Synthesis and membrane transport properties of bis(dihexylphosphorylmethyl)-1,4-diaminebutane

© 2016 Taylor & Francis Group, LLC.The membrane-transport properties have been studied. It was found that bis(dihexylphosphorylmethyl)- 1,4-diaminebutane is a good extractant for triply charged metal ions such as Sc(III), Nd(III), and Sm(III). However, it does not exhibit any noticeable selectivity with respect to certain substrates. Bis(dihexylphosphorylmethyl)-1,4-diaminebutane is a good carrier of nitric acid.We have recorded the crystal structure of the complex of the reagent mentioned with the nitric acid

Climate changes in East Siberia (Russia) in the Holocene based on diatom, chironomid and pollen records from the sediments of Lake Kotokel

We analysed a 620-cm-long sediment record from Lake Kotokel located in East Siberia (Russia) for subfossil diatoms, chironomids and pollen to provide a reconstruction of the climate history of the area for the last 12. 2 kyr. The subfossil records show differing time lags in their responses to climate change; diatoms and chironomids were more sensitive to climate change than the pollen record. Changes in the biogenic proxies seem related with changes in insolation, the temperature of the North Atlantic and solar activity. The chironomids Chironomus plumosus-type and Einfeldia carbonaria-type and the diatom Aulacoseira granulata were interpreted as markers of warm climate condition. The proxy records were divided into four periods (A, B, C and D) suggesting differing climate in East Siberia during the Holocene. Period D (12. 2-9. 5 kyr BP) at the beginning of the Holocene, according to chironomid and diatom records, was characterized by warm climate with summer temperatures close to modern. However, forest vegetation had not become fully established yet. During Period C (9. 5-5. 8 kyr BP), the climate seemed to gradually become colder and wetter from the beginning of Period C to 7 kyr BP. From 7 to 5. 8 kyr BP, the climate seemed to remain cold, but aridity increased. Period B (5. 8-1. 7 kyr BP) was characterised by frequent and sharp alternations between warm and cold conditions. Unstable conditions during this time are also registered in records from Lakes Baikal, Khubsugul and various other shallow lakes of the region. Optimal warm and wet conditions seemed to occur ca. 4 kyr BP. During Period A (the last 1. 5 kyr) the diatom and chironomid records show evidence of cold conditions at 1. 5-1 kyr BP, but the forest vegetation did not change significantly. © 2012 Springer Science+Business Media B.V

Constraints on the CMB Temperature Evolution using Multi-Band Measurements of the Sunyaev Zel'dovich Effect with the South Pole Telescope

The adiabatic evolution of the temperature of the cosmic microwave background (CMB) is a key prediction of standard cosmology. We study deviations from the expected adiabatic evolution of the CMB temperature of the form $T(z) =T_0(1+z)^{1-\alpha}$ using measurements of the spectrum of the Sunyaev Zel'dovich Effect with the South Pole Telescope (SPT). We present a method for using the ratio of the Sunyaev Zel'dovich signal measured at 95 and 150 GHz in the SPT data to constrain the temperature of the CMB. We demonstrate that this approach provides unbiased results using mock observations of clusters from a new set of hydrodynamical simulations. We apply this method to a sample of 158 SPT-selected clusters, spanning the redshift range $0.05 < z < 1.35$, and measure $\alpha = 0.017^{+0.030}_{-0.028}$, consistent with the standard model prediction of $\alpha=0$. In combination with other published results, we constrain $\alpha = 0.011 \pm 0.016$, an improvement of $\sim 20\%$ over published constraints. This measurement also provides a strong constraint on the effective equation of state in models of decaying dark energy $w_\mathrm{eff} = -0.987^{+0.016}_{-0.017}$.Comment: Submitted to MNRAS Letter

The Growth of Cool Cores and Evolution of Cooling Properties in a Sample of 83 Galaxy Clusters at 0.3 < z < 1.2 Selected from the SPT-SZ Survey

