scattering component closer to (< 2 kpc) or even (tentatively) within (< 700 pc) the GC produces most or all of the temporal broadening observed in the other GC pulsars. Outside the GC, the scattering locations for all three pulsars are ~2 kpc from Earth, consistent with the distance of the Carina-Sagittarius or Scutum spiral arm. For each object the 3D scattering origin coincides with a known HII region (and in one case also a supernova remnant), suggesting that such objects preferentially cause the intense interstellar scattering seen towards the Galactic plane. We show that the HII regions should contribute > 25% of the total dispersion measure (DM) towards these pulsars, and calculate reduced DM distances. Those distances for other pulsars lying behind HII regions may be similarly overestimated.Comment: 16 pages, 10 figures, MNRAS, in pres