4,838 research outputs found
A functional combinatorial central limit theorem
The paper establishes a functional version of the Hoeffding combinatorial
central limit theorem. First, a pre-limiting Gaussian process approximation is
defined, and is shown to be at a distance of the order of the Lyapounov ratio
from the original random process. Distance is measured by comparison of
expectations of smooth functionals of the processes, and the argument is by way
of Stein's method. The pre-limiting process is then shown, under weak
conditions, to converge to a Gaussian limit process. The theorem is used to
describe the shape of random permutation tableaux.Comment: 23 page
On the identification of Ti-Ta-Nb-oxides in “wiikites” from Karelia
Purpose. With respect to the nature of Ti-Ta-Nb-oxides, which are included in the mineral associations that have historically gone by the now outdated name of “wiikites”, there is no unanimity of opinion. The main difficulty in identifying them is associated with the complexity of their chemical composition, their metamict structure and the substantial changes in their initial mineral form due to the effects of natural weathering. The aim of this work is the development of methodology to identify Ti-Ta-Nb-oxides corresponding to the mineral formulas AB2O6 and A2B2O7.
Methods. The methodology developed in the work includes two experimental approaches: 1) electron probe microanalysis of phases revealed through use of the SEM-BSE method. Based on the resulting data, a hypothesis about the nature of the Ti-Ta-Nb-oxides in a number of wiikite samples is proposed. 2) XRD analysis of those phases that are formed in the course of thermal annealing of samples from 200 to 1000°C. Based on the resulting data here, the previous hypotheses are either accepted or rejected for each sample.
Findings. Using this methodology, three “wiikite” samples were analyzed (the experimental codes were Wk-2, Wk-3 and Wk-7). The Ti-Ta-Nb-oxides in two of these wiikites (Wk-2 and Wk-3) were preliminarily determined to be hydroxyyttropyrochlore and hydroxycalciobetafite, respectively. In the third sample (Wk-7), the Ti-Ta-Nb-oxide was classified as polycrase. The results of XRD phase analysis of the annealed samples were compatible with the primary hypotheses that hydroxycalciobetafite and polycrase were the initial minerals in “wiikites” 3 and 7, respectively.
Originality. The paper considers the issue of the chemical conditions necessary for the recovery of the original
Ti-Ta-Nb-oxide during recrystallization of the metamict structures. This is a problem that has not been substantively addressed in the literature. Also for the first time experimentally proved the existence of the polycrase in “wiikites”.
Practical implications. Completed work expands our knowledge of the mineral composition of the granitic pegmatites of the Baltic shield and the possibility of their use both for research purposes and for needs of national economy.Мета. Розробка методології ідентифікації Ti-Ta-Nb-оксидів складного хімічного складу з метаміктною структурою, що відповідають мінеральним формулами АВ2О6 та А2В2О7.
Методика. Для розробки методології ідентифікації у роботі використано два експериментальних підходи: 1) рентген-спектральний мікроаналіз фаз, виявлених методом скануючої електронної мікроскопії зразків у назад відображених електронах. На основі отриманих результатів висунута гіпотеза щодо природи Ti-Ta-Nb-оксидів. 2) рентген-дифракційний аналіз фаз, що утворюються в процесі термічного відпалу зразків від 200 до 1000°С. На основі отриманих результатів для кожного зразка первинна гіпотеза приймалася або відкидалася.
Результати. З використанням даної методики були вивчені три зразки “віікітів” (шифри зразків: Wk-2, Wk-3 і Wk-7). Наявність Ti-Ta-Nb-оксидів попередньо визначено e двох зразках (Wk-2 і Wk-3) відповідно, як гідроксііттропірохлор та гідроксікальціобетафіт. У третьому зразку (Wk-7) Ti-Ta-Nb діагностований як полікраз. Результати рентген-дифракційного аналізу відпалених зразків підтвердили гіпотези про те, що початковими мінералами у Wk-3 і Wk-7 були гідроксікальціобетафіт і полікраз відповідно.
Наукова новизна. Визначено хімічні умови, необхідні для утворення початкового Тi-Ta-Nb під час рекристалізації метаміктної структури, що раніше не розглядалось у відповідній тематичній науковій літературі. Вперше експериментально виявлено присутність у “віікітах” полікраза.
Практична значимість. Отримані результати розширюють й доповнюють знання щодо мінерального складу гранітних пегматитів Балтійського щита та надають можливість їх використання в дослідницьких цілях і потребах народного господарства.Цель. Разработка методологии идентификации Ti-Ta-Nb-оксидов сложного химического состава с метамиктной структурой, соответствующих минеральным формулам АВ2О6 и А2В2О7.
Методика. Для разработки методологии идентификации в работе использовано два экспериментальных подхода: 1) рентген-спектральный микроанализ фаз, выявленных методом сканирующей электронной микроскопии образцов в обратно отраженных электронах. На основе полученных результатов выдвинута гипотеза о природе Ti-Ta-Nb-оксидов. 2) рентген-дифракционный анализ фаз, образующихся в процессе термического отжига образцов от 200 до 1000°С. На основе полученных результатов для каждого образца первоначальная гипотеза принималась или отвергалась.
Результаты. С использованием данной методики были изучены три образца “виикитов” (шифры образцов: Wk-2, Wk-3 и Wk-7). Наличие Ti-Ta-Nb-оксидов предварительно определено в двух образцах (Wk-2 и Wk-3) соответственно, как гидроксииттропирохлор и гидроксикальциобетафит. В третьем образце (Wk-7)
Ti-Ta-Nb диагностирован как поликраз. Результаты рентген-дифракционного анализа отожженных образцов подтвердили гипотезы о том, что первоначальными минералами в Wk-3 и Wk-7 были гидроксикальциобетафит и поликраз соответственно.