We present first results on the cooling properties derived from Chandra X-ray observations of 83 high-redshift (0.3 < z < 1.2) massive galaxy clusters selected by their Sunyaev-Zel'dovich signature in the South Pole Telescope data. We measure each cluster's central cooling time, central entropy, and mass deposition rate, and compare to local cluster samples. We find no significant evolution from z~0 to z~1 in the distribution of these properties, suggesting that cooling in cluster cores is stable over long periods of time. We also find that the average cool core entropy profile in the inner ~100 kpc has not changed dramatically since z ~ 1, implying that feedback must be providing nearly constant energy injection to maintain the observed "entropy floor" at ~10 keV cm^2. While the cooling properties appear roughly constant over long periods of time, we observe strong evolution in the gas density profile, with the normalized central density (rho_0/rho_crit) increasing by an order of magnitude from z ~ 1 to z ~ 0. When using metrics defined by the inner surface brightness profile of clusters, we find an apparent lack of classical, cuspy, cool-core clusters at z > 0.75, consistent with earlier reports for clusters at z > 0.5 using similar definitions. Our measurements indicate that cool cores have been steadily growing over the 8 Gyr spanned by our sample, consistent with a constant, ~150 Msun/yr cooling flow that is unable to cool below entropies of 10 keV cm^2 and, instead, accumulates in the cluster center. We estimate that cool cores began to assemble in these massive systems at z ~ 1, which represents the first constraints on the onset of cooling in galaxy cluster cores. We investigate several potential biases which could conspire to mimic this cool core evolution and are unable to find a bias that has a similar redshift dependence and a substantial amplitude.Comment: 17 pages with 15 figures, plus appendix. Published in Ap

Optical Spectroscopy and Velocity Dispersions of Galaxy Clusters from the SPT-SZ Survey

We present optical spectroscopy of galaxies in clusters detected through the Sunyaev-Zel'dovich (SZ) effect with the South Pole Telescope (SPT). We report our own measurements of $61$ spectroscopic cluster redshifts, and $48$ velocity dispersions each calculated with more than $15$ member galaxies. This catalog also includes $19$ dispersions of SPT-observed clusters previously reported in the literature. The majority of the clusters in this paper are SPT-discovered; of these, most have been previously reported in other SPT cluster catalogs, and five are reported here as SPT discoveries for the first time. By performing a resampling analysis of galaxy velocities, we find that unbiased velocity dispersions can be obtained from a relatively small number of member galaxies ($\lesssim 30$), but with increased systematic scatter. We use this analysis to determine statistical confidence intervals that include the effect of membership selection. We fit scaling relations between the observed cluster velocity dispersions and mass estimates from SZ and X-ray observables. In both cases, the results are consistent with the scaling relation between velocity dispersion and mass expected from dark-matter simulations. We measure a $\sim$30% log-normal scatter in dispersion at fixed mass, and a $\sim$10% offset in the normalization of the dispersion-mass relation when compared to the expectation from simulations, which is within the expected level of systematic uncertainty.Comment: Accepted to ApJ. 20 pages, 6 figure

SPT-CL J0205-5829: A z = 1.32 Evolved Massive Galaxy Cluster in the South Pole Telescope Sunyaev-Zel'dovich Effect Survey

The galaxy cluster SPT-CL J0205-5829 currently has the highest spectroscopically-confirmed redshift, z=1.322, in the South Pole Telescope Sunyaev-Zel'dovich (SPT-SZ) survey. XMM-Newton observations measure a core-excluded temperature of Tx=8.7keV producing a mass estimate that is consistent with the Sunyaev-Zel'dovich derived mass. The combined SZ and X-ray mass estimate of M500=(4.9+/-0.8)e14 h_{70}^{-1} Msun makes it the most massive known SZ-selected galaxy cluster at z>1.2 and the second most massive at z>1. Using optical and infrared observations, we find that the brightest galaxies in SPT-CL J0205-5829 are already well evolved by the time the universe was <5 Gyr old, with stellar population ages >3 Gyr, and low rates of star formation (<0.5Msun/yr). We find that, despite the high redshift and mass, the existence of SPT-CL J0205-5829 is not surprising given a flat LambdaCDM cosmology with Gaussian initial perturbations. The a priori chance of finding a cluster of similar rarity (or rarer) in a survey the size of the 2500 deg^2 SPT-SZ survey is 69%.Comment: 11 pages, 5 figures, submitted to Ap

