Compressive and shear behaviour of masonry panels: experimentation and numerical analysis

The compressive and shear behavior of masonry is here studied both experimental- ly and numerically. An experimental campaign has been carried out on 9 square-shaped one leaf masonry panels, reproducing historical masonry. Tests have been done for evaluating the elastic and shear moduli in both plane directions, with 6 panels rotated by 90 degrees, lead- ing to vertically aligned bed joints, and 3 panels maintained with horizontal bed joints. Com- pressive tests were executed on 6 masonry panels, 3 of them rotated by 90 degrees. Initial shear strength and shear modulus parallel to bed joints are evaluated through shear tests on 9 masonry triplets. Shear tests are performed on 3 rotated panels, applying an horizontal dis- tributed load, without vertical compression. Attention is paid to the service load state: only the initial phase of the tests is studied. Numerical models are proposed for representing actu- al masonry behavior, both discrete [1] and continuous [2,3], standard and micropolar, ob- tained by homogenization procedures [4]. Several numerical analyses are performed for simulating the experimental tests on masonry triplets and panels. The mechanical elastic pa- rameters of both discrete and continuous models are calibrated starting from laboratory data of masonry constituents and then by fitting the results of the initial phases of the experimental tests on masonry specimens

Uncertainties in risk assessment of hydrogen discharges from pressurized storage vessels at low temperatures

Evaluations of the uncertainties resulting from risk assessment tools to predict releases from the various hydrogen storage types are important to support risk informed safety management. The tools have to predict releases from a wide range of storage pressures (up to 80 MPa) and temperatures (at 20K) e.g. the cryogenic compressed gas storage covers pressures up to 35 MPa and temperatures between 33K and 338 K. Accurate calculations of high pressure releases require real gas EOS. This paper compares a number of EOS to predict hydrogen properties typical in different storage types. The vessel dynamics are modeled to evaluate the performance of various EOS to predict exit pressures and temperatures. The results are compared to experimental data and results from CFD calculations.JRC.F.2-Cleaner energ

Electron-phonon coupling in potassium-doped graphene: Angle-resolved photoemission spectroscopy

The electron-phonon coupling in potassium-doped graphene on Ir(111) is studied via the renormalization of the pi* band near the Fermi level, using angle-resolved photoemission spectroscopy. The renormalization is found to be fairly weak and almost isotropic, with a mass enhancement parameter of lambda= 0.28(6) for both the K-M and the K-G direction. These results are found to agree well with recent first principles calculations.Comment: 5 pages, 3 figure

Sensitivity to damage imperfection for multileaf masonry walls based on vibrational analyses

Damage-imperfection indicators based on variation of dynamic parameters allow to identify the intrinsic discontinuity and the damage of structures. Here, the structural health monitoring through the vibration-based approach has been carried out by two steps on three different multileaf masonry specimens (full infill, damaged infill, and strengthened infill) subjected to uniaxial compressive load. In the first step, the characterization of initial conditions based on the investigation of the intrinsic discontinuity and the manufacturing imperfections has been done. In this phase, the detection, localization, assessment, and prediction of damage have been given by the comparison between the experimental and numerical modal data calculated by the commercial finite element code. Subsequently, in the second step, starting from the identification of undamaged condition, the damage effects on changes of the dynamic parameters have been recorded. As well known, the incoherent response between the leaves is related to frequency values, damping ratios, and modal shapes

Surface Core Level Shifts of Clean and Oxygen Covered Ru(0001)

We have performed high resolution XPS experiments of the Ru(0001) surface, both clean and covered with well-defined amounts of oxygen up to 1 ML coverage. For the clean surface we detected two distinct components in the Ru 3d_{5/2} core level spectra, for which a definite assignment was made using the high resolution Angle-Scan Photoelectron Diffraction approach. For the p(2x2), p(2x1), (2x2)-3O and (1x1)-O oxygen structures we found Ru 3d_{5/2} core level peaks which are shifted up to 1 eV to higher binding energies. Very good agreement with density functional theory calculations of these Surface Core Level Shifts (SCLS) is reported. The overriding parameter for the resulting Ru SCLSs turns out to be the number of directly coordinated O atoms. Since the calculations permit the separation of initial and final state effects, our results give valuable information for the understanding of bonding and screening at the surface, otherwise not accessible in the measurement of the core level energies alone.Comment: 16 pages including 10 figures. Submitted to Phys. Rev. B. Related publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm

Antimicrobial activity of an iron triple helicate

The prevalence of antibiotic resistance has resulted in the need for new approaches to be developed to combat previously easily treatable infections. Here we investigated the potential of the synthetic metallomolecules [Fe2L3]4+ and [Cu2(L’)2]2+ as antibacterial agents. Both molecules have been shown to bind DNA; [Fe2L3]4+ binds in the major groove and causes DNA coiling, whilst [Cu2(L’)2]2+ can act as an artificial nuclease. The work described here shows that only [Fe2L3]4+ is bactericidal for Bacillus subtilis and Escherichia coli. We demonstrate that [Fe2L3]4+ binds bacterial DNA in vivo and, strikingly, that it kills B. subtilis cells very rapidly

Laboratory and numerical experimentation for masonry in compression

In this paper, the initial part of a laboratory and numerical experimental campaign dedicated to historical masonry is described. One leaf masonry panels with regular texture are built in order to simulate a historical material characterised by strong resisting elements and weak mortar joints. Laboratory tests are first dedicated to masonry components and then to the behaviour in compression of masonry panels, which is applied both orthogonal and parallel to bed joints, in order to highlight the orthotropic behaviour of the material. First of all, the mechanical parameters of masonry constituents are calibrated and then a heterogeneous finite element model is introduced and calibrated for reproducing the orthotropic behaviour of masonry, together with the initial elastic response and the initial nonlinear behaviour due to the first level of damage

Induced expression of the Fragaria 7 ananassa Rapid alkalinization factor-33-like gene decreases anthracnose ontogenic resistance of unripe strawberry fruit stages

Rapid alkalinization factor (RALF) genes encode for ubiquitous small peptides that stimulate apoplastic alkalinization through interaction with malectin-like receptor kinase. RALF peptides may act as negative regulators of plant immune response, inhibiting the formation of the signal receptor complex for immune activation. Recently RALF homologues were identified in different fungal pathogen genomes contributing to host infection ability. Here, FaRALF-33-like gene expression was evaluated in strawberry fruits inoculated with Colletotrichum acutatum, Botrytis cinerea, or Penicillium expansum after 24 and 48 h post-infection. To investigate the role of FaRALF-33-like in strawberry susceptibility, transient transformation was used to overexpress it in white unripe fruits and silence it in red ripe fruits. Agroinfiltrated fruits were inoculated with C. acutatum and expression, and histological analysis of infection were performed. Silencing of FaRALF-33-like expression in C. acutatum-inoculated red fruits led to a delay in fruit colonization by the fungal pathogen, and infected tissues showed less penetrated infective hyphae than in wild-type fruits. In contrast, C. acutatum-inoculated white unripe fruits overexpressing the FaRALF-33-like gene decreased the ontogenic resistance of these fruits, leading to the appearance of disease symptoms and penetrated subcuticular hyphae, normally absent in white unripe fruits. The different response of transfected strawberry fruits to C. acutatum supports the hypothesis that the FaRALF-33-like gene plays an important role in the susceptibility of fruits to the fungal pathogen C. acutatum