22,955 research outputs found
Explicit correlation and basis set superposition error: The structure and energy of carbon dioxide dimer
We have investigated the slipped parallel and t-shaped structures of carbon dioxide dimer [(CO₂)₂] using both conventional and explicitly correlated coupled cluster methods, inclusive and exclusive of counterpoise (CP) correction. We have determined the geometry of both structures with conventional coupled cluster singles doubles and perturbative triples theory [CCSD(T)] and explicitly correlated cluster singles doubles and perturbative triples theory [CCSD(T)-F12b] at the complete basis set (CBS) limits using custom optimization routines. Consistent with previous investigations, we find that the slipped parallel structure corresponds to the global minimum and is 1.09 kJ mol⁻¹ lower in energy. For a given cardinal number, the optimized geometries and interaction energies of (CO₂)₂ obtained with the explicitly correlated CCSD(T)-F12b method are closer to the CBS limit than the corresponding conventional CCSD(T) results. Furthermore, the magnitude of basis set superposition error (BSSE) in the CCSD(T)-F12b optimized geometries and interaction energies is appreciably smaller than the magnitude of BSSE in the conventional CCSD(T) results. We decompose the CCSD(T) and CCSD(T)-F12b interaction energies into the constituent HF or HF CABS, CCSD or CCSD-F12b, and (T) contributions. We find that the complementary auxiliary basis set (CABS) singles correction and the F12b approximation significantly reduce the magnitude of BSSE at the HF and CCSD levels of theory, respectively. For a given cardinal number, we find that non-CP corrected, unscaled triples CCSD(T)-F12b/VXZ-F12 interaction energies are in overall best agreement with the CBS limit
Less government intervention in biodiversity management: risks and opportunities
n a changing global environment, with increasing pressure on ecosystem goods and services, biodiversity conservation is likely to become increasingly important. However, with the current global financial crisis, governments are increasingly trying to stabilise economies through spending cuts aiming to reduce national deficits. Within such an economic climate, the devolution of governance through public participation is an intrinsically appealing concept. We outline a number of challenges that explain why increased participation in biodiversity management has been and may continue to be problematic. Using as a case study the local stakeholder-driven Moray Firth Seal Management Plan in Scotland, we identify four key conditions that were crucial to the successful participatory management of a biodiversity conflict: a local champion, the emergence of a crisis point, the involvement of decision-makers, and long-term financial and institutional support. Three of the four conditions point to the role of direct government involvement, highlighting the risk of devolving responsibility for biodiversity conflict management to local communities. We argue that without an informed debate, the move towards a more participatory approach could pose a danger to hard-won policy gains in relation to public participation, biodiversity conservation and conflict management
An astronomical search for evidence of new physics: Limits on gravity-induced birefringence from the magnetic white dwarf RE J0317-853
The coupling of the electromagnetic field directly with gravitational gauge
fields leads to new physical effects that can be tested using astronomical
data. Here we consider a particular case for closer scrutiny, a specific
nonminimal coupling of torsion to electromagnetism, which enters into a
metric-affine geometry of space-time. We show that under the assumption of this
nonminimal coupling, spacetime is birefringent in the presence of such a
gravitational field. This leads to the depolarization of light emitted from
extended astrophysical sources. We use polarimetric data of the magnetic white
dwarf to set strong constraints on the essential coupling
constant for this effect, giving k^2 \lsim (19 {m})^2 .Comment: Statements about Moffat's NGT modified. Accepted for publication in
Phys.Rev.
QUASAT: An orbiting very long baseline interferometer program using large space antenna systems
QUASAT, which stands for QUASAR SATELLITE, is the name given to a new mission being studied by NASA. The QUASAT mission concept involves a free flying Earth orbiting large radio telescope, which will observe astronomical radio sources simultaneously with ground radio telescopes. The primary goal of QUASAT is to provide a system capable of collecting radio frequency data which will lead to a better understanding of extremely high energy events taking place in a variety of celestial objects including quasars, galactic nuclei, interstellar masers, radio stars and pulsars. QUASAT's unique scientific contribution will be the increased resolution in the emission brightness profile maps of the celestial objects
Investigation of a laser Doppler velocimeter system to measure the flow field around a large scale V/STOL aircraft in ground effect
The flow field measured around a hovering 70 percent scale vertical takeoff and landing (V/STOL) aircraft model is described. The velocity measurements were conducted with a ground based laser Doppler velocimeter. The remote sensing instrumentation and experimental tests of the velocity surveys are discussed. The distribution of vertical velocity in the fan jet and fountain; the radial velocity in the wall jet and the horizontal velocity along the aircraft underside are presented for different engine rpms and aircraft height above ground. Results show that it is feasible to use a mobile laser Doppler velocimeter to measure the flow field generated by a large scale V/STOL aircraft operating in ground effect
Multi-centre retrospective study of long-term outcomes following traumatic elbow luxation in 37 dogs
The flashing ratchet and unidirectional transport of matter
We study the flashing ratchet model of a Brownian motor, which consists in
cyclical switching between the Fokker-Planck equation with an asymmetric
ratchet-like potential and the pure diffusion equation. We show that the motor
really performs unidirectional transport of mass, for proper parameters of the
model, by analyzing the attractor of the problem and the stationary vector of a
related Markov chain.Comment: 11 page
On the existence of infinitely many closed geodesics on orbifolds of revolution
Using the theory of geodesics on surfaces of revolution, we introduce the
period function. We use this as our main tool in showing that any
two-dimensional orbifold of revolution homeomorphic to S^2 must contain an
infinite number of geometrically distinct closed geodesics. Since any such
orbifold of revolution can be regarded as a topological two-sphere with metric
singularities, we will have extended Bangert's theorem on the existence of
infinitely many closed geodesics on any smooth Riemannian two-sphere. In
addition, we give an example of a two-sphere cone-manifold of revolution which
possesses a single closed geodesic, thus showing that Bangert's result does not
hold in the wider class of closed surfaces with cone manifold structures.Comment: 21 pages, 4 figures; for a PDF version see
http://www.calpoly.edu/~jborzell/Publications/publications.htm
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