Historical Y. pestis Genomes Reveal the European Black Death as the Source of Ancient and Modern Plague Pandemics

© 2016 Elsevier Inc.Ancient DNA analysis has revealed an involvement of the bacterial pathogen Yersinia pestis in several historical pandemics, including the second plague pandemic (Europe, mid-14th century Black Death until the mid-18th century AD). Here we present reconstructed Y. pestis genomes from plague victims of the Black Death and two subsequent historical outbreaks spanning Europe and its vicinity, namely Barcelona, Spain (1300-1420 cal AD), Bolgar City, Russia (1362-1400 AD), and Ellwangen, Germany (1485-1627 cal AD). Our results provide support for (1) a single entry of Y. pestis in Europe during the Black Death, (2) a wave of plague that traveled toward Asia to later become the source population for contemporary worldwide epidemics, and (3) the presence of an historical European plague focus involved in post-Black Death outbreaks that is now likely extinct

Redshifts, Sample Purity, and BCG Positions for the Galaxy Cluster Catalog from the First 720 Square Degrees of the South Pole Telescope Survey

We present the results of the ground- and space-based optical and near-infrared (NIR) follow-up of 224 galaxy cluster candidates detected with the Sunyaev-Zel'dovich (SZ) effect in the 720 deg^2 of the South Pole Telescope (SPT) survey completed in the 2008 and 2009 observing seasons. We use the optical/NIR data to establish whether each candidate is associated with an overdensity of galaxies and to estimate the cluster redshift. Most photometric redshifts are derived through a combination of three different cluster redshift estimators using red-sequence galaxies, resulting in an accuracy of Δz/(1 + z) = 0.017, determined through comparison with a subsample of 57 clusters for which we have spectroscopic redshifts. We successfully measure redshifts for 158 systems and present redshift lower limits for the remaining candidates. The redshift distribution of the confirmed clusters extends to z = 1.35 with a median of z_(med) = 0.57. Approximately 18% of the sample with measured redshifts lies at z > 0.8. We estimate a lower limit to the purity of this SPT SZ-selected sample by assuming that all unconfirmed clusters are noise fluctuations in the SPT data. We show that the cumulative purity at detection significance ξ > 5(ξ > 4.5) is ≥95% (≥70%). We present the red brightest cluster galaxy (rBCG) positions for the sample and examine the offsets between the SPT candidate position and the rBCG. The radial distribution of offsets is similar to that seen in X-ray-selected cluster samples, providing no evidence that SZ-selected cluster samples include a different fraction of recent mergers from X-ray-selected cluster samples

Weak-Lensing Mass Measurements of Five Galaxy Clusters in the South Pole Telescope Survey Using Magellan/Megacam

We use weak gravitational lensing to measure the masses of five galaxy clusters selected from the South Pole Telescope (SPT) survey, with the primary goal of comparing these with the SPT Sunyaev--Zel'dovich (SZ) and X-ray based mass estimates. The clusters span redshifts 0.28 < z < 0.43 and have masses M_500 > 2 x 10^14 h^-1 M_sun, and three of the five clusters were discovered by the SPT survey. We observed the clusters in the g'r'i' passbands with the Megacam imager on the Magellan Clay 6.5m telescope. We measure a mean ratio of weak lensing (WL) aperture masses to inferred aperture masses from the SZ data, both within an aperture of R_500,SZ derived from the SZ mass, of 1.04 +/- 0.18. We measure a mean ratio of spherical WL masses evaluated at R_500,SZ to spherical SZ masses of 1.07 +/- 0.18, and a mean ratio of spherical WL masses evaluated at R_500,WL to spherical SZ masses of 1.10 +/- 0.24. We explore potential sources of systematic error in the mass comparisons and conclude that all are subdominant to the statistical uncertainty, with dominant terms being cluster concentration uncertainty and N-body simulation calibration bias. Expanding the sample of SPT clusters with WL observations has the potential to significantly improve the SPT cluster mass calibration and the resulting cosmological constraints from the SPT cluster survey. These are the first WL detections using Megacam on the Magellan Clay telescope.Comment: Main body: 18 pages, 7 figures, 6 tables. Appendix: 6 pages, 10 figures. Accepted by ApJ. New version incorporates changes from accepted articl