37 research outputs found

    Elucidation of cationic polymerization mechanisms by means of quantum chemical methods

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    Mechanochemistry: The Mechanical Activation of Covalent Bonds

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    Deciphering protein post-translational modifications using chemical biology tools

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    Performance of the ALICE Electromagnetic Calorimeter

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    International audienceThe performance of the electromagnetic calorimeter of theALICE experiment during operation in 2010–2018 at the Large HadronCollider is presented. After a short introduction into the design,readout, and trigger capabilities of the detector, the proceduresfor data taking, reconstruction, and validation are explained. Themethods used for the calibration and various derived corrections arepresented in detail. Subsequently, the capabilities of thecalorimeter to reconstruct and measure photons, light mesons,electrons and jets are discussed. The performance of thecalorimeter is illustrated mainly with data obtained with test beamsat the Proton Synchrotron and Super Proton Synchrotron or inproton-proton collisions at √s = 13 TeV, and compared tosimulations

    Neutron emission in ultraperipheral Pb-Pb collisions at sNN\sqrt {s_{NN}} = 5.02 TeV

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    In ultraperipheral collisions (UPCs) of relativistic nuclei without overlap of nuclear densities, the two nuclei are excited by the Lorentz-contracted Coulomb fields of their collision partners. In these UPCs, the typical nuclear excitation energy is below a few tens of MeV, and a small number of nucleons are emitted in electromagnetic dissociation (EMD) of primary nuclei, in contrast to complete nuclear fragmentation in hadronic interactions. The cross sections of emission of given numbers of neutrons in UPCs of 208^{208}Pb nuclei at sNN=5.02\sqrt{s_{\mathrm{NN}}}=5.02~TeV were measured with the neutron zero degree calorimeters (ZDCs) of the ALICE detector at the LHC, exploiting a similar technique to that used in previous studies performed at sNN=2.76\sqrt{s_{\mathrm{NN}}}=2.76~TeV. In addition, the cross sections for the exclusive emission of 1, 2, 3, 4 and 5 forward neutrons in the EMD, not accompanied by the emission of forward protons, and thus mostly corresponding to the production of 207,206,205,204,203^{207,206,205,204,203}Pb, respectively, were measured for the first time. The predictions from the available models describe the measured cross sections well. These cross sections can be used for evaluating the impact of secondary nuclei on the LHC components, in particular, on superconducting magnets, and also provide useful input for the design of the Future Circular Collider (FCC-hh).In ultraperipheral collisions (UPCs) of relativistic nuclei without overlap of nuclear densities, the two nuclei are excited by the Lorentz-contracted Coulomb fields of their collision partners. In these UPCs, the typical nuclear excitation energy is below a few tens of MeV, and a small number of nucleons are emitted in electromagnetic dissociation (EMD) of primary nuclei, in contrast to complete nuclear fragmentation in hadronic interactions. The cross sections of emission of given numbers of neutrons in UPCs of Pb208 nuclei at sNN=5.02 TeV were measured with the neutron zero degree calorimeters (ZDCs) of the ALICE detector at the LHC, exploiting a similar technique to that used in previous studies performed at sNN=2.76 TeV. In addition, the cross sections for the exclusive emission of one, two, three, four, and five forward neutrons in the EMD, not accompanied by the emission of forward protons, and thus mostly corresponding to the production of Pb207,206,205,204,203, respectively, were measured for the first time. The predictions from the available models describe the measured cross sections well. These cross sections can be used for evaluating the impact of secondary nuclei on the LHC components, in particular, on superconducting magnets, and also provide useful input for the design of the Future Circular Collider (FCC-hh).In ultraperipheral collisions (UPCs) of relativistic nuclei without overlap of nuclear densities, the two nuclei are excited by the Lorentz-contracted Coulomb fields of their collision partners. In these UPCs, the typical nuclear excitation energy is below a few tens of MeV, and a small number of nucleons are emitted in electromagnetic dissociation (EMD) of primary nuclei, in contrast to complete nuclear fragmentation in hadronic interactions. The cross sections of emission of given numbers of neutrons in UPCs of 208^{208}Pb nuclei at sNN=5.02\sqrt{s_{\mathrm{NN}}}=5.02 TeV were measured with the neutron zero degree calorimeters (ZDCs) of the ALICE detector at the LHC, exploiting a similar technique to that used in previous studies performed at sNN=2.76\sqrt{s_{\mathrm{NN}}}=2.76 TeV. In addition, the cross sections for the exclusive emission of one, two, three, four, and five forward neutrons in the EMD, not accompanied by the emission of forward protons, and thus mostly corresponding to the production of 207,206,205,204,203^{207,206,205,204,203}Pb, respectively, were measured for the first time. The predictions from the available models describe the measured cross sections well. These cross sections can be used for evaluating the impact of secondary nuclei on the LHC components, in particular, on superconducting magnets, and also provide useful input for the design of the Future Circular Collider (FCC-hh)