Научная новизна. Определены химические условия, необходимые для образования первоначального Тi-Ta-Nb во время рекристаллизации метамиктной структуры, что ранее не рассматривалось в соответствующих тематических научных литературе. Впервые экспериментально выявлено присутствие в “виикитах” поликраза.
Практическая значимость. Полученные результаты расширяют и дополняют знания о минеральном составе гранитных пегматитов Балтийского щита и дают возможности их использования в исследовательских целях и нуждах народного хозяйства.The study was conducted using equipment of the Center of X-ray Diffraction Studies and the Center for Microscopy and Microanalysis of the Research Park at Saint Petersburg State University, as well as the analytical laboratory of OJSC MMC Norilsk Nickel in Saint Petersburg
A network-based threshold model for the spreading of fads in society and markets
We investigate the behavior of a threshold model for the spreading of fads
and similar phenomena in society. The model is giving the fad dynamics and is
intended to be confined to an underlying network structure. We investigate the
whole parameter space of the fad dynamics on three types of network models. The
dynamics we discover is rich and highly dependent on the underlying network
structure. For some range of the parameter space, for all types of substrate
networks, there are a great variety of sizes and life-lengths of the fads --
what one see in real-world social and economical systems
Discovery of a stellar companion to the nearby solar-analogue HD 104304
Sun-like stars are promising candidates to host exoplanets and are often
included in exoplanet surveys by radial velocity (RV) and direct imaging. In
this paper we report on the detection of a stellar companion to the nearby
solar-analogue star HD 104304, which previously was considered to host a
planetary mass or brown dwarf companion. We searched for close stellar and
substellar companions around extrasolar planet host stars with high angular
resolution imaging to characterize planet formation environments. The detection
of the stellar companion was achieved by high angular resolution measurements,
using the "Lucky Imaging" technique at the ESO NTT 3.5m with the AstraLux Sur
instrument. We combined the results with VLT/NACO archive data, where the
companion could also be detected. The results were compared to precise RV
measurements of HD 104304, obtained at the Lick and Keck observatories from
2001-2010.
We confirmed common proper motion of the binary system. A spectral type of
M4V of the companion and a mass of 0.21 M_Sun was derived. Due to comparison of
the data with RV measurements of the unconfirmed planet candidate listed in the
Extrasolar Planets Encyclopaedia, we suggest that the discovered companion is
the origin of the RV trend and that the inclination of the orbit of
approximately 35 degrees explains the relatively small RV signal.Comment: 4 pages, 4 PNG figures, use aa.cls, accepted for publication in
Astronomy & Astrophysic
Spatially resolved spectroscopy of the exoplanet HR 8799 c
HR 8799 is a multi-planet system detected in direct imaging, with three
companions known so far. Here, we present spatially resolved VLT/NACO
3.88--4.10 micron spectroscopy of the middle planet, HR 8799 c, which has an
estimated mass of ~10 Mjup, temperature of ~1100 K and projected separation of
38 AU. The spectrum shows some differences in the continuum from existing
theoretical models, particularly longwards of 4 microns, implying that detailed
cloud structure or non-equilibrium conditions may play an important role in the
physics of young exoplanetary atmospheres.Comment: 4 pages, 4 figures, accepted for publication in ApJ Letter
Modeling the Searching Behavior of Social Monkeys
We discuss various features of the trajectories of spider monkeys looking for
food in a tropical forest, as observed recently in an extensive {\it in situ}
study. Some of the features observed can be interpreted as the result of social
interactions. In addition, a simple model of deterministic walk in a random
environment reproduces the observed angular correlations between successive
steps, and in some cases, the emergence of L\'evy distributions for the length
of the steps.Comment: 7 pages, 3 figure
Thermodynamic versus Topological Phase Transitions: Cusp in the Kert\'esz Line
We present a study of phase transitions of the Curie--Weiss Potts model at
(inverse) temperature , in presence of an external field . Both
thermodynamic and topological aspects of these transitions are considered. For
the first aspect we complement previous results and give an explicit equation
of the thermodynamic transition line in the -- plane as well as the
magnitude of the jump of the magnetization (for . The signature
of the latter aspect is characterized here by the presence or not of a giant
component in the clusters of a Fortuin--Kasteleyn type representation of the
model. We give the equation of the Kert\'esz line separating (in the
-- plane) the two behaviours. As a result, we get that this line
exhibits, as soon as , a very interesting cusp where it
separates from the thermodynamic transition line
Distance distribution in random graphs and application to networks exploration
We consider the problem of determining the proportion of edges that are
discovered in an Erdos-Renyi graph when one constructs all shortest paths from
a given source node to all other nodes. This problem is equivalent to the one
of determining the proportion of edges connecting nodes that are at identical
distance from the source node. The evolution of this quantity with the
probability of existence of the edges exhibits intriguing oscillatory behavior.
In order to perform our analysis, we introduce a new way of computing the
distribution of distances between nodes. Our method outperforms previous
similar analyses and leads to estimates that coincide remarkably well with
numerical simulations. It allows us to characterize the phase transitions
appearing when the connectivity probability varies.Comment: 12 pages, 8 figures (18 .eps files
Area Distribution of Elastic Brownian Motion
We calculate the excursion and meander area distributions of the elastic
Brownian motion by using the self adjoint extension of the Hamiltonian of the
free quantum particle on the half line. We also give some comments on the area
of the Brownian motion bridge on the real line with the origin removed. We will
stress on the power of self adjoint extension to investigate different possible
boundary conditions for the stochastic processes.Comment: 18 pages, published versio
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