    Measurement of inclusive and leading subjet fragmentation in pp and Pb–Pb collisions at sNN \sqrt{s_{\textrm{NN}}} = 5.02 TeV

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    This article presents new measurements of the fragmentation properties of jets in both proton--proton (pp) and heavy-ion collisions with the ALICE experiment at the Large Hadron Collider (LHC). We report distributions of the fraction zrz_r of transverse momentum carried by subjets of radius rr within jets of radius RR. Charged-particle jets are reconstructed at midrapidity using the anti-kTk_{\rm{T}} algorithm with jet radius R=0.4R=0.4, and subjets are reconstructed by reclustering the jet constituents using the anti-kTk_{\rm{T}} algorithm with radii r=0.1r=0.1 and r=0.2r=0.2. In proton--proton collisions, we measure both the inclusive and leading subjet distributions. We compare these measurements to perturbative calculations at next-to-leading logarithmic accuracy, which suggest a large impact of threshold resummation and hadronization effects on the zrz_r distribution. In heavy-ion collisions, we measure the leading subjet distributions, which allow access to a region of harder jet fragmentation than has been probed by previous measurements of jet quenching via hadron fragmentation distributions. The zrz_r distributions enable extraction of the parton-to-subjet fragmentation function and allow for tests of the universality of jet fragmentation functions in the quark-gluon plasma (QGP). We find indications that there is a turnover in the ratio between the distributions in \mbox{Pb--Pb} and pp\mathrm{p\kern-0.05em p} collisions as zr1z_r \rightarrow 1, exposing qualitatively new possibilities to disentangle competing jet quenching mechanisms. By comparing our results to theoretical calculations based on an independent extraction of the parton-to-jet fragmentation function, we find consistency with the universality of jet fragmentation and no indication of factorization breaking in the QGP.This article presents new measurements of the fragmentation properties of jets in both proton–proton (pp) and heavy-ion collisions with the ALICE experiment at the Large Hadron Collider (LHC). We report distributions of the fraction zr_{r} of transverse momentum carried by subjets of radius r within jets of radius R. Charged-particle jets are reconstructed at midrapidity using the anti-kT_{T} algorithm with jet radius R = 0.4, and subjets are reconstructed by reclustering the jet constituents using the anti-kT_{T} algorithm with radii r = 0.1 and r = 0.2. In proton–proton collisions, we measure both the inclusive and leading subjet distributions. We compare these measurements to perturbative calculations at next-to-leading logarithmic accuracy, which suggest a large impact of threshold resummation and hadronization effects on the zr_{r} distribution. In heavy-ion collisions, we measure the leading subjet distributions, which allow access to a region of harder jet frag- mentation than has been probed by previous measurements of jet quenching via hadron fragmentation distributions. The zr_{r} distributions enable extraction of the parton-to-subjet fragmentation function and allow for tests of the universality of jet fragmentation functions in the quark–gluon plasma (QGP). We find no significant modification of zr_{r} distributions in Pb–Pb compared to pp collisions. However, the distributions are also consistent with a hardening trend for zr_{r}< 0.95, as predicted by several jet quenching models. As zr_{r} → 1 our results indicate that any such hardening effects cease, exposing qualitatively new possibilities to disentangle competing jet quenching mechanisms. By comparing our results to theoretical calculations based on an independent extraction of the parton-to-jet fragmentation function, we find consistency with the universality of jet fragmentation and no indication of factorization breaking in the QGP.[graphic not available: see fulltext]This article presents new measurements of the fragmentation properties of jets in both proton-proton (pp) and heavy-ion collisions with the ALICE experiment at the LHC. We report distributions of the fraction zrz_r of transverse momentum carried by subjets of radius rr within jets of radius RR. Charged-particle jets are reconstructed at midrapidity using the anti-kTk_{\rm{T}} algorithm with jet radius R=0.4R=0.4, and subjets are reconstructed by reclustering the jet constituents using the anti-kTk_{\rm{T}} algorithm with radii r=0.1r=0.1 and r=0.2r=0.2. In pp collisions, we measure both the inclusive and leading subjet distributions. We compare these measurements to perturbative calculations at next-to-leading logarithmic accuracy, which suggest a large impact of threshold resummation and hadronization effects on the zrz_r distribution. In heavy-ion collisions, we measure the leading subjet distributions, which allow access to a region of harder jet fragmentation than has been probed by previous measurements of jet quenching via hadron fragmentation distributions. The zrz_r distributions enable extraction of the parton-to-subjet fragmentation function and allow for tests of the universality of jet fragmentation functions in the quark-gluon plasma (QGP). We find no significant modification of zrz_r distributions in Pb-Pb compared to pp collisions. However, the distributions are also consistent with a hardening trend for zr<0.95z_r<0.95, as predicted by several jet quenching models. As zr1z_r \rightarrow 1 our results indicate that any such hardening effects cease, exposing qualitatively new possibilities to disentangle competing jet quenching mechanisms. By comparing our results to theoretical calculations based on an independent extraction of the parton-to-jet fragmentation function, we find consistency with the universality of jet fragmentation and no indication of factorization breaking in the QGP

    Measurement of the production of charm jets tagged with D0^{0} mesons in pp collisions at s \sqrt{s} = 5.02 and 13 TeV

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    The measurement of the production of charm jets, identified by the presence of a D0{\rm D^0} meson in the jet constituents, is presented in proton–proton collisions at centre-of-mass energies of s\sqrt{s} = 5.02 and 13 TeV with the ALICE detector at the CERN LHC. The D0 mesons were reconstructed from their hadronic decay D0Kπ+{\rm D^0} \rightarrow {\rm K^-}\pi^+ and the respective charge conjugate. Jets were reconstructed from D0{\rm D^0}-meson candidates and charged particles using the anti-kTk_{\rm T} algorithm, in the jet transverse momentum range 5<pT;chjet<505<p_{\rm T;chjet}<50 GeV/cc, pseudorapidity ηjet<0.9R|\eta_{\rm jet}| <0.9-R, and with the jet resolution parameters RR = 0.2, 0.4, 0.6. The distribution of the jet momentum fraction carried by a D0{\rm D^0} meson along the jet axis (zchz^{\rm ch}_{||}) was measured in the range 0.4<zch<1.00.4 < z^{\rm ch}_{||} < 1.0 in four ranges of the jet transverse momentum. Comparisons of results for different collision energies and jet resolution parameters are also presented. The measurements are compared to predictions from Monte Carlo event generators based on leading-order and next-to-leading-order perturbative quantum chromodynamics calculations. A generally good description of the main features of the data is obtained in spite of a few discrepancies at low pT;chjetp_{\rm T;chjet}. Measurements were also done for R=0.3R = 0.3 at s\sqrt{s} = 5.02 TeV and are shown along with their comparisons to theoretical predictions in an appendix to this paper.The measurement of the production of charm jets, identified by the presence of a D0^{0} meson in the jet constituents, is presented in proton–proton collisions at centre-of-mass energies of s \sqrt{s} = 5.02 and 13 TeV with the ALICE detector at the CERN LHC. The D0^{0} mesons were reconstructed from their hadronic decay D0^{0} → K^{−}π+^{+} and the respective charge conjugate. Jets were reconstructed from D0^{0}-meson candidates and charged particles using the anti-kT_{T} algorithm, in the jet transverse momentum range 5 < pT,chjet_{T,chjet}< 50 GeV/c, pseudorapidity |ηjet_{jet}| < 0.9 − R, and with the jet resolution parameters R = 0.2, 0.4, 0.6. The distribution of the jet momentum fraction carried by a D0^{0} meson along the jet axis (zch) \left({z}_{\Big\Vert}^{\textrm{ch}}\right) was measured in the range 0.4 <zch {z}_{\Big\Vert}^{\textrm{ch}} < 1.0 in four ranges of the jet transverse momentum. Comparisons of results for different collision energies and jet resolution parameters are also presented. The measurements are compared to predictions from Monte Carlo event generators based on leading-order and next-to-leading-order perturbative quantum chromodynamics calculations. A generally good description of the main features of the data is obtained in spite of a few discrepancies at low pT,chjet_{T,chjet}. Measurements were also done for R = 0.3 at s \sqrt{s} = 5.02 and are shown along with their comparisons to theoretical predictions in an appendix to this paper.[graphic not available: see fulltext]The measurement of the production of charm jets, identified by the presence of a D0{\rm D^0} meson in the jet constituents, is presented in proton-proton collisions at centre-of-mass energies of s\sqrt{s} = 5.02 and 13 TeV with the ALICE detector at the CERN LHC. The D0{\rm D^0} mesons were reconstructed from their hadronic decay D0Kπ+{\rm D^0} \rightarrow {\rm K^-}\pi^+ and the respective charge conjugate. Jets were reconstructed from D0{\rm D^0}-meson candidates and charged particles using the anti-kTk_{\rm T} algorithm, in the jet transverse momentum range 5<pT;chjet<505<p_{\rm T;chjet}<50 GeV/cc, pseudorapidity ηjet<0.9R|\eta_{\rm jet}| <0.9-R, and with the jet resolution parameters RR = 0.2, 0.4, 0.6. The distribution of the jet momentum fraction carried by a D0{\rm D^0} meson along the jet axis (zchz^{\rm ch}_{||}) was measured in the range 0.4<zch<1.00.4 < z^{\rm ch}_{||} < 1.0 in four ranges of the jet transverse momentum. Comparisons of results for different collision energies and jet resolution parameters are also presented. The measurements are compared to predictions from Monte Carlo event generators based on leading-order and next-to-leading-order perturbative quantum chromodynamics calculations. A generally good description of the main features of the data is obtained in spite of a few discrepancies at low pT;chjetp_{\rm T;chjet}. Measurements were also done for R=0.3R = 0.3 at s\sqrt{s} = 5.02 TeV and are shown along with their comparisons to theoretical predictions in an appendix to this paper

    Constraining the KN{\overline{\textrm{K}}}{\textrm{N}} coupled channel dynamics using femtoscopic correlations at the LHC

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    The interaction of K{\rm{K}^{-}} with protons is characterised by the presence of several coupled channels, systems like K0{\rm \overline{K}^0}n and πΣ{\pi\Sigma} with a similar mass and the same quantum numbers as the K{\rm{K}^{-}} p state. The strengths of these couplings to the K{\rm{K}^{-}}p system are of crucial importance for the understanding of the nature of the Λ(1405)\Lambda(1405) resonance and of the attractive K{\rm{K}^{-}} p strong interaction. In this article, we present measurements of the K{\rm{K}^{-}}p correlation functions in relative momentum space obtained in pp collisions at s=13\sqrt{s} = 13~TeV, in p-Pb collisions at sNN=5.02\sqrt{s_{\rm NN}} = 5.02~TeV, and (semi)peripheral Pb-Pb collisions at sNN=5.02\sqrt{s_{\rm NN}} = 5.02~TeV. The emitting source size, composed of a core radius anchored to the K+{\rm{K}^{+}}p correlation and of a resonance halo specific to each particle pair, varies between 1 and 2 fm in these collision systems. The strength and the effects of the K0{\rm \overline{K}^0}n and πΣ{\pi\Sigma} inelastic channels on the measured K{\rm{K}^{-}}p correlation function are investigated in the different colliding systems by comparing the data with state-of-the-art models of chiral potentials. A novel approach to determine the conversion weights ω\omega, necessary to quantify the amount of produced inelastic channels in the correlation function, is presented. In this method, particle yields are estimated from thermal model predictions, and their kinematic distribution from blast-wave fits to measured data. The comparison of chiral potentials to the measured K{\rm{K}^{-}}p interaction indicates that, while the \mbox{πΣ{\pi\Sigma}-K{\rm{K}^{-}}p} dynamics is well reproduced by the model, the coupling to the K0{\rm \overline{K}^0}n channel in the model is currently underestimated.The interaction of K\textrm{K}^{-}with protons is characterised by the presence of several coupled channels, systems like K0{\overline{\textrm{K}}}^0n and \uppi \Sigma with a similar mass and the same quantum numbers as the K\textrm{K}^{-}p state. The strengths of these couplings to the K\textrm{K}^{-}p system are of crucial importance for the understanding of the nature of the Λ(1405)\Lambda (1405) resonance and of the attractive K\textrm{K}^{-}p strong interaction. In this article, we present measurements of the K\textrm{K}^{-}p correlation functions in relative momentum space obtained in pp collisions at s = 13\sqrt{s}~=~13 Te, in p–Pb collisions at sNN = 5.02\sqrt{s_{\textrm{NN}}}~=~5.02 Te, and (semi)peripheral Pb–Pb collisions at sNN = 5.02\sqrt{s_{\textrm{NN}}}~=~5.02 Te. The emitting source size, composed of a core radius anchored to the K+\textrm{K}^{+}p correlation and of a resonance halo specific to each particle pair, varies between 1 and 2 fm in these collision systems. The strength and the effects of the K0{\overline{\textrm{K}}}^0n and \uppi \Sigma inelastic channels on the measured K\textrm{K}^{-}p correlation function are investigated in the different colliding systems by comparing the data with state-of-the-art models of chiral potentials. A novel approach to determine the conversion weights ω\omega , necessary to quantify the amount of produced inelastic channels in the correlation function, is presented. In this method, particle yields are estimated from thermal model predictions, and their kinematic distribution from blast-wave fits to measured data. The comparison of chiral potentials to the measured K\textrm{K}^{-}p interaction indicates that, while the \uppi \Sigma K\textrm{K}^{-}p dynamics is well reproduced by the model, the coupling to the K0{\overline{\textrm{K}}}^0n channel in the model is currently underestimated.The interaction of K\rm{K}^{-} with protons is characterised by the presence of several coupled channels, systems like K0{\rm \overline{K}^0}n and πΣ\pi\Sigma with a similar mass and the same quantum numbers as the K\rm{K}^{-}p state. The strengths of these couplings to the K\rm{K}^{-}p system are of crucial importance for the understanding of the nature of the Λ(1405)\Lambda(1405) resonance and of the attractive K\rm{K}^{-}p strong interaction. In this article, we present measurements of the K\rm{K}^{-}p correlation functions in relative momentum space obtained in pp collisions at s = 13\sqrt{s}~=~13 TeV, in p-Pb collisions at sNN = 5.02\sqrt{s_{\mathrm{NN}}}~=~5.02 TeV, and (semi)peripheral Pb-Pb collisions at sNN = 5.02\sqrt{s_{\mathrm{NN}}}~=~5.02 TeV. The emitting source size, composed of a core radius anchored to the K+\rm{K}^{+}p correlation and of a resonance halo specific to each particle pair, varies between 1 and 2 fm in these collision systems. The strength and the effects of the K0{\rm \overline{K}^0}n and πΣ\pi\Sigma inelastic channels on the measured K\rm{K}^{-}p correlation function are investigated in the different colliding systems by comparing the data with state-of-the-art models of chiral potentials. A novel approach to determine the conversion weights ω\omega, necessary to quantify the amount of produced inelastic channels in the correlation function, is presented. In this method, particle yields are estimated from thermal model predictions, and their kinematic distribution from blast-wave fits to measured data. The comparison of chiral potentials to the measured K\rm{K}^{-}p interaction indicates that, while the πΣK\pi\Sigma-\rm{K}^{-}p dynamics is well reproduced by the model, the coupling to the K0{\rm \overline{K}^0}n channel in the model is currently underestimated